Authigenic clays are potential proxies for paleoclimate change when formed under saline conditions. Between 1.9 -1.7 mya, Olduvai was a closed-hydrologic basin into which Al- and Fe- rich detrital clays were transported from surrounding soils. Authigenic Mg-rich smectite formed within the basin due to chemical alteration in alkaline and saline conditions. 40 samples were chosen from a stratigraphic section in the center of the paleolake and analyzed to characterize the geochemical facies of the material using XRD, EMPA, and FTIR. ~70% of samples were Mg-rich with clay d060 XRD peaks between 1.506-1.523Å. EMPA indicated (Al2O3 + Fe2O3)/MgO ratios ranged from 0.2-4.8, 21 had ratios >1.0, indicating higher (Al2O3 + Fe2O3) content. These clay data correlated with bulk XRF data, indicating diagenetic controls on bulk composition. Therefore, bulk geochemistry can potentially indicate paleoclimate change when influenced by Mg-rich phyllosilicate formation.

West Reflex Lake is a hypersaline lake in the Canadian Great Plains. The lake contains four types of shoreline carbonate structures: isolated pinnacles, bioherms (aggregates of pinnacles), laminated coatings, and beachrock. This study investigates the processes of formation of West Reflex Lake’s shoreline carbonates. A variety of petrographic and geochemical techniques were used to characterize the texture, mineralogy, and chemistry of the carbonates. The shoreline carbonates formed as a result of biotic and abiotic precipitation at the site of saline springs that supply Ca2+ to the lake. Evidence for biologically-influenced precipitation includes strong epifluorescence, presence of micrite cements, and abundance of microbial filaments. Abiotically-precipitated cements formed due to groundwater inflow. The isolated pinnacles and bioherms formed as a result of groundwater percolating through a framework of microbial filaments, whereas the laminated coatings formed as a result of calcification of coherent microbial mats adhering to a substrate. / May 2017

Sediment accumulated in lakes stores valuable information about past environments and paleoclimatological conditions. Cores previously obtained from Saint Albans Bay, located in the Northeast Arm of Lake Champlain, VT record the transition from the Champlain Sea to Lake Champlain. Belrose (2015) documented the presence of a peat horizon separating the sediments of the Champlain Sea from those of Lake Champlain. Initially, this layer was thought to comprise the transition from the marine environment of the Champlain Sea to a freshwater wetland. However, based on the results from this study, the transition between marine and freshwater conditions is thought to be represented by an erosional unconformity, indicative of a lowstand at the end of the Champlain Sea period. For this study, five additional cores were collected from Saint Albans Bay along a transect following the long axis of the bay moving into progressively deeper water. These cores better constrain the spatial extent, thickness and age variability of the peat layer within the bay and allow us to better understand the environmental conditions that preceded the period of peat deposition. In each of the cores there is evidence of sediment reworking in the uppermost Champlain Sea sediments, indicated by the presence of coarse-grained sediment, which is suggestive of a lowstand at the end of the Champlain Sea period before the inception of Lake Champlain. This coarse-grained layer is immediately overlain by a thick peat horizon. The widespread occurrence of the peat layer points to a large wetland that occupied the entire inner portion of Saint Albans Bay, and lake level ~ 9 m lower than at present during the Early Holocene. Based on radiocarbon dating, this paleo-wetland existed in Saint Albans Bay from ~ 9,600-8,400 yr BP. The development of this wetland complex is time transgressive, reflecting rapidly increasing lake level during the Early Holocene. This hypothesis is supported by the basal peat radiocarbon dates, as well as by the composition of plant macrofossils recovered from the peat horizons. The shift from peat deposition to fine-grained, low organic content lacustrine sedimentation is believed to have occurred at ~8.6-8.4 ka and is likely the result of continued isostatically driven lake level rise coupled with a changing climate. Although it was not its primary focus, this study also seeks to address the variations in sediment composition in the Lake Champlain sections of the cores. Evidence from the Lake Champlain record in Saint Albans Bay indicates that there were notable fluctuations in sedimentation, which were likely linked to both climatic variations and a change in the morphology of the bay. The rebound in productivity from ~8-5 ka is likely the result of warmer conditions during the Hypsithermal period. An increase in terrigenous sedimentation during this same time suggests a change in the morphology of the bay in which the Mill River delta migrated towards the inner bay. Initially, the cooler conditions of the Neoglacial are reflected in Saint Albans Bay by a decrease in organic matter content from ~5-3 ka. During the latter part of the Neoglacial (~3-1 ka), increases in organic matter content and detrital input point to enhanced productivity in response to increased precipitation and runoff from the watershed. The most recently deposited sediments in Saint Albans Bay bear out the legacy of anthropogenic nutrient enrichment of the bay in the form of increased algal productivity.

Tropical wetlands such as the Pantanal help regulate global biogeochemical cycles, but climate change is modifying these environments. Controls on environmental changes can potentially be assessed from ancient, well-dated lacustrine sedimentary records. An integrated field and laboratory approach was undertaken to study the limnogeology of Lake Uberaba in the northern Pantanal, and test whether the lake has preserved a reliable record of environmental change in its strata. This study was designed to understand how the basin accumulates sediment and to assess its sensitivity to hydroclimatic variability. The data showed that modern Lake Uberaba is a highly dynamic, freshwater fluvial-lacustrine basin. Modern lake floor sediments are largely siliciclastic silts, with limited organic matter content and abundant sponge spicules. This sedimentary composition reflects the lake’s open hydrology and well-mixed water column. Limited data from sediment cores indicates that Lake Uberaba may have formed ~1760 CE, following an abrupt transgression over an oxidized floodplain depositional environment. The stratal contact between lacustrine and floodplain deposits suggests the presence of an erosional unconformity, the timing and duration of which remains unknown. The environmental change favoring lake formation appears to be linked to increased effective precipitation provided by the Intertropical Convergence Zone (ITCZ) in the northern Pantanal.

No description available.