Thermoplastics reinforced with continuous fibers are very promising building materials for the auto industry and consumer electronics to reduce the weight of vehicles and portable devices, and to deliver a high impact tolerance at the same time. Polypropylene is an abundant thermoplastic, and its glass fibers composites make a valuable solution that is suitable for mass production. But the adoption of such composites requires a deep understanding of their mechanical behavior under the relevant loading conditions. In this Ph.D. work, we aim to understand the damage process in continuous glass fiberreinforced polypropylene in detail. We will focus in particular on developing an approach for microscale observation of damage during the out-of-plane loading process and will use these observations for both qualitative and quantitative evaluation of the composite. We will apply our approach to two kinds of polypropylene composites, one of them is specially designed to withstand impact. The comparison between the two types of composites at slow and fast loading cases will shed some light on the effect of the polymer properties on the behavior of composites under out-of-plane loading.

Austenitic stainless steels are frequently used for engineering applications in aggressive environments. Typical sources of component failures are associated with localized attack at grain boundaries, such as intergranular corrosion and stress corrosion cracking. To prevent premature failures, structural integrity assessments are carried out, with the aim of predicting the maximum likelihood of cracking that may develop. For accurate predictions it is of great importance to know the interaction of parameters involved in life-determining processes. This PhD thesis investigates the effect of microstructure and stress on intergranular stress corrosion cracking in Type 302 / Type 304 austenitic stainless steels. High-resolution X-ray tomography has been successfully applied to examine, for the first time in 3-dimensions, in-situ, the interaction between microstructure and crack propagation. The development and subsequent failure of crack bridging ligaments has been observed and correlated with regions of ductile tearing persistent on the fracture surface. These ductile regions were consistent with the morphology of low-energy, twin-type grain boundaries, and are believed to possess the capability of shielding the crack tip. Following this observation, a new grain bridging model has been developed, in order to quantify the effect of static stress and crack bridging on the maximum likely crack length. The model was compared and evaluated with in the literature available percolation-like models. Intergranular stress corrosion tests in tetrathionate solutions have been designed and carried out to validate the new model. The assessment comprised,(i) a thorough examination of the microstructure and analysis parameters employed,(ii) the determination of the degree of sensitisation with subsequent crack path investigations,(iii) the identification of a suitable test system with associated grain boundary susceptibility criteria,(iv) the application of Grain Boundary Engineering (GBE) for microstructure control,(v) statistical crack length assessments of calibrated IGSCC test specimens. The results of these tests showed that the new model successfully predicts the magnitude of stress and the effect of grain boundary engineering on the maximum crack lengths.

The aim of this thesis was to improve the understanding of microstructure in single crystal ferroelectrics. This was achieved through macroscopic testing of Lead Magnesium Niobate – Lead Titanate (PMN-PT) and microscopic observations of Barium Titanate (BT) single crystals. Multi-axial polarization rotation tests on PMN-PT showed a gradual increase in the change in dielectric displacement due to ferroelectric switching as the electric field is applied at increasing angles to the initial polarization direction. A relatively high remnant polarization for loading angle near to 90° suggested that PMN-PT is more polarizable in certain directions. Strains measured in two directions, parallel to the electric field and perpendicular to the electric field, showed a noticeable variation on two opposite faces of the specimen suggesting an effect of local domain configurations on macroscopic behaviour. A micromechanical model gave an insight into the switching systems operating in the crystal during the polarization rotation test. Domain structure in BT was mapped using synchrotron X-ray reflection topography. By making use of the angular separation of the diffracted reflections and specimen rocking, different domain types could be unambiguously identified, along with the relative tilts between adjacent domains. Fine needle domains (width ≈ 10μm) were successfully mapped providing a composite topograph directly comparable with optical micrograph. The domain structure was confirmed using other techniques such as piezoresponse force microscopy and atomic force microscopy/scanning electron microscopy and optical observations on the etched crystal. Results show that combined use of multiple techniques is necessary to gain a consistent interpretation of the microstructure. Finally, domain evolution in BT under compressive mechanical loading was observed in-situ using optical and X-ray diffraction techniques providing a series of images that show ferroelastic transition. The domain configurations influence the switching behaviour and constitutive models that can account for such effects need to be developed. Quantitative and qualitative data presented in this thesis can assist model development and validation.

