No description available.

This thesis presents an analytical method based on classical matrix methods for computing the dynamic response of elastic-plastic multi-storey building frames. The method developed is comparatively simple and is of much use for building frames having large number of storeys. By this method, response of multi-storey build­ings could be calculated on high-speed digital computers of high storage capacity. The computer program developed saves huge storage locations and thus makes it possible to analyze multi-storey frames which till now were con­sidered as very difficult. Dynamic response of a two-storey and six-storey frame are shown to demonstrate the utility of the method. / Thesis / Master of Engineering (ME)

This thesis investigates Raman spectra of novel glasses and their correlation with structure for Raman gain applications. Raman gain for all-optical amplification by fibers depends significantly on the cross section for spontaneous Raman scattering allowing to compare signal strength and spectral coverage. We also investigate the relationship between glass structure and the Boson peak (enhancement of the low-frequency vibrational density of states) and report new inelastic neutron scattering spectra for niobium-phosphate glasses. Polarization resolved Raman spectra of glasses based on tellurite and phosphate formers have been measured from 6 – 1500 cm-1 using an excitation wavelength of 514 nm. The Tellurite glasses exhibit Raman Spectra at least 10 times more intense, are more spectrally uniform and possess spectral bandwidths more than a factor of two wider than fused silica. Assignments of the vibrational bands are presented and the compositional dependence of the spectra is discussed with respect to the molecular structure. Significantly high Boson peaks were found in the frequency range from 30-100 cm-1. The Raman gain curves were calculated from the polarized spontaneous Raman spectra. In particular, they show broad and flat band in the low frequency region (50-400 cm-1) suggesting that these glasses may be useful for Raman gain applications extending to very low frequencies. The inelastic neutron scattering spectra of the niobium-phosphate glasses display a pronounced low-frequency enhancement of the vibrational density of states. By averaging over the full accessible wavevector range we obtain an approximate spectral distribution of the vibrational modes. Through direct comparison with the Raman spectra we determine the Raman coupling function which shows a linear behavior near the Boson peak maximum. Possible mechanisms contributing to the low frequency Raman band such as disorder-induced irregular vibrational states are discussed.

This thesis presents the results of an investigation of a multiple degree of freedom (MDOF) structure with hyperelastic bracing using nonlinear and incremental dynamic analysis. New analytical software is implemented in the investigation of the structure, and the study seeks to investigate the effectiveness of hyperelastic bracing as a seismic protection device. Hyperelastic braces incorporate a new idea of a nonlinear elastic material that gains stiffness as the brace deforms. Structural behaviors of particular concern for an MDOF frame are stability, residual displacement, base shear, and dispersion. The structure is analyzed under two ground motion records of varying content, and for two separate P-Delta cases of varying severity. Two sets of hyperelastic braces are investigated for their influence under the two ground motions and two P-Delta cases. Each scenario is analyzed using nonlinear dynamic analyses to investigate the response histories, and Incremental Dynamic Analysis (IDA) to investigate dispersion and the behavior of specific response measures as ground motion intensity increases. IDA curves are created for interstory drift and base shear for comparison between the two response measures. The research shows that the inclusion of hyperelastic braces in the MDOF frame improves the overall stability of the structure and reduces the amount of dispersion and residual displacement. The hyperelastic braces are shown to give positive performance characteristics while not detrimentally increasing system forces under regular service loads. The results highlight the benefit of the unique stiffening properties of hyperelastic braces as a seismic protection device. / Master of Science

<p> A Matrix Stiffness-Modification Technique has been proposed for the inelastic analysis of ·reinforced concrete frames subjected to short term or sustained loads. To check the applicability of the analytical method, two large scale concrete frames were tested under short-term loads and sustained-loads respectively. In addition, data for twenty-two frame tests from other sources has also been compared with the non-linear analysis. Close agreement has. been observed for all the frames considered. It was further concluded that a conventional elastic matrix method using stiffnesses based on a cracked transformed section of concrete does net yield accurate results, especially in the case of sustained loading conditions. From the method developed, comments can therefore be made on present column design practice. </p> / Thesis / Master of Engineering (MEngr)

