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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Studies in the synthesis of n-butyl strontium

Kuck, John F. R. January 1940 (has links)
1. Strontium does not easily react with n-butyl bromide in ether or benzene to produce an organostrontium compound. Strontium amalgam reacts to give a trace of the butyl mercury compound, perhaps through the formation of an organostrontium compound as intermediate. 2. The conversion, 2BuLi + SrCl₂ = 2LiCl + Bu₂Sr, seems to proceed predominantly to the left, perhaps because of relative solubilities of the lithium and strontium halides in the solvents used. 3. The conversion, Bu₂Hg + Sr = Hg + Bu₂Sr, appears to proceed to a slight extent to the right. So far, this reaction seems to offer the most promise in synthesizing an organostrontium compound. / M.S.

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