The alloy Mo-3Si-1B (wt%) may have the fracture toughness and oxidation resistance required for use as jet turbine engine blades. Mo-3Si-1B (wt%) forms a three-phase mixture of and #945;-Moss, A15 (Mo3Si) and T2 (Mo5SiB2). It has been observed that at high-temperatures, the A15 and T2 intermetallics form a oxidation resistant borosilicate glass coating. To achieve the proper combination of mechanical and thermal properties, the material must have a molybdenum matrix with a fine dispersion of intermetallics to produce a continuous protective layer. In this project, reactive sintering of molybdenum, Si3N4 and BN powders was used to create a semi-continuous molybdenum matrix with a fine dispersion of the A15 and T2 intermetallics. Sintering of the materials was further enhanced by the use of submicron-sized reactants. X-ray diffraction analysis was used verify the desired phases were formed. It was determined that formation of the A15 intermetallic phases begins as low as 1200?nd formation of T2 begins at 1300? The reactions are complete by 1400? Samples with bulk densities as high as 95% of theoretical were produced. Scanning electron microscopy images reveal a microstructure with dispersed intermetallics in a semi-continuous molybdenum matrix with grain sizes on the order of 1-4 and #956;m. It was found that by varying parameters such as mixing method and heating rates, it is possible to engineer the final microstructure, changing the level of dispersion of the intermetallics and continuity of the matrix.

Thesis (MScEng)--Stellenbosch University, 2014. / ENGLISH ABSTRACT: The main components of a micro gas turbine engine are a centrifugal or mixed-flow compressor, a combustion chamber and a single stage axial-flow or radial-flow turbine. The goal of this thesis is to formulate a design methodology for small axial-flow turbines. This goal is pursued by developing five design-related capabilities and applying them to develop a turbine for an existing micro gas turbine engine. Firstly, a reverse engineering procedure for producing digital three-dimensional models of existing turbines is developed. Secondly, a procedure for generating candidate turbine designs from performance requirement information is presented. The third capability is to use independent analysis procedures to analyse the performance of a turbine design. The fourth capability is to perform structural analysis to investigate the behavior of a turbine design under static and dynamic loading. Lastly, a manufacturing process for prototypes of a feasible turbine design is developed. The reverse engineering procedure employs point cloud data from a coordinate measuring machine and a CT-scanner to generate a three-dimensional model of the turbine in an existing micro gas turbine engine. The design generation capability is used to design three new turbines to match the performance of the turbine in the existing micro gas turbine engine. Independent empirical and numerical turbine performance analysis procedures are developed. They are applied to the four turbine designs and, for the new turbine designs, the predicted efficiency values differ by less than 5% between the two procedures. A finite element analysis is used to show that the stresses in the roots of the turbine rotor blades are sufficiently low and that the dominant excitation frequencies do not approach any of the blade natural frequencies. Finally prototypes of the three new turbine designs are manufactured through an investment casting process. Patterns made of an organic wax-like material and a polystyrene material are used, with the former yielding superior results. / AFRIKAANSE OPSOMMING: Mikro-gasturbiene-enjins bestaan uit 'n sentrifugaal- of ‘n gemende-vloeikompressor, 'n verbrandingsruim en 'n enkel-stadium-aksiaalvloei- of ‘n radiaalvloei-turbine. Die doel van hierdie tesis is om 'n ontwerpsmetodologie vir klein aksiaalvloei-turbines saam te stel. Hierdie doel word deur die ontwikkeling en toepassing van vyf ontwerpsverwante vermoëns nagestreef. Eerstens word 'n tru-waartse-ingenieursproses ontwikkel om drie-dimensionele rekenaarmodelle van die bestaande turbines te skep. Tweedens word 'n metode om kandidaatturbineontwerpe vanaf werkverrigtingsvereistes te verkry, voorgestel. Die derde ontwerpsvermoë is om die werksverrigting van 'n turbineontwerp met onafhanklike analises te evalueer. Die vierde ontwerpsvermoë is om die struktuur van 'n turbinelem te analiseer sodat die effek van statiese en dinamiese belastings ondersoek kan word. Laastens word 'n vervaardigingsproses vir prototipes van geskikte turbineontwerpe ontwikkel. Die tru-waartse-ingenieursproses maak gebruik van 'n koördinaat-meet-masjien en 'n CT-skandeerder om puntewolkdata vanaf die turbine in 'n bestaande mikro-gasturbiene-enjin te verkry. Die data word dan gebruik om 'n drie-dimensionele model van die turbine te skep. Die ontwerpskeppingsvermoë word dan gebruik om drie kandidaatturbineontwerpe vir die bestaande mikro-gasturbiene-enjin te skep. Onafhanklike empiriese en numeriese prosedures om die werkverrigting van 'n turbineontwerp te analiseer word ontwikkel. Beide prosedures word op die vier turbineontwerpe toegepas. Daar word gevind dat die voorspelde benuttingsgraadwaardes van die nuwe ontwerpe met minder as 5% verskil vir die twee prosedures. 'n Eindige-element-analise word dan gebruik om te wys dat die spannings in die wortels van die turbinelemme laag genoeg is, asook dat die dominante opwekkingsfrekwensies nie die lem se natuurlike frekwensies nader nie. Laastens word prototipes van die drie nuwe turbineontwerpe deur 'n beleggingsgietproses vervaardig. In die vervaardigingproses word die effektiwiteit van twee materiale vir die gietpatrone getoets, naamlik 'n organiese wasagtige materiaal en 'n polistireen-materiaal. Daar word bevind dat die gebruik van die wasagtige gietpatrone tot beter resultate lei.