This work is the result of two separate lines of study into the family of frustrated rare-earth pyrochlores with ferromagnetic interactions. The first is an examination of Yb2Ti2O7 and Ho2Ti2O7 through small angle neutron scattering (SANS) techniques. The sensitivity to anisotropic ferromagnetic correlations of SANS makes it an ideal tool to investigate the anomalous scattering of Yb2Ti2O7 , and to take a closer look into the low Q region of the spin ice Ho2Ti2O7 , where long range dipolar effects modify magnetic scattering. We show that in Yb2Ti2O7 the ferromagnetic order observed by other researchers coexists with short range HHH correlations to 0.03 K. We identify a new feature in Yb2Ti2O7 , a medium range (on the order of 100 ̊A) ferromagnetic correlation which appears to correlate well with the systems heat capacity anomaly. In Ho2Ti2O7 , we observe isotropic magnetic scattering in the low Q region that correlates to the system heat capacity anomaly. The second research project involves the system Ho2Sn2−xTixO7 with x=0,0.5,1,1.5,2. We use SQUID magnetometry and inelastic neutron scattering to examine the effects of B-site disorder on the spin ice system. We find some discrepancies with previous generation instrument results for the crystal electric field (CEF) Hamiltonian, and find results consistent with our previously hypothesized picture of the effects of B-site disorder on the CEF levels. We also observe increased spin dynamics in the disordered compounds, which is consistent with recent theory work predicting a transition to a quantum spin liquid phase in disordered non-kramers spin ice compounds. / Thesis / Master of Science (MSc)

No description available.

No description available.

A three-dimensional finite element code to analyze coupled thermomechanical deformations of composites has been developed. It incorporates geometric nonlinearities, delamination between adjoining layers, and damage due to fiber breakage, fiber/matrix debonding, and matrix cracking. The three damage modes are modeled using the theory of internal variables and the delamination by postulating a failure envelope in terms of the transverse stresses; the damage degrades elastic moduli. The delamination of adjoining layers is simulated by the nodal release technique. Coupled nonlinear partial differential equations governing deformations of a composite, and the pertinent initial and boundary conditions are first reduced to coupled ordinary differential equations (ODEs) by the Galerkin method. These are integrated with respect to time with the Livermore solver for ODEs. After each time step, the damage in an element is computed, and material properties modified. The code has been used to analyze several static and transient problems; computed results have been found to compare well with the corresponding test results. The effect of various factors such as the fiber orientation, ply stacking sequence, and laminate thickness on composite's resistance to shock loads induced by underwater explosions has been delineated. / Ph. D.

