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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Experimental determination of the volumetric properties for the system CO₂-CH₄-N₂ at 100-1000 bars and 50-300°C

Seitz, Jeffery Charles 01 February 2006 (has links)
CO₂ CH₄, and N₂ are key volatile constituents of the earth; therefore, thermochemical data on these gas species and their mixtures find application in geochemical modeling of crustal fluids in a wide variety of geologic environments. However, volumetric data for gaseous mixtures are scarce, particularly at high pressures and temperatures. In this study, the volumetric properties of binary and ternary mixtures in the system CO₂-CH₄-N₂ were measured at 100-1000 bars, 50-300°C, using a vibrating-tube densimeter constructed at the Oak Ridge National Laboratory. An isobaric, isothermal flow-through method was employed to obtain a statistically significant number of measurements for the period of vibration at each set of P-T-X conditions. During each experimental session, three well Characterized standard gases (He, N₂ and Ar) were used to calibrate the response of the instrument. Precisions achieved in experimentation were: P, ±0.1 bar; and T, ±0.01 °C. Conservative estimates of accuracy are: P, ±0.2 bar; and T, ±0.05 °C. The uncertainties associated with volumetric determinations derive from counting statistics and vary as a function of the density and composition of the gas mixture. Generally, the uncertainty in volume ranges from ±0.1 to ±0.3 %. / Ph. D.

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