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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Analysis of doubly and triply ionised indium

Bhatia, Kuldip Singh January 1969 (has links)
Emission spectra of Indium have been photographed over the spectral range from 340A° (177A° in 2nd order) to 9500A° using the disruptive electrodeless and spark in helium sources. About 4000 lines of Indium have been measured and 36% of these lines are classified as belonging to the spectra of InI,InII, Inlll, InlV and InV. The analyses of Inlll and InlV have been revised and extended to include 4d¹ºns(n=5 to 12), `4d¹ºns(n=5 to 9), 4d¹ºnd (n=5 to 9) and 4d¹ºnf(n=4 to 7). Polarisation theory has been applied to 4d¹ºng(n=5 to 9) and 4d¹ºnh (n=6 to 9) series and the ionization potential deduced from this is reported to be 226191.3 cm⁻¹. The dipole polarizability of the 4d¹º core is estimated to be 3.48a₀³ . Most of the expected terms of 4d⁹ 5s5p and 4d⁹ 5s6s are established for the first time. Some of the levels of 4d⁹ 5s5d are also added as well as some levels from the higher configurations 4d⁹ 5s7s and 4d⁹ 5s6d. In triply ionised Indium the new additions are to the 4d⁹5d, 4d⁹ 6d, 4d⁸5s and 4d⁹6p configurations. Houston's theory of intermediate coupling has been successfully applied to 4d⁹ns (n=5,6 and 7) terms. Tentative values are given to several levels of 4d⁸5s5p and 4d⁹4f terms. The double limit of InlV is calculated from 4d⁹ns series as 461875 cm⁻¹ and 468989 cm⁻¹. Experimental results are compared with the theoretical calculations for some of the configurations of Inlll and InlV. / Science, Faculty of / Physics and Astronomy, Department of / Graduate

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