Youth and varsity football helmets are currently designed similarly and tested to the same impact standards from the National Operating Committee on Standards for Athletic Equipment (NOCSAE). Youth players have differences in anthropometry, physiology, impact exposure, and potentially injury tolerance that should be considered in future youth-specific helmets and standards. This thesis begins by investigating the current standards and relating them to on-field data. The standard drop tests represented the most severe on-field impacts, and the performance of the youth and varsity helmet did not differ. There likely is not a need for a youth-specific standard as the current standard has essentially eliminated the catastrophic head injuries it tests for. As more is known about concussion, standards specific to the youth population can be developed. The second portion of this thesis compares the impact performance between 8 matched youth and varsity helmet models, using linear acceleration, rotational acceleration, and concussion correlate. It was found that helmet performance did not differ between the youth and varsity helmets, likely attributed to testing to the same standard. The final portion of this feature is aimed at advancing STAR for youth and varsity football helmets by including linear and rotational head kinematics. For varsity helmets, an adult surrogate is used for impact tests which are weighted based on on-field data collected from collegiate football players. For youth helmets, a youth surrogate is used and tests are weighted based on data collected from youth players. / Master of Science

This thesis investigated the impact performance of CFRP products within the sports industry. The primary aim of this thesis was to evaluate different configurations, matrix system, and technologies to find the best performing solutions for impact. During this work, an extensive literature study was conducted and various solutions were reviewed. Further on, several tubes were manufactured, impacted and put through a 2 point bending test to find out the residual strength. It was found that TeXtreme R fabrics positively affected the impact performance when compared to conventional fabrics and UD depending on the placement location. Thin plies proved to be better than conventional plies. Newer technologies such as CNT stitching requires further investigation before it can be qualitatively assessed.

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The focus of this work is to investigate the dissolution of MW25, a non-radioactive simulant of UK high-level nuclear waste borosilicate glass, and to predict its performance in the near field of a geological repository. A single-pass flow-through (SPFT) experimental system was used to measure the forward dissolution rates of MW25. Experiments were conducted in two parts. Experiment Part 1 considers the dissolution of the waste glass in deionised water at 40 and 90 oC and circum-neutral pH. Experiment Part 2 considers the dissolution of the waste glass in simulant groundwaters, with similar compositions to groundwaters of Callovo-Oxfordian clay (lower-strength sedimentary rock (LSSR)) and Borrowdale Volcanic Group rocks (higher-strength rock (HSR)), at 40 oC and pH 7. The forward dissolution rate measured in deionised water was found to be approximately one order of magnitude higher at 90 oC than at 40 oC. A similar release was observed for Si, Mg and Al at 40 oC and 90 oC, whereas the B, Cs, Na, Li and Mo showed an order of magnitude increase when the temperature was increased from 40 to 90 oC for low q/S values. The activation energy (Ea) of the reactions shows that the dissolution process is a surface phenomenon. At 90 oC the net effect of the processes governing MW25 dissolution led to the preferential release of boron and alkali metals relative to the release of Si during the transient dissolution stage, accompanied by an increase in the concentration of silicic acid. This suggests that the solution activity of silicic acid at a higher temperature has a weak influence on the release of the mobile elements. The forward dissolution rate measured in LSSR simulant groundwater was found to be slightly higher than that measured in HSR simulant groundwater. The dissolution behaviour of MW25 in both groundwaters is consistent with its behaviour in deionised water at 40 oC, with the dissolution rates of elements increasing as flow rates were increased. However, forward dissolution rates measured in the simulant groundwaters were lower than the forward dissolution rates measured in deionised water under these experimental conditions. This is attributable to the interaction of the components of the simulant groundwaters with the glass, as revealed by post-reaction surface analyses, and a consequential lower alkalinity of the leachates collected in the experiments with simulant groundwater than in deionised water. Reactive chemical transport simulations of waste glass dissolution and radionuclide release in a hypothetical near field were conducted over a time span of a million years with GoldSim. The results showed that enclosing the waste glass in a steel canister covered by a copper canister and emplacing the waste package in a granite host rock is optimal for the long-term isolation of the radionuclides. The waste glass was found to play a significant role in the overall performance of the near field. This study features a new method for estimating the surface area of reacted glass powder more accurately than the geometric surface area estimate, which is the preferred standard method among researchers.