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Thesis (Ph. D.)--University of Texas at Austin, 2002. / Includes bibliographical references. Available also in an electronic version.

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Flammability limit is a significant safety issue for industrial processes. A certain amount of flammability limit data for pure hydrocarbons are available in the literature, but for industrial applications, there are conditions including different combinations of fuels at standard and non-standard conditions, in which the flammability limit data are scarce and sometimes unavailable. This research is two-fold: (i) Performing experimental measurements to estimate the lower flammability limits and upper flammability limits of binary hydrocarbon mixtures, conducting experimental data numerical analysis to quantitatively characterize the flammability limits of these mixtures with parameters, such as component compositions, flammability properties of pure hydrocarbons, and thermo-kinetic values; (ii) Estimating flammability limits of binary hydrocarbon mixtures through CFT-V modeling prediction (calculated flame temperature at constant volume), which is based on a comprehensive consideration of energy conservation. For the experimental part, thermal detection was used in this experiment. The experimental results indicate that the experimental results fit Le Chatelier’s Law within experimental uncertainty at the lower flammability limit condition. At the upper flammability limit condition, Le Chatelier’s Law roughly fits the saturated hydrocarbon mixture data, while with mixtures that contain one or more unsaturated components, a modification of Le Chatelier’s is preferred to fit the experimental data. The easy and efficient way to modify Le Chatelier’s Law is to power the molar percentage concentrations of hydrocarbon components. For modeling prediction part, the CFT-V modeling is an extended modification of CAFT modeling at constant volume and is significantly related to the reaction vessel configuration. This modeling prediction is consistent with experimental observation and Le Chatelier’s Law at the concentrations of lower flammability limits. When the quenching effect is negligible, this model can be simplified by ignoring heat loss from the reaction vessel to the external surroundings. Specifically, when the total mole changes in chemical reactions can be neglected and the quenching effect is small, CFTV modeling can be simplified to CAFT modeling.

The International Thermonuclear Experimental Reactor (ITER) is currently designed to use graphite targets in the divertor for power handling and impurity control. Understanding and quantifying chemical sputtering is therefore key to the success of fusion as a clean energy source. The principal goal of this thesis is to design and carry out experiments, then analyze and interpret the results in order to elucidate the role of chemical sputtering in carbon sources in the DIII-D tokamak. A self-contained gas puff system has been designed, constructed, and employed for in-situ study of chemical erosion. The porous plug injector (PPI) releases methane through a porous graphite surface into the divertor plasma at a precisely calibrated rate, minimizing perturbation to local plasma while replicating the immediate environment of methane molecules released from a solid graphite surface more accurately than done previously. For the first time in a tokamak environment, the methane flow rate used in a puffing experiment was the same order of magnitude as that expected from laboratory experiments for intrinsic chemical sputtering. Effective photon efficiencies for injection are reported; results are found to have significant dependencies on surface conditions and the divertor operating regime. The contribution of sputtering processes to sources of C0 and C+ are assessed through measurement of background and incremental spectroscopic emissions of both physically and chemically-released sputtering products and by CI, 910 nm line profile fitting. Comparison of background and incremental emissions of chemically-released products demonstrate a dramatic drop in production of CH in cold and detached conditions. Finally, the chemical erosion yield is calculated in both attached and cold-divertor conditions and found to be much closer to that measured ex-situ in ion beam experiments than previously determined in DII-D. These observations represent a positive result for ITER which will operate at all times with a detached divertor, i.e., a low chemical sputtering yield. Results and analysis techniques presented here point the direction for future experiments with the PPI for study of chemical sputtering in the tokamak edge environment.

The International Thermonuclear Experimental Reactor (ITER) is currently designed to use graphite targets in the divertor for power handling and impurity control. Understanding and quantifying chemical sputtering is therefore key to the success of fusion as a clean energy source. The principal goal of this thesis is to design and carry out experiments, then analyze and interpret the results in order to elucidate the role of chemical sputtering in carbon sources in the DIII-D tokamak. A self-contained gas puff system has been designed, constructed, and employed for in-situ study of chemical erosion. The porous plug injector (PPI) releases methane through a porous graphite surface into the divertor plasma at a precisely calibrated rate, minimizing perturbation to local plasma while replicating the immediate environment of methane molecules released from a solid graphite surface more accurately than done previously. For the first time in a tokamak environment, the methane flow rate used in a puffing experiment was the same order of magnitude as that expected from laboratory experiments for intrinsic chemical sputtering. Effective photon efficiencies for injection are reported; results are found to have significant dependencies on surface conditions and the divertor operating regime. The contribution of sputtering processes to sources of C0 and C+ are assessed through measurement of background and incremental spectroscopic emissions of both physically and chemically-released sputtering products and by CI, 910 nm line profile fitting. Comparison of background and incremental emissions of chemically-released products demonstrate a dramatic drop in production of CH in cold and detached conditions. Finally, the chemical erosion yield is calculated in both attached and cold-divertor conditions and found to be much closer to that measured ex-situ in ion beam experiments than previously determined in DII-D. These observations represent a positive result for ITER which will operate at all times with a detached divertor, i.e., a low chemical sputtering yield. Results and analysis techniques presented here point the direction for future experiments with the PPI for study of chemical sputtering in the tokamak edge environment.

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