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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.

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1

Hypervalent diorganoantimony(III) fluorides via diorganoantimony(III) cations – a general method of synthesis

Preda, Ana Maria, Raţ, Ciprian I., Silvestru, Cristian, Lang, Heinrich, Rüffer, Tobias, Mehring, Michael 18 February 2016 (has links) (PDF)
Novel diorganoantimony(III) fluorides containing ligands with pendant arms, R2SbF (5), (R)PhSbF (6) [R = 2-(2′,6′-iPr2C6H3N[double bond, length as m-dash]CH)C6H4], R′′2SbF (7) and (R′′)PhSbF (8) [R′′ = 2-(Me2NCH2)C6H4], were prepared via the ionic derivatives [R2Sb]+[PF6]− (1), [(R)PhSb]+[PF6]− (2), [R′′2Sb]+[SbF6]− (4) and [(R′′)PhSb]+[SbF6]− (obtained in situ) by treatment with [Bu4N]F·3H2O. The ionic species used as starting materials as well as [R′2Sb]+[PF6]− (3) [R′ = 2-(2′,4′,6′-Me3C6H2N[double bond, length as m-dash]CH)C6H4] were obtained from the corresponding bromides or chlorides and Tl[PF6] or Ag[SbF6]. The compounds were investigated by multinuclear NMR spectroscopy in solution, MS and IR spectroscopy in the solid state. The molecular structures of the ionic species 1·2CH2Cl2 and 3·2CHCl3 as well as of the fluorides 5–8 were determined by single-crystal X-ray diffraction. / Dieser Beitrag ist aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
Antimon
Fluorid
Organoantimonverbindungen
Hypervalente Verbindungen
Ionogene Verbindungen
Strukturanalyse
antimony
fluoride
organoantimony compounds
hypervalent compounds
ionic species
structure analysis
ddc:540
Antimon
Hypervalentes Molekül
Strukturanalyse
2

Hypervalent diorganoantimony(III) fluorides via diorganoantimony(III) cations – a general method of synthesis

Preda, Ana Maria, Raţ, Ciprian I., Silvestru, Cristian, Lang, Heinrich, Rüffer, Tobias, Mehring, Michael 18 February 2016 (has links)
Novel diorganoantimony(III) fluorides containing ligands with pendant arms, R2SbF (5), (R)PhSbF (6) [R = 2-(2′,6′-iPr2C6H3N[double bond, length as m-dash]CH)C6H4], R′′2SbF (7) and (R′′)PhSbF (8) [R′′ = 2-(Me2NCH2)C6H4], were prepared via the ionic derivatives [R2Sb]+[PF6]− (1), [(R)PhSb]+[PF6]− (2), [R′′2Sb]+[SbF6]− (4) and [(R′′)PhSb]+[SbF6]− (obtained in situ) by treatment with [Bu4N]F·3H2O. The ionic species used as starting materials as well as [R′2Sb]+[PF6]− (3) [R′ = 2-(2′,4′,6′-Me3C6H2N[double bond, length as m-dash]CH)C6H4] were obtained from the corresponding bromides or chlorides and Tl[PF6] or Ag[SbF6]. The compounds were investigated by multinuclear NMR spectroscopy in solution, MS and IR spectroscopy in the solid state. The molecular structures of the ionic species 1·2CH2Cl2 and 3·2CHCl3 as well as of the fluorides 5–8 were determined by single-crystal X-ray diffraction. / Dieser Beitrag ist aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
info:eu-repo/classification/ddc/540
ddc:540

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