L'océan Austral est une région clé pour la compréhension de la circulation océanique globale et du climat. C'est dans cette région qu'une large majorité des eaux de la planète est ventilée dans la couche de surface avant d'être réexpédiée dans l'océan profond. Ainsi la couche de surface de l'océan Austral est un élément central pour la compréhension de la circulation océanique planétaire. Malgré leur rôle fondamental dans la circulation océanique globale et dans le climat, la structure et les caractéristiques de la couche de mélange sont encore mal comprises dans la région Antarctique en raison d'un manque important d'observations in-situ. Cependant, le programme international MEOP (2004) a conduit au déploiement de milliers de capteurs hydrologiques sur des éléphants de mer, et offre une couverture spatiale de données inédites couvrant l’ensemble du cycle saisonnier. Dans cette thèse, nous exploitons ce jeu de données ainsi que d'autres plus conventionnels, afin de décrire les propriétés climatologiques et la dynamique de la couche de mélange sous la glace de mer en Antarctique. Les transferts verticaux entre la couche de mélange et l’océan plus profond, associés à la circulation de retournement y sont décrits aux échelles de temps saisonnières et inter-annuelles. Les résultats soulignent et quantifient le rôle primordial des flux d’eau douce, issus de la glace de mer et des précipitations, sur la transformation de masses d’eau sous la banquise. Nos conclusions suggèrent que des changements dans l’intensité de ces flux d’eau douce pourraient directement affecter les budgets de densité de la couche de mélange et impacter la circulation de retournement globale. / The Southern Ocean is a key region for the understanding of the global ocean circulation and for the climate as a whole. In this region, a large majority of the ocean’s water masses are ventilated in the surface layer, before being sent back to the deep ocean. The surface layer of the Southern Ocean is therefore a central element for understanding the global ocean circulation. Despite their fundamental role in the global ocean circulation and climate, the structure and characteristics of the mixed-layer are still poorly understood in the Antarctic Polar Region due to a significant lack of in-situ observations.However, the international MEOP program (2004) has led to the deployment of thousands of hydrological sensors on Elephant Seals and offers a unique spatial coverage of new data that cover the entire seasonal cycle. In this thesis, we exploit this dataset and other more conventional data, to bring a new perspective on this unknown region. Based on these observations, we describe the climatological properties and dynamics of the mixed-layer under Antarctic sea-ice. The vertical transfers between the mixed-layer and the deep ocean, associated with the meridional overturning circulation, and the hydrographic variations of the water masses in the mixed-layer, are described at seasonal and inter-annual time scales. The results highlight the critical role of freshwater fluxes, induced by sea-ice and precipitations, on the transformation of water masses under the sea-ice. Our findings suggest that changes in the intensity of these freshwater fluxes would directly affect the buoyancy budgets of the mixed-layer and impact the large-scale overturning circulation.

Parmi les différents plasmas spatiaux, le vent solaire et les magnétogaines planétaires représentent les meilleurs laboratoires pour l’étude des propriétés de la turbulence. Les fluctuations de densité dans le vent solaire étant faibles, à basses fréquences ces dernières sont généralement décrites par la théorie de la MHD incompressible. Malgré son incompressibilité, l’effet de la compressibilité dans le vent solaire a fait l’objet de nombreux travaux depuis des décennies, à la fois théoriques,numériques et observationnels.Le but de ma thèse est d’étudier le rôle de la compressibilité dans les magnétogaines planétaires(de la Terre et de Saturne) en comparaison avec un milieu beaucoup plus étudié et moins compressible (quasi incompressible), le vent solaire. Ce travail a été réalisé en utilisant des données in-situ de trois sondes spatiales, Cassini, Cluster et THEMIS B/ARTEMIS P1.La première partie de mon travail a été consacrée à l’étude des propriétés de la turbulence dans la magnétogaine de Saturne aux échelles MHD et sub-ionique, en comparaison avec celle de la Terre en utilisant les données Cassini et Cluster respectivement. Ensuite j’ai appliqué la loiexacte de la turbulence isotherme et compressible dans le vent rapide et lent en utilisant les données THEMIS B/ARTEMIS P1, afin d’étudier l’effet et le rôle de la compressibilité sur le taux de transfert de l’énergie dans la zone inertielle. Enfin, une première application de ce modèle dans la magnétogaine de la Terre est présentée en utilisant les données Cluster. / Among the different astrophysical plasmas, the solar wind and the planetary magnetosheathsrepresent the best laboratories for studying the properties of fully developed plasma turbulence.Because of the relatively weak density fluctuations (∼ 10%) in the solar wind, the low frequencyfluctuations are usually described using the incompressible MHD theory. Nevertheless, the effectof the compressibility (in particular in the fast wind) has been a subject of active research withinthe space physics community over the last three decades.My thesis is essentially dedicated to the study of compressible turbulence in different plasma environments,the planetary magnetosheaths (of Saturn and Earth) and the fast and slow solar wind.This was done using in-situ spacecraft data from the Cassini, Cluster and THEMIS/ARTEMISsatellites.I first investigated the properties of MHD and kinetic scale turbulence in the magnetosheathof Saturn using Cassini data at the MHD scales and compared them to known features of thesolar wind turbulence. This work was completed with a more detailed analysis performed in themagnetosheath of Earth using the Cluster data. Then, by applying the recently derived exactlaw of compressible isothermal MHD turbulence to the in-situ observations from THEMIS andCLUSTER spacecrafts, a detailed study regarding the effect of the compressibility on the energycascade (dissipation) rate in the fast and the slow wind is presented. Several new empirical lawsare obtained, which include the power-law scaling of the energy cascade rate as function of theturbulent Mach number. Eventually, an application of this exact model to a more compressiblemedium, the magnetosheath of Earth, using the Cluster data provides the first estimation of theenergy dissipation rate in the magnetosheath, which is found to be up to two orders of magnitudehigher than that observed in the solar wind.

