There are 1,305 Superfund Sites on the United States Environmental Protection Agencies National Priorities List that may require remediation due to the environmental or human health risks associated with subsurface contamination. The contaminants present at these sites and others vary with respect to their physical and chemical properties which dictate the selection of appropriate remediation technologies. In-Situ Thermal Desorption (ISTD) has been studied as a remediation technique for removing many recalcitrant contaminants from soil. ISTD involves passing electrical current through heating elements in wells and removing contaminants through heater/vacuum wells. Heating occurs by heat conduction through the soil. At high temperatures, even relatively low volatility contaminants can be vaporized, removed by vacuum and treated with an on-site recovery system. The main objective of this research was to design and test a laboratory apparatus scaled to a typical ISTD field site and to use it to conduct experiments that could be used to aid in the validation of the STARS numerical simulator. A dimensional analysis was done on the governing energy balance equation to determine the most important scaling groups for the ISTD process so the laboratory experiments could be scaled up to the field. The laboratory apparatus was modeled after a symmetry element of the hexagonal field pattern and a triangular glass prism was constructed for heated sandpack experiments. Temperature data was measured in dry sand, sand partially saturated with water, and sand with both water and PCE added to it. The apparatus was made of glass so that the behavior of the PCE contaminant could be observed when the sand was heated. / text

Mercury is a toxic metal that has been released to the environment through numerous industrial activities. It can exist in various solid, aqueous, and gaseous forms. Volatile Hg(0) is frequently present at the source of a spill where it behaves as a dense non-aqueous phase liquid (DNAPL) contaminant that can change oxidation state and speciation via chemical or biological reactions. Mercury speciation is a key factor determining the mobility, bioavailability, and toxicity of Hg in the environment. Previous research has demonstrated that In Situ Thermal Desorption (ISTD) can be used in various modes to treat soil contaminants including Hg(0). The application of ISTD and other remediation processes must incorporate potential speciation during remediation and assess mobility of any mercury remaining in the soil post-remediation. However, research examining the impact of mercury speciation on ISTD processes is limited. The goals of this research are to investigate the fate and transport of mercury in soils from the source where concentrations are expected to be high to dilute solutions associated with down gradient groundwater, lakes, and rivers. For high concentrations of mercury, equilibrium speciation has been investigated to identify potential transformations at high temperatures consistent with those applied in ISTD processes. A model has been developed that describes mercury speciation over a range of environmental conditions. At low mercury concentrations, competitive Hg(II) adsorption on the soil minerals, goethite and gibbsite, has been evaluated over a range of experimental conditions. Models describing Hg(II) adsorption and aqueous speciation have been developed to provide a tool for predicting the fate and transport of residual mercury after thermal remediation applications. The results of these studies demonstrate that ISTD is feasible, but the off-gas speciation will depend on both the applied temperatures and the soil composition and redox conditions of the site. Pure phase mercury was predicted to be vaporized at temperatures well within the range of typical ISTD processes. The adsorption of trace levels of Hg(II) remaining after ISTD was successfully modeled on goethite and gibbsite using the 1-pK CD-MUSIC model. / text