Thesis (Ph. D.)--University of Washington, 2005. / Vita. Includes bibliographical references (leaves 100-123).

Thesis (M. S.)--Earth and Atmospheric Sciences, Georgia Institute of Technology, 2008. / Newman, Andrew, Committee Member ; Lowell, Robert, Committee Chair ; Germanovich, Leonid, Committee Member.

Thesis (Ph. D.)--Civil and Environmental Engineering, Georgia Institute of Technology, 2008. / Committee Chair: Germanovich, Leonid; Committee Co-Chair: Lowell, Robert; Committee Member: Di Iorio, Daniela; Committee Member: Huang, Haiying; Committee Member: Rix, Glenn; Committee Member: Xu, Wenyue.

Thesis (Ph. D.)--University of Washington, 2008. / Vita. Includes bibliographical references (leaves 131-141).

Thesis (MTech (Oceanography))Cape Peninsula University of Technology, 2010 / The current dynamics along the Tsitsikamma coast is described from a combination of acoustic current measurements. satellite-tracked surface drifters and underwater temperature recordings made between November 2006 and March 2008. The Tsitsikamma coast is largely a Marine Protected Area (MPA) that protects a rich marine biodiversity. The nearshore currents are important in the dispersal of eggs and larvae of many marine species. including the paralarvae of the commercially caught chokka squid. LoNgo reynaudii. Changes in the environment, including the currents. can affect the successful recruitment of chokka squid, and can bring about large annual fluctuations in biomass that creates economic uncertainty in the squid fishery. Results confirm the existence of a predominantly alongshore current off the Tsitsikamma coast. At Middelbank eastward flow was slightly dominant, with a percentage occurrence of 58% vs. 41% westward flow near the surface. The percentage eastward flow decreased with depth, with 41% vs. 58% westward flow near the seabed. At Thyspunt westward and eastward flow occurred at near equal percentages. but westward flow was slightly dominant throughout the water column. The alongshore current was strongest near the surface during eastward flow (maximum = 141 crn.s1: average = 27 crn.s '). while westward surface currents were weaker (maximum velocity = 78 cm.s1: average = 19 crn.s1). Current speed generally decreased with depth and opposing surface and bottom currents, associated with a thermal stratified water column, were occasionally recorded. The nearshore flow regime was characterised by frequent barotropic alongshore reversals that occurred year round. An increase in strong eastward episodes, and opposing surface and bottom currents during spring and summer months have implications for the dispersal of squid paralarvae during the summer and winter spawning seasons. In summer, the combination of strong eastward pulses in the current and upwelling at the capes favoured dispersal onto the midshelf of the Agulhas Bank. In winter, alongshore oscillations without the offshore displacement associated with upwelling. restricted offshore dispersal which caused surface particles to be retained inshore. Drifter trajectories show that both the eastward and westward nearshore current can link the inshore spawning grounds with the nursery grounds, offshore on the central Agulhas Bank; and that passive, neutrally buoyant material in the surface layer can reach the vicinity of the cold ridge in as little as eight days. The wind-driven processes of upwelling and coastal trapped waves (CTWs). and the influence of the greater shelf circulation are discussed as possible driving forces of variability in the currents off the Tsitsikamma coast. The occurrence of coastal trapped waves during thermal stratification appears to drive the jet-like, eastward pulses in the current. and results suggest that the propagation of CTWs may regulate and even enhance upwelling and downwelling along the Tsitsikamma coast.

Thesis (Ph. D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2010. / Cataloged from PDF version of thesis. / Includes bibliographical references. / This thesis presents the results of four discrete investigations into processes governing the organic and inorganic chemical composition of seafloor hydrothermal fluids in a variety of geologic settings. Though Chapters 2 through 5 of this thesis are disparate in focus, each represents a novel investigation aimed at furthering our understanding of subsurface geochemical processes affecting hydrothermal fluid compositions. Chapters 2 and 3 concern the abiotic (nonbiological) formation of organic compounds in high temperature vent fluids, a process which has direct implications for the emergence of life in early Earth settings and sustainment of present day microbial populations in hydrothermal environments. Chapter 2 represents an experimental investigation of methane (CH4) formation under hydrothermal conditions. The overall reduction of carbon dioxide (C02) to CH4, previously assumed to be kinetically inhibited in the absence of mineral catalysts, is shown to proceed on timescales pertinent to crustal residence times of hydrothermal fluids. In Chapter 3, the abundance of methanethiol (CH3SH), considered to be a crucial precursor for the emergence of primitive chemoautotrophic life, is characterized in vent fluids from ultramafic-, basalt- and sediment-hosted hydrothermal systems. Previous assumptions that CH3SH forms by reduction of CO2 are not supported by the observed distribution in natural systems. Chapter 4 investigates factors regulating the hydrogen isotope composition of hydrocarbons under hydrothermal conditions. Isotopic exchange between low molecular weight n-alkanes and water is shown to be facilitated by metastable equilibrium reactions between alkanes and their corresponding alkenes, which are feasible in natural systems. In Chapter 5, the controls on vent fluid composition in a backare hydrothermal system are investigated. A comprehensive survey of the inorganic geochemistry of fluids from sites of hydrothermal activity in the eastern Manus Basin indicates that fluids there are influenced by input of acidic magmatic solutions at depth, and subsequently modified by variable extents of seawater entrainment and mixing-related secondary acidity production. / by Eoghan Reeves. / Ph.D.

