Mixes with lower water to cement (w/c) ratio and supplementary cementing materials produce strong and durable concrete. The consequence of lowering w/c is an increase in autogenous shrinkage (AS), which contributes to concrete cracking. Internal curing (IC) is shown to mitigate AS, however improper dosing of IC material can negatively affect the concrete properties. The effectiveness of IC material, such as superabsorbent polymer (SAP), depends on the 1) amount of water stored, 2) particle distribution, and 3) ability to deliver water. The objective of this research is to quantify the in-situ efficiency of SAP by investigating its effect on the cement chemical reaction using non-destructive testing methods, specifically isothermal calorimetry and nuclear magnetic resonance (NMR). IC was tested with varying quantities of SAP in plain cement paste using white Portland cement and three w/c (0.30, 0.32, 0.35). Overdosing of the SAP material was found to significantly affect the hydration reaction and reduce the efficiency of the material. The initial porosity of the paste influences the ability of IC to provide water. However, the extra porosity provided by SAP needs to be considered when calculating the degree of hydration. Particle agglomeration occurs when the mass of SAP to IC water is greater than 5% and is the main factor causing loss of efficiency. A new geometric model was developed to estimate the SAP distribution within the cement paste. The model employs the SAP absorption determined by NMR and assumes that the SAP particles are spherical, of equal diameter, and individual particles absorb the same amount of pore solution. The results reveal that particle spacing increases with agglomeration and reduces the IC efficiency. A hybrid 1-D finite element transient flow model was developed to reverse engineer the effective diffusion coefficient from the NMR water distribution. The gel solid volume fraction and its impedance to water transfer were accounted for through the cement degree of hydration and tortuosity factor, respectively. Model results reveal that the effective water diffusion coefficient depends on w/c, gel volume fraction, and tortuosity once the cement gel fractions start to connect, i.e., after 20% cement degree of hydration. The diffusion length quantifies the distance water can transfer from the SAP to the cement paste. / Thesis / Doctor of Philosophy (PhD)