Thesis (M.S.)--Ohio University, June, 2006. / Title from PDF t.p. Includes bibliographical references (p. 63-71)

Dissertation (Ph. D.)--University of Akron, Dept. of Polymer Engineering, 2006. / "May, 2006." Title from electronic dissertation title page (viewed 10/11/2006) Advisor, Erol Sancaktar; Committee members, James L. White, Kyonsuku Min, Darrell H. Reneker, Wieslaw Binienda; Department Chair, Sadhan C. Jana; Dean of the College, Frank N. Kelley; Dean of the Graduate School, George R. Newkome. Includes bibliographical references.

The overall goal of this study is to evaluate the ability of novel nanostructured adsorbent media (NTAs, iron sulfides (FeS2 and FeS)) to remove arsenic, selenium and mercury from ash and scrubber pond effluents. The NTAs aim to enhance arsenic removal from solution compared to conventional adsorbents. The iron sulfides are expected to produce stable residuals for ultimate disposal after removing As, Se and Hg from solution, so that removal of these compounds from wastewaters will not result in contamination of soils and groundwaters. Methods for reliably and economically producing these materials were developed. The synthesized NTAs and iron sulfides were characterized by surface analysis techniques such as XRD, FT-IR, SEM-EDS, TEM, XPS, AFM and N2-adsorption. These analyses indicated that Ti(25)-SBA-15 has highly ordered hexagonal mesopores, MT has interparticle mesopores, pyrite (FeS2) forms crystalline, nonporous rectangular nanoparticles (<500 nm), and mackinawite (FeS) forms amorphous, nonporous nanoparticles (<100 nm). Kinetic and equilibrium tests for As(III, V) removal were conducted with NTAs over a range of pH (4, 7, 9.5). The rates of arsenic uptake were very fast and followed a bi-phasic sorption pattern, where sorption was fast for the first 10 minutes, and then slowed and was almost completed within 200 minutes. Distinct sorption maxima for As(III) removal were observed between pH 7 and pH 9.5 for MT and between pH 4 and pH 7 for Ti(25)-SBA-15. The amount of As(V) adsorbed generally decreased as pH increased. In addition, a surface complexation model (SCM) based on the diffuse layer model (DLM) was used to predict arsenic adsorption envelopes by NTAs under various environmental conditions. The SCM for As(III, V) adsorption by NTAs demonstrated the role of mono- and bidentate surface complexes in arsenic adsorption. A batch reactor system was employed in an anaerobic chamber to conduct experiments to characterize both the removal of As, Se, Hg from solution and their subsequent reactions with iron sulfides. Experiment variables for removal experiments included: contaminant valence state (As(V), As(III), Se(VI), Se(IV), Hg(II)); adsorbent/reactant type (FeS, FeS2); adsorbent/reactant concentration; pH (7, 8, 9, 10); and competing ion (SO42-) concentration (0, 1, 10 mM). Experimental variables for reaction experiments were reaction time (up to 30 days) at pH 8 and oxidation states of contaminants. In addition, the stability of iron sulfides (FeS2, FeS) combined with target compounds was investigated by measuring the ability of the target compounds to resist release to the aqueous phase after removal. These experiments showed that iron sulfides were good adsorbent/reactants for target contaminants in spite of the presence of sulfate. This was particularly true at intermediate concentrations of target compounds. The experiments also demonstrated that iron sulfides interacted with target contaminants in such a way to improve their resistance to being released back to solution as pH was changed. Therefore, this study demonstrates the ability of novel nanostructured adsorbent media to remove arsenic, selenium and mercury from ash and scrubber pond effluents and the ability of iron sulfides to produce residuals that are stable when disposed in landfills.

Nanowire structure plays an important role in the development of nanotechnology. However, further study shows that the shape of nanowires may not be the ideal morphology for some applications such as solar cells and sensors. Thus, the purpose of this thesis is to find a low cost and high yield approach to the synthesis of other morphologies of nanostructures in order to further improve the performance of these nanodevices. To this end, a chemical approach has been extended to the synthesis ZnO nanocones and platelets. With UV illumination, the synthesis of ZnO nanocones was achieved on GaN films on sapphire and gold films on silicon substrates. Both TEM and XRD results show that as-grown ZnO nanocones are single crystals. The formation of ZnO nanocones could be explained by the absorption process of photons. The UV light induced thermal gradient modifies the heat distribution as well as the reagent transport. The chemical reaction system is kinetically limited and results in ZnO nanocones. If the UV light is blocked, the ZnO nanowires result. In addition, the density of ZnO nanocones is higher than ZnO nanowires grown without UV illumination. By this chemical approach, ZnO platelets could also be obtained on GaN films deposited by PLD, whose c-axis is parallel to the surface of the substrate. The diameters and the thickness of the platelets depend on the quality and thickness of GaN film. TEM results illustrate that the obtained ZnO platelets are single crystals grown along the <0 1 1 0> direction within the {0 0 0 1} planes. Relative growth rates of various facets were altered by the presence of [1 0 0] textured GaN film. The suppression of the growth along c axis can also be achieved by citrate anions as a structure-directing agent to adsorb selectively on ZnO basal planes. Electrical measurement shows that the resistance of ZnO platelets is about 20-40 GΩ¸ and it is higher than that of ZnO nanowires. Piezoelectric potential calculation results also indicate that the piezoelectric potential is higher than for ZnO nanowires with the same external applied stress. These procedures and results demonstrate an easy and low cost way to fabricate ZnO nanocones and platelets, which may aid the utilization of nanostructures in solar cells, sensors and other applications to further improve their performance.

Thesis (Ph. D.)--Lehigh University, 2000. / Includes vita. Includes bibliographical references (leaves 127-134).

Thesis (Ph. D.)--University of Hong Kong, 2009. / Includes bibliographical references (leaves 138-139). Also available online.

Thesis (M.S.)--West Virginia University, 2001. / Title from document title page. Document formatted into pages; contains vii, 44 p. : ill. (some col.). Vita. Includes abstract. Includes bibliographical references (p. 35-37).

Thesis (Ph. D.)--Rutgers University, 2008. / "Graduate Program in Physics and Astronomy." Includes bibliographical references (p. 130-135).

Thesis (Ph. D.)--Lehigh University, 2001. / Includes bibliographical references and vita.

Thesis (Ph.D.)--Drexel University, 2009. / Includes abstract and vita. Includes bibliographical references (leaves 222-238).