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Sno2 based oxide systems: synthesis, material science and sensing properties as a function of surface hydroxylsPavelko, Roman G. 22 March 2010 (has links)
The thesis is dedicated to the synthesis, comprehensive material science and some sensing properties of SnO2-MetOx oxide systems (where MetOx are IVB and IIIB metal oxides). The study was performed in comparison with blank SnO2, and SnO2 doped with noble metals (Pd, Pt, Rh and their binary mixtures). Results of 8 ex-situ (TEM, HRTEM, XRD, FTIR, UV-Vis, BET, XPS and element analysis), 5 in-situ (TGA, MS-analysis, DRIFT, TXRD, TPR) techniques and sensing properties characterization (DC measurements as a function of temperature and gas composition) are discussed regarding surface chemistry of SnO2 sensing phenomenon. The special attention is paid to the role of surface hydroxyls in the processes related with conductivity change of semiconductor adsorbents upon hydrogen chemisorption and oxidation in dry and humid air. / Los principales objetivos de la presente investigación fueron la síntesis de las sistemas oxídicos SnO2-MetOx (donde MetOx corresponde a los óxidos de grupos IVB y IIIB), el estudio extensivo de sus propiedades fisicoquímicas y sus propiedades como sensores de gases. La investigación se ha basado en la comparación de estos materiales con el SnO2 puro y el SnO2 dopado con metales nobles (Pd, Pt, Rh y sus combinaciones binarias). Resultados de 8 estudios ex-situ (TEM, HRTEM, XRD, FTIR, UV-Vis, BET, XPS y MS-análisis de elementos), 5 estudios in-situ (TGA, MS-analysis, DRIFT, TXRD, TPR) y la caracterización de los sensores de gases (conductividad de los materiales semiconductores en función de la temperatura y los componentes de los gases compuestos) se analizan considerando las reacciones químicas superficiales del SnO2. Se ha prestado una especial atención en la participación de los grupos hidroxilo superficiales en el mecanismo de cambio de conductividad del adsorbente semiconductor durante la quimisorción u oxidación del hidrógeno en el aire seco o húmedo.
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The application of tetrakis(dimethylamino)ethylene chemiluminescence in characterization of the surface properties of metal oxides and reversed microemulsion systemsHuang, Chien-Chang January 1900 (has links)
Doctor of Philosophy / Department of Chemical Engineering / Keith L. Hohn / To characterize surface properties by current techniques, metal oxides typically have to be pre-treated at high temperature to remove surface absorbents. Therefore, a new low temperature method which can provide information on the surface chemistry is desired. In this work, the surface properties of metal oxide samples were studied by tetrakis(dimethylamino)ethylene (TDE) chemiluminescence (CL). This chemiluminescent method was also employed in probing the properties of reversed microemulsions.
It was found that the emission intensity vs. reaction time curve (I[subscript]t) of catalyzed TDE CL on MgO was affected by the distributions and types of surface hydroxyl groups. Isolated hydroxyls with lower coordination were found to have higher catalytic reactivity for the emission of TDE CL. Although hydrogen bonded hydroxyls also catalyze the TDE oxidation reaction, the influence on the light emission was negative. Because the properties of surface hydroxyls are associated with specific orientations of adjacent ions, information on surface hydroxyls can provide information about some general surface characteristics of a metal oxide.
When characterizing surface hydroxyls on Al[subscript]2O[subscript]3 by TDE CL, it was found that the catalytic reactivity of isolated hydroxyl groups is strongly associated with the stretching frequency of isolated hydroxyl. The stretching frequency of an isolated hydroxyl group is related to the modification of the adjacent ions and the coordination of the isolated hydroxyl. The results showed that the blue-shifts in the stretching frequencies of isolated hydroxyls led to increases in the catalytic reactivity of Al[subscript]2O[subscript]3 surfaces for the emission of TDE CL.