In order to explain the observed time-dependent salinity variations in seafloor hydrothermal vent fluids, quasi-numerical and fully numerical fluid flow models of the NaCl-H2O system are constructed. For the quasi-numerical model, a simplified treatment of phase separation of seawater near an igneous dike is employed to obtain rough estimates of the thickness and duration of the two-phase zone, the amount of brine formed, and its distribution in the subsurface. For the fully numerical model, the equations governing fluid flow, the thermodynamic relations between various quantities employed, and the coupling of these elements together in a time marching scheme is discussed. The fully numerical model is benchmarked against previously published heat pipe and Elder problem simulation results, and is shown to be largely in agreement with those results. A number of simulation results are presented in the context of two-phase flow and phase separation within the framework of the single pass model. It is found that a quasi-stable two-phase (liquid + vapor) zone at depth below the hydrothermal discharge outlet gives rise to vent fluid with lower than normal seawater salinity. Additionally, it is shown that increasing the spatial extent of the two-phase zone can lower vent fluid salinity. The numerical approach used in this thesis is able to generate salinity patterns predicted by a widely held conceptual model of vent fluid salinity variation, and may be able to explain the vent fluid salinities and temperatures found at the Main Endeavour Vent Field on the Juan de Fuca Ridge, as this approach is able to produce simulated vent fluid salinities that match observed values from the Endeavour Field vents Dante and Hulk.

Continental and submarine hydrothermal systems are commonly found around the world. Similar systems that sustain water or other fluids are also likely to exist in planetary bodies throughout the solar system. Also, terrestrial submarine systems have been suggested as the locations of the first life on Earth and may, therefore, provide indications of where to find life on other planetary bodies. The study of these systems is vital to the understanding of planetary heat transfer, chemical cycling, and biological processes; hence hydrothermal processes play a fundamental role in planetary evolution. In this thesis, three particular types of hydrothermal systems are investigated through the development of mathematical models: (1) terrestrial low-temperature diffuse flows at mid-oceanic ridges (MORs), (2) submarine near-axis convection on Earth, and (3) convection driven by magmatic intrusives on Mars. Model set-ups for all systems include a two-dimensional space with a vertical, hot wall, maintained at constant temperature, located adjacent to a water-saturated porous medium at a lower temperature. By assuming that convection occurs vigorously and within a thin layer next to the hot wall, boundary layer theory is applicable. The models provide steady-state, single-phase estimates of the total heat and mass transfer rates in each scenario over permeability ranges of 10^-14 m² to 10^-10 m² for the submarine systems and 10^-14 m² to 10^-8 m² for the Martian systems. Heat output results derived from the boundary layer model suggest that diffuse flow on MORs contributes 50% or less of heat output to the ridge system, which falls at the low end of observations. For the near-axis model, results found that heat transfer in the hydrothermal boundary layer was greater than the input from steady state generation of the oceanic crust by seafloor spreading. This suggests that the size of the mushy zone evolves with time. Heat output and fluid flux calculations for Martian systems show that fluid outflow adjacent to a single intrusion is too small to generate observed Martian surface features in a reasonable length of time.

Seafloor hydrothermal systems play a key role in Earth s energy and geochemical budgets. They also support the existence and development of complex chemosynthetic biological ecosystems that use the mineral-laden fluids as a source of energy and nutrients. This dissertation focuses on two inter-related topics: (1) the heat output at mid-ocean ridge (MOR) hydrothermal sites, and (2) the hydrothermal response to earthquakes at mid-ocean ridges. The response of mid-ocean ridge hydrothermal systems to seismic and magmatic activity could provide a means of using seafloor observations to assess processes occurring at crustal depths. Three decades of study of the ocean floor have made clear that tectonic/volcanic perturbations and changes in the hydrothermal activity are correlated. Yet, this relationship is still highly misunderstood. In this dissertation, we developed a mathematical model of hydrothermal circulation affected by magmatic and/or tectonic events occurring at depth. We showed that the perturbations they generate need not propagate through the entire upflow zone, as previously suggested, but need only affect the movement of the boundary layers. In this case, the fluid residence time in the discharge zone is on the order of years. The determination of heat output at MOR hydrothermal sites provides important constraints on the physics of these processes. Yet, such measurements are still very limited, available only for ~30 sites out of the ~10^3 estimated worldwide. This dissertation reports the first measurements of hydrothermal heat output at 9°50' N on the East Pacific Rise (EPR), which has been the most intensively studied site for the past 20 years (~10^2 expeditions). The values we obtained helped constraining the afore-mentioned mathematical model, which was tested based on the March 1995 microearthquake swarm near 9°50' N, EPR. Our results showed that the current interpretation based on a thermal cracking episode at the bottom of the upflow zone, may be incorrect. We argue that a diking scenario better explains the seismic and temperature data, while being consistent with the mechanics of inflation of the axial magma chamber in the 9°50' N, EPR area between two major eruptions, in 1991 and 2006.