[ES] En esta tesis se realiza un estudio de acidez de zeolita LTA con la relación Si/Al 5 y 40 utilizando la técnica de dispersión inelástica de neutrones (INS) en combinación con otras tecnicas como la modelización computacional y la espectroscopía de resonancia magnética nuclear (RMN). Las zeolitas son aluminosilicatos altamente cristalinos que forman parte de un grupo importante de los materiales funcionales. Las zeolitas son extremadamente útiles como catalizadores para muchas reacciones importantes con moléculas orgánicas. Las más importantes son craqueo, isomerización y síntesis de hidrocarburos. Las propiedades catalíticas de una zeolita dependen principalmente de su acidez y ésta depende de tres factores: el número totál de los sitios ácidos, sus fuerzas individuales y su localización individual, estando estos tres factores relacionados. Los parámetros geométricos definidos por localización de los sitios ácidos (es decir, la longitud y los ángulos de enlaces entre los átomos alrededor del sitio ácido) contribuyen de una manera importante a la fuerza ácida. En la literatura hay muchos trabajos de estudios de acidez en zeolita utilizando la espectrometría infrarroja (IR), sin embargo, con esta técnica es imposible medir las vibraciones de flexión (bending modes, 200-1200 cm-1), las bandas más sensibles al entorno local de los centros ácidos, ya que estas bandas se superponen con las bandas de vibración de la red de zeolite (300-1800 cm-1). En esta tesis se realiza un estudio de acidez utilizando la tecnica de INS, que nos permite medir principalmente los modos de vibración de los átomos de H y también nos permite medir todas las bandas de vibración (incluido el bending). Este estudio muestra que la combinación de la alta calidad de las muestras y la sensibilidad del instrumento utilizado permite detectar con alta precisión los sitios ácidos y obtener la información sobre su posición que a su vez nos perimte obtener la posición de los átomos de Al. Con el fin de interpretar los espectros INS se ha realizado un estudio computacional (cálculos ab-initio) con el objetivo de comparar los espectros cálculados con los resultados experimentales y definir el modelo que reproduce la posición mas probable de los centros ácidos en la muestra. / [CA] En aquesta tesi es realitza un estudi d'acidesa de zeolita LTA amb la relació Si / Al 5 i 40 utilitzant la tècnica de dispersió inelastica de neutrons (INS) en combinació d'altres tècniques com la modelització computacional i la espectroscòpia de ressonància magnètica nuclear (RMN ). Les zeolites són aluminosilicats altament cristal·lins que formen part d'un grup important dels materials funcionals. Les zeolites són extremadament útils com a catalitzadors per a moltes reaccions importants amb molècules orgàniques. Les més importants són craqueig, isomerització i síntesi d'hidrocarburs. Les propietats catalítiques d'una zeolita depenen principalment de la seva acidesa i aquesta depèn de tres factors: el nombre total dels llocs àcids, les seves forces individuals i la seva localització individual, estant aquests tres factors relacionats. Els paràmetres geomètrics definits per localització dels llocs àcids (és a dir, la longitud i els angles d'enllaços entre els àtoms al voltant del lloc àcid) contribueixen d'una manera important a la força àcida. En literatura hi ha molts treballs d'estudis d'acidesa en zeolita utilitzant l'espectrometria infraroja (IR), però és impossible mesurar les vibracions de flexió (bending modes, 200-1200 cm-1) amb aquesta tècnica ja que aquestes bandes es superposen amb les bandes de vibració de la xarxa de zeolita (300-1800 cm-1). La tècnica de dispersió inelastica de neutrons (Inelastic neutron scattering) ha estat utilitzada per estudiar l'acidesa de la zeolita LTA amb diferents relacions Si / Al (per tant diferents c.ontinguts de H en la zeolita). En aquesta tesi es realitza un estudi d'acidesa utilitzant la tècnica de INS, que ens permet mesurar principalment els modes de vibració dels àtoms d'H i també ens permet mesurar totes les bandes de vibració (inclòs el bending). Aquest estudi mostra que la combinació de l'alta qualitat de les mostres i la sensibilitat del instrument utilitzat permet detectar amb alta precisió els llocs àcids i obtenir la informació sobre la seva posició que en el seu lloc ens perimte obtenir la posició d'Al. Per tal de interpretar els espectres INS s'ha realitzat un estudi computacional (càlculs ab-initio) amb la comparació dels espectres calculats amb els resultats experimentals. / [EN] This thesis is dedicated to the study of acidity of LTA zeolites with Si/Al ratios 5 and 40 by using the technique of inelastic neutron scattering (INS) in combination with other techniques such as computational modeling and nuclear magnetic resonance (NMR) spectroscopy. Zeolites are crystalline and microporous aluminosilicates which form one of the most important groups of functional materials. Zeolites are widely used as solid acid catalysts for the wide range of important processes regarding organic molecules. The most important are cracking, isomerization reaction and synthesis of hydrocarbons. The catalytic properties of a zeolite depend strongly on its acidity, and this in turns depends on: the total number of acid sites, their individual strength, and their individual location. These three factors are strongly correlated. Geometric parameters that are defined by the location of the acid site (i.e., bond angles and lengths around the acid site) make a remarkable contribution to the acid strength. There are several studies, found in literatures, typically done by Infrared (IR) or Nuclear magnetic resonance (NMR) technique and dedicated to acidity of zeolites. However, the hydrogen bending modes (200-1200 cm-1), which are found to be more sensitive to local environment, cannot be observed by this technique, since these bands overlap with strong bands of the vibrations of zeolitic framework (300-1800 cm-1). INS technique used in this study allows to detect the bands of vibrations of hydrogen atoms in zeolites (including bending modes). Moreover, this study shows that the combination of an extremely high quality of the samples and the sensitivity of the instrument allows to detect with high precision the acid sites of both high-silica and low-silica zeolites and obtain information about their position. This in its turn gives us the possibility to obtain the aluminium location in zeolites. In order to fully understand the INS spectra we performed ab-initio calculations that allow to interpret the experimental bands and choose a structural model that reproduces the probable location of acid sites in the sample. / Lemishko, T. (2019). Inelastic neutron scattering study of Brønsted acidity in LTA zeolite [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/119966