TDE CL was further applied in characterizing the surfaces of other metal oxides and chemically grafted Al[subscript]2O[subscript]3. The results indicated that the isolated hydroxyl groups with fewer adjacent ions likely have higher affinity for the binding of grafting agents. Higher emission intensities were obtained from catalyzed TDE CL on metal oxides featuring higher percentages of isolated hydroxyls.
The determination of a surfactant’s critical micellar concentration was accomplished by measuring the decay rate of the emission of TDE CL in a reversed microemulsion system. In this study, the CMC values of non-ionic and ionic surfactants were measured in different non-polar solvents.
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Amélioration d'un champ de force pour la description des bordures de particules argileuses / Improvement of a force field to model the edges of clay particlesPouvreau, Maxime 13 December 2016 (has links)
Le champ de force CLAYFF est largement employé pour modéliser les interfaces de minéraux argileux – et minéraux apparentés – avec une phase aqueuse. Dans les simulations, les particules d’argile sont typiquement représentées par des feuillets semi-infinis, ainsi seules les surfaces parallèles au plan du feuillet (surfaces basales) sont considérées. Cette simplification est valable dans la mesure où ces surfaces sont majoritaires, mais les feuillets d’argile sont en réalité de taille nanométrique et terminés par des surfaces latérales, ou bordures. Ces surfaces peuvent non seulement adsorber les espèces en solution mais sont aussi sujettes aux transferts de proton, et tous les processus physico-chimiques liés à l’acidité de la phase aqueuse se produisent de façon prédominante au niveau des bordures. En ajoutant au champ de force CLAYFF un terme angulaire métal-O‑H dont les paramètres ont été correctement ajustés, les simulations réalistes des interfaces de bordure deviennent possibles.Les paramètres des termes Al-O‑H et Mg-O‑H ont été obtenus à partir de calculs DFT sur des modèles structuraux du bulk, de la surface basale et de la bordure de la gibbsite Al(OH)3 et de la brucite Mg(OH)2, dont les feuillets peuvent être considérés comme le squelette des minéraux argileux et apparentés. De plus, le terme Si-O‑H a été paramétré à partir d’un modèle de bordure de la kaolinite Al2Si2O5(OH)4. Les propriétés structurales et dynamiques issues de simulations de dynamique moléculaire DFT et classiques basées sur CLAYFF avec et sans terme métal-O‑H ont été comparées. Le champ de force modifié améliore nettement la description des surfaces hydroxylées : l'orientation et la dynamique librationnelle des groupes hydroxyles, les liaisons hydrogène dans lesquelles ils sont impliqués, et la coordination des atomes de métal appartenant aux bordures sont tous plus proches de la réalité. / The CLAYFF force field is widely used to model the interfaces of clay minerals – and related layered materials – with an aqueous phase. In the simulations, clay particles are typically represented by semi-infinite layers, i.e. only surfaces parallel to the layer plane (basal surfaces) are considered. This simplification is acceptable to a certain extent, but clay layers are really nanosized and terminated by lateral surfaces or edges. These surfaces can not only adsorb solvated species but are also subject to proton transfers, and all physico-chemical processes related to the aqueous phase acidity predominantly occur at the edges. By adding to the CLAYFF force field a Metal-O‑H angle bending term whose parameters are correctly adjusted, the simulations of edge interfaces become possible.The parameters of Al-O‑H and Mg-O‑H terms were obtained from DFT calculations on bulk, basal surface and edge structural models of gibbsite Al(OH)3 and brucite Mg(OH)2, whose layers can be considered as the backbones of clay minerals and related materials. In addition, the Si-O‑H term was parametrized from an edge model of kaolinite Al2Si2O5(OH)4 . Molecular dynamics simulations based on DFT and on CLAYFF with and without Metal-O‑H term were performed. The modified force field clearly improves the description of hydroxylated surfaces : the orientation and the librational dynamics of the hydroxyl groups, the hydrogen bonding, and the coordination of metal atoms belonging to the edge are all closer to reality.
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