The use of communication networks in digital control systems introduces stability and reliability concerns. Standard reliability and safety assessment methods need further modification to accommodate the issue in the reliability assessment of networked control systems. In this thesis, it is demonstrated that the Dynamic Flowgraph Methodology (DFM) can be extended to model networked control systems. The modelling of the communication network influence on the performance of the control system is presented. The areas that can affect the reliability of the control system are identified using the methodology. The thesis also presents the application of the DFM to a nuclear-based thermochemical water splitting process for hydrogen production, the Copper-Chlorine (Cu-Cl) cycle. The architecture of a networked control system and configuration of instrumentation and control systems for the hydrogen production plant are proposed in the thesis. / UOIT