La reconnexion magnétique est un processus omniprésent et fondamental dans la physique des plasmas spatiaux. La "Magnetospheric multiscale mission" (MMS) de la NASA, lancée le 12 mars 2015, a été conçue pour fournir des mesures in-situ permettant d'analyser le processus de reconnexion dans la magnétosphère terrestre. Dans ce but, quatre satellites identiquement instrumentés mesurent les champs électromagnétiques et les particules chargées dans les régions de reconnexion, avec une résolution temporelle cent fois meilleure que celle des missions précédentes. MMS permet, pour la première fois, d'étudier les structures microscopiques associées à la reconnexion magnétique et, en particulier, la région de diffusion électronique. Au niveau de la magnétopause terrestre, la reconnexion magnétique a un rôle chef dans le transport de l'énergie du vent solaire vers la magnétosphère terrestre, en convertissant l'énergie magnétique en énergie cinétique et thermique. Les événements à transfert de flux (FTEs) sont considérés comme l'un des produits principaux et les plus typiques de la reconnexion magnétique à la magnétopause terrestre. Cependant, des structures magnétiques 3D plus complexes, avec des signatures similaires à celles des FTEs, peuvent également exister à la magnétopause. On retrouve, par exemple, des tubes de flux entrelacés qui résultent de reconnexions magnétiques ayant eues lieu à des sites différents. La première partie de cette thèse étudie l'un de ces événements, qui a été observé dans des conditions de vent solaire inhabituelles, au voisinage de la magnétopause terrestre par MMS. Malgré des signatures qui, à première vue, semblaient cohérentes avec un FTE classique, cet événement a été interprété comme étant le résultat de l'interaction de deux tubes de flux avec des connectivités magnétiques différentes. La haute résolution temporelle des données MMS a permis d'étudier en détail une fine couche de courant observée à l'interface entre les deux tubes de flux. La couche de courant était associée à un jet d'ions, suggérant ainsi que la couche de courant était soumise à une compression qui a entraîné une reconnexion magnétique à l'origine du jet d'ions. La direction, la vitesse de propagation et la taille de différentes structures ont été déduites en utilisant des techniques d'analyse de données de plusieurs satellites. La deuxième partie de la thèse fournit une étude complémentaire à la précédente et s'intéresse aux ondes observées autour de la couche de courant. / Magnetic reconnection is a ubiquitous and fundamental process in space plasma physics. The NASA's Magnetospheric Multiscale mission (MMS) launched on 12 March 2015 was designed to provide in-situ measurements for analyzing the reconnection process at the Earth's magnetosphere. In this aim, four identically instrumented spacecraft measure fields and particles in the reconnection regions with a time resolution which is one hundred times faster than previous missions. MMS allows for the first time to study the microscopic structures associated with magnetic reconnection and, in particular, the thin electron diffusion region. At the Earth's magnetopause, magnetic reconnection governs the transport of energy and momentum from the solar wind plasma into the Earth's magnetosphere through conversion of magnetic energy into kinetic and thermal energies after a rearrangement of magnetic field lines. Flux Transfer Events (FTEs) are considered to be one of the main and most typical products of magnetic reconnection at the Earth's magnetopause. However, more complex 3D magnetic structures with signatures akin to those of FTEs might also occur at the magnetopause like interlaced flux tubes resulting from magnetic reconnection at multiple sites. The first part of the work presented in this thesis consisted of the investigation of one of these events that was observed, under unusual and extreme solar wind conditions, in the vicinity of the Earth's magnetopause by MMS. Despite signatures that, at first glance, appeared consistent with a classic FTE, this event was interpreted to be the result of the interaction of two separate sets of magnetic field lines with different connectivities. The high time resolution of MMS data allowed to resolve a thin current sheet that was observed at the interface between the two sets of field lines. The current sheet was associated with a large ion jet suggesting that the current sheet was submitted to a compression which drove magnetic reconnection and led to the formation of the ion jet. The direction, velocity and scale of different structures were inferred using multi-spacecraft data analysis techniques. This study was completed with a plasma wave analysis that focused on the reconnecting current sheet.