published_or_final_version / Environmental Management / Master / Master of Science in Environmental Management

Research was initiated to examine the feasibility of removing the majority of 4-PCH from the XSBR latex employed in carpet manufacturing. The reduction of 4-PCH from such latices would lend insight into the control of certain carpet related illnesses.

The research reported in this thesis describes: the prevalence of respiratory symptoms, COPD and cardiovascular problems in rural and urban adults taking account of all major confounding factors; and estimates of exposures, both indoor and outdoor, and assessment of the relationships between measured exposure and health outcomes. A cross-sectional study was conducted in an adult population (16+ years) in Nepal to compare the respiratory and cardiovascular risk of indoor air pollution in a rural population exposed to biomass smoke compared to an urban population using liquefied petroleum gas using an investigator-delivered questionnaire, lung function and blood pressure measurements.  Direct measures of indoor particular exposure (PM_2.5 and CO) and outdoor PM_2.5 were made with other relevant factors obtained by questionnaire. Direct measures of 24-hour indoor PM_2.5were carried out in 245 rural and equal numbers of urban homes. Health outcomes were assessed in 846 rural and 802 urban dwellers.  The main risk factors studied were socio-economic status, smoking, fuel types, stove types, ventilation, BMI, income, ETS and cooking. The result suggests that cooking with biomass is associated with reduced lung function and thus a higher prevalence of COPD in the rural dwellers compared to the non-exposed urban dwellers.  No clear relationship between biomass smoke exposure and cardiovascular endpoints was found although reported cooking with biomass fuel was associated with higher blood pressure and chest pain.  Methodological issues including more invasive assessment of cardiovascular disease will in future studies be important in interpretation of this relationship.

Approximately 3 billion people in developing countries rely on solid fuels for their cooking, heating and lighting needs (Smith 2000). Household air pollution (HAP) from the incomplete combustion of these fuels constitutes the fourth leading risk factor for death and morbidity worldwide, and the number one risk factor for disease burden in some developing nations, including Ghana (Lim et al. 2013; Institute for Health Metrics and Evaluation 2016). While research shows biomass fuel combustion presents a significant global health and environmental burden, no regional, national or global policies have been enacted to reduce fine particulate matter (PM2.5) and black carbon (BC) emissions from cooking with biomass fuels. More data on personal exposures to particulate matter and BC from cooking with biomass are needed across geographic areas to assess whether exposure is mediated by (cultural) cooking customs, practices and behaviors. These data are critical in informing improved cookstove design as well as policies aimed at reducing harmful emissions and exposures from biomass smoke. The overall objective of this proposal is to examine personal exposures to cooking and non-cooking sources of HAP, characterize the elemental composition of the fine particulate matter across two common biomass fuels (charcoal and wood), and assess acute respiratory symptoms in pregnant women cooking with biomass fuels in rural Ghana. Through aerosol monitoring of PM2.5, our goal is to identify and apportion sources of personal exposures borne by cooks in rural Ghana, in order to inform mitigation policies and intervention design to alleviate health burden associated with cooking with biomass fuels. Specifically, in Aim 1 we propose to measure personal exposures and kitchen air concentrations of PM2.5 and BC across cooking locations, (i.e. enclosed, semi-enclosed, outdoor) and assess cooking characteristics (e.g. fuel, kitchen type, ethnicity) as possible determinants of exposure. In Aim 2, we will characterize the elemental composition of personal and kitchen air samples across fuel and kitchen types. These two aims will allow us to assess cooking and non-cooking sources of personal HAP exposure based on air monitoring data, composition of the filters, and survey-based cooking characteristics/demographics. In Aim 3, we propose to characterize the prevalence of adult respiratory symptoms in 1183 pregnant women in the region, and assess associations between personal exposure, measured by personal carbon monoxide (CO), and other cooking and non-cooking determinants of personal exposure, including fuel type, years cooked, kerosene lamp, mosquito coils, and charcoal production.

Since the beginning of the 20th century indoor air has produced distinctive pollution problems. The most critical pollutants in relation to indoor air quality (IAQ) are chemical contaminants which, in the form of volatile organic compounds (VOCs), have been identified as arising mainly from building materials. Conventional solutions such as ventilation systems and bake-out processes have been developed, but the IAQ problem, often reported as sick building syndrome (SBS), still persists. This study set out to establish to what extent VOCs may affect the health of occupants in a particular built environment, and how much architectural design factors, the use of particular building materials, and human activities may contribute to the problem of SBS. A further question was to establish to what extent current attempted solutions to IAQ problems, namely ventilation and bake-out, were in practice effective in a specific built environment. While previous research and attempted solutions have focused on work places as areas of concern for SBS, the problem is especially significant in residential housing and is particularly concentrated in post-disaster public housing (PDPH). For this reason the research was based on the case of a PDPH project in Abuta, Japan. To analyse the separate components of the problem, several distinct studies were undertaken. The level of pollutants in the air was analysed by means of chemical sampling of VOCs in two units of the PDPH, while the a SBS survey and assessment of the residents of the entire project, as well as interviews with the building professionals involved was designed to identify the human causes and effects of the situation. The effectiveness of the attempted solutions to the problem were considered by means of a study of the bake-out procedure, and finally an airflow simulation by computational fluid dynamics (CFD) was conducted to consider the design and ventilation features of the units in relation to IAQ. The study results have indicated that IAQ problems existed after the completion of construction. It was found that certain VOC levels were far above the guidelines, and the health hazard symptoms known for these VOCs matched the SBS symptoms found in participants??? health complaints. Interviews with building professionals involved in the project revealed that the lifestyles of the occupants were not seriously considered in the project design. The results of the airflow simulation also revealed problematic aspects of the planning design, exacerbating rather than limiting the pollution problem as intended. The study concludes with a number of recommendations for taking these inter-related aspects of the problem into consideration in future, so that the health of residents is not adversely affected.

Graduation date: 1998

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Problems associated with instruments used to measure low levels of NO₂ include non-specificity, low sensitivity, and an uncharacterized dependence on environmental conditions. MDA Scientific has recently introduced a continuous colorimetric tape technique (chemcassette) to monitor for pollutant gases. Advantages of this technology include ease of use, fast-response alarm capability, and adaptability to measure different pollutants. This research characterized and compared chemcassette performance for NO₂ with other low-level NO₂ monitoring technologies including the luminox LMA-3 monitor and the EPA reference CSI chemiluminescnt monitor. The test protocol was based on EPA procedures. The chemcassette was found to be sensitive to temperature and relative humidity effects. The chemiluminescent monitor had the best overall performance. The luminox monitor displayed temperature dependence. Variation in stability of the chemcassette optical system, tape paper uniformity, and possible interference from ozone were characterized. (Abstract shortened with permission of author.)

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