The effectiveness of CO₂ injection in the subsurface for storage and EOR are controlled by reservoir quality variation. This study determines the depositional processes and diagenetic alterations affecting reservoir quality of the Lower Tuscaloosa Formation at Cranfield Field. It also determines the origin, time and processes of the grain-coating chlorite and its impacts on reservoir quality. Moreover, by integrating depositional and diagenetic characteristics and by linking them to sequence stratigraphy, the distribution of reservoir quality, could be predicted within a sequence stratigraphic framework. The studied sandstones are composed of medium to coarse-grained, moderately sorted litharenite to sublitharenite with composition of Q76.1F0.4L23.5. Depositional environment of this formation in the Mississippi Interior Salt Basin is interpreted as incised-valley fluvial fill systems. The cross sections and maps at the field show trend of the sandy intervals within channels with a NW-SE paleocurrent direction. During burial of the sandstones, different digenetic alterations including compaction, dissolution, replacement and cementation by chlorite, quartz, carbonate, kaolinite, titanium oxides, pyrite and iron-oxide modified the porosity and permeability. Among these, formation of chlorite coats plays the most important role in reservoir quality. The well-formed, thick and continuous chlorite coatings in the coarser grain sandstones inhibited formation of quartz overgrowth, resulted in high porosity and permeability after deep burial; whereas the finer grain sandstones with the poorly-formed, thin and discontinuous chlorite coatings have been cemented by quartz. The optimum amount of chlorite to prevent formation of quartz overgrowths is 6% of rock volume. The chlorite coats are composed of two layers including the inner chlorite layer formed by transformation of the Fe-rich clay precursors (odinite) through mixed-layer clays (serpentine-chlorite) during early eodiagenesis and the outer layer formed by direct precipitation from pore waters through dissolution of ferromagnesian rock fragments during late eodiagenesis to early mesodiagenesis. In the context of the reservoir quality prediction within sequence stratigraphic framework, the late LST and early TST are suitable for deposition of chlorite precursor clays, which by progressive burial during diagenesis could be transformed to chlorite, and thus results in preserving original porosity and permeability in deep burial. / text

For decades the Upper Cretaceous Lower Tuscaloosa Formation of the U.S. Gulf Coast has been considered an onshore hydrocarbon play with no equivalent offshore deposits. A better understanding of the Lower Tuscaloosa sequence stratigraphic and paleogeographic framework, source-to-sink depositional environments, magnitude of fluvial systems, regional trends in reservoir quality, and structural influences on its deposition along with newly acquired data from offshore wells has changed this decades-long paradigm of the Lower Tuscaloosa as simply an onshore play. The mid-Cenomanian unconformity, underlying the Lower Tuscaloosa, formed an extensive regional network of incised valleys. This incision and accompanying low accommodation allowed for sediment bypass and deposition of over 330 m thick gravity-driven sand-rich deposits over 400 km from their equivalent shelf edge. Subsequently a transgressive systems tract comprised of four fluvial sequences in the Lower Tuscaloosa Massive sand and an overlying estuarine sequence (Stringer sand) filled the incised valleys. Both wave- and tide-dominated deltaic facies of the Lower Tuscaloosa are located at the mouths of incised valleys proximal to the shelf edge. Deltaic and estuarine depositional environments were interpreted from impoverished trace fossil suites of the Cruziana Ichnofacies and detailed sedimentological observations. The location and trend of valleys are controlled by basement structures. Lower Tuscaloosa rivers were 3.8m – 7.8m deep and 145m – 721m wide comparable to the Siwalik Group outcrop and the modern Missouri River. These systems were capable of transporting large amounts of sediment indicating the Lower Tuscaloosa was capable of transporting large amounts of sediments to the shelf edge for resedimentation into the deep offshore. Anomalously high porosity (>25%) and permeability (>1200md) in the Lower Tuscaloosa at stratigraphic depths below 20,000 ft. are influenced by chlorite coating the detrital grains. Chlorite coatings block quartz nucleation sites inhibiting quartz cementation. Chlorite coats in the Lower Tuscaloosa are controlled by the presence and abundance of volcanic rock fragments supplying the ions needed for the formation of chlorite. Chlorite decrease to the east in sediments derived from the Appalachian Mountains. An increase in chlorite in westward samples correlates with an increase of volcanic rock fragments derived from the Ouachita Mountains. / text