Thesis (Ph. D.)--University of Washington, 2008. / Vita. Includes bibliographical references (p. 119-154).

Carbon-doped aluminium oxide, α-Al₂O₃:C, is a ultra-sensitive dosimeter of topical research interest. The aim of this project was to investigate the dynamics of luminesce in this material. The methods of investigation consisted of thermoluminescence and time-resolved optical stimulation. Thermoluminescence measurements provide information on trap distribution and kinetic parameters of the traps involved in luminescence whereas time-resolved optical stimulation is a handy technique in investigation of luminescence lifetimes and provides an insight into the charge transitions between traps and recombination centres. Measurements were made on samples annealed at a nominal temperature of 900⁰C for 15 minutes. The material shows the presence of five thermoluminescence peaks at 37⁰C, 160⁰C, 300⁰C 410⁰C, and 480⁰C at a heating rate of 0.03k/s when irradiated to 6.0 Gy of beta. The main peak at 160⁰C, shows a linear dose response for doses between 0.1 Gy and 10 Gy and then goes sublinear above 10 Gy, the peak at 37⁰C shows a sublinear dose response for doses between 0.1 Gy and 10 Gy and appears to saturate thereafter, whereas the dose response of the peak at 300⁰C goes from linear to supralinear then apparently quadratic behaviour in the dose range of 0.1 Gy to 16.0 Gy. The trap depth of the main peak, that is, its activation energy as determined below the conduction band, has been approximated at 1.3 eV with a kinetic order of approximately 1.2. Time-resolved optical stimulation has been used to investigate luminescence lifetimes. The mean luminescence lifetime obtained for the sample at ambient temperatures is 35.0±1.0 ms. The investigations of the dependence of luminescence lifetimes on measurement temperature show that the material suffers from thermal quenching effects at measurement temperatures above 140⁰C with the activation energy of thermal quenching estimated at 1.045±0.002 eV. Shallow traps i.e. traps lying close to the conduction band, seem to elongate the lifetimes of optically stimulated luminescence in the material at temperatures between 30⁰C - 80⁰C due to charge retrapping. The material exhibits both fading and recuperation of the optically stimulated luminescence signal with storage time.

published_or_final_version / abstract / Earth Sciences / Master / Master of Philosophy

Reconstruction of former Central Asian glaciers extents can provide valuable information about past atmospheric circulation variations. These extents, often marked by terminal moraines, need to be chronologically constrained. Cosmogenic nuclide exposure (CNE) dating is widely used to directly date moraines. In addition, there is increasing interest on using optically stimulated luminescence (OSL) techniques for dating glacial landforms. This thesis focuses on the methodological aspects of directly dating glacial landforms to perform paleoglacial reconstructions in Central Asia, with an emphasis on OSL dating. For OSL dating of sediments from glacial settings, it is important to measure the luminescence signal at the single grain scale, because the sediments are likely affected by partial bleaching due to short light exposure during glacial or glaciofluvial transport. The use of an Electron Multiplying Charges Coupled Device (EMCCD)-based imaging system for single grain OSL measurements would offer larger flexibility in light stimulation and sediment type, compared to the current Single Grain Risø reader. An automated image processing procedure has been developed to compensate for sample carrier displacement over repeated measurements and for attributing pixels to each grain for signal integration when using this imaging system. However, significant cross talk contamination, demonstrated by laboratory and simulation experiments, prohibits accurate single grain luminescence measurements. Preliminary experiments using a basic image processing algorithm show good potential for software correction solutions. Paleoglacial reconstructions conducted in the Altai Mountains, Central Asia, using both CNE and OSL dating demonstrate that luminescence measurements of glaciofluvial sediments performed at the multi-grain scale result in large age overestimates, and that single grain measurements allow for more accurate dating of glacial landforms. However, uncertainties remain that are related to the model used for extracting equivalent doses for well-bleached grains and to fading corrections when using feldspar minerals. The timing of glaciation can be inferred from scattered CNE moraine boulder ages if most of the ages are concentrated within a few thousand years, with only few ages clearly older or younger. Overall, combining CNE and OSL techniques for dating a glacial landform is a powerful approach for producing robust glacial chronologies, despite uncertainties inherent to each technique. Paleoglacial reconstructions from the Altai Mountains indicate Marine Isotope Stage (MIS) 2 and MIS 4/late MIS 5 local Last Glacial Maximums. In Central Asia, in addition to a regional MIS 2 glaciation, previous studies indicate a period of major glacial advances during MIS 3 that is out of phase with global ice volume records. However, most MIS 3 glacial chronologies from Central Asia are based on too few or too heavily scattered CNE data sets, or on OSL or Electron Spin Resonance (ESR) ages for which partial bleaching has not been properly investigated. Hence, at this stage, chronological evidence is insufficient to demonstrate a regional MIS 3 glaciation in Central Asia. Surge-related glacial features identified in the Russian Altai also highlight the importance of conducting detailed geomorphology and sedimentology studies to understand former ice dynamics, which is essential for inferring appropriate paleoclimate information from paleoglacial reconstructions. / <p>At the time of the doctoral defense, the following paper was unpublished and had a status as follows: Paper 4: Manuscript.</p>

Zuni Salt Lake (ZSL) is a large maar in the Red Hill-Quemado volcanic field located in west-central New Mexico in the southwestern USA. Stratigraphic analysis of sections in and around the maar, coupled with optically stimulated luminescence (OSL) and accelerator mass spectrometry (AMS) C-14 dating, indicate that ZSL volcanic activity occurred between similar to 13.4 and 9.9 ka and was most likely confined to a <= 500-year interval sometime between similar to 12.3 and 11.0 ka. The basal volcanic unit consists of locally widespread basaltic ash fallout interpreted to represent a violent or wind-aided strombolian eruption tentatively attributed to Cerro Pomo, a scoria cone similar to 10 km south of ZSL. Subsequent eruptions emanated from vents near or within the present-day ZSL maar crater. Strombolian eruptions of multiple spatter and scoria cones produced basaltic lava and scoria lapilli fallout. Next, a phreatomagmatic eruption created the maar crater and surrounding tephra rim and apron. ZSL eruptions ended with strombolian eruptions that formed three scoria cones on the crater floor. The revised age range of ZSL is younger and more precise than the 190-24 ka 2-sigma age range derived from previous argon dating. This implies that other morphologically youthful, argon-dated volcanoes on the southern margin of the Colorado Plateau might be substantially younger than previously reported.

published_or_final_version / Earth Sciences / Doctoral / Doctor of Philosophy

published_or_final_version / Applied Geosciences / Master / Master of Science

Tian Shan is one of the most important orogenic belts in central Asia. It has been reactivated as a result of the Cenozoic India-Eurasia collision. Dating of the late Cenozoic tectonic deformation of Tian Shan and its piedmonts is important for understanding the mountain building as well as evaluating seismic hazards in the region. This study is focused on the applications of optical dating to the late Quaternary uplift and thrust activity along Manas River, in the northern piedmont of the Tian Shan, China. The sediments on river terraces were dated with optical dating. The elevations were measured with the kinematic global position system (GPS). The results suggest that two phases can be identified according to the significantly different river incision rates. One phase was from ~20 ka to ~4.8 ka, with a much slower incision rate of ~ 2.2 ± 0.6 mm/yr. The other phase was from ~4.8 ka to present, with a faster incision rate of ~ 13.5 ± 0.6 mm/yr. The accelerated incision rate of Manas River was mainly attributed to the tectonic forces, suggesting that the tectonic uplift was significantly intensified since ~4.8 ka in the northern piedmont of Tian Shan. The study region has suffered from multiple thrust activities during the late Quaternary, which led to the intensive deformations of the river terraces. By studying the deformed terraces, I evaluated the timing of the past thrust activities as well as the vertical slip rate of the thrust faults. The results demonstrated that the thrust activity intensified during the late Holocene, as manifested by the more frequent thrust activities and higher vertical slip rates. Both quartz and potassium feldspar can be as dosimeters for optical dating of sediments. However, quartz OSL is sometimes seriously impeded with problems such as very dim signals and insufficient bleaching problems. K-feldspar has attractive advantages over quartz, despite of problem of anomalous fading. K-feldspar was explored in this study, by investigating the relationship between the infrared stimulated luminescence (IRSL) and blue light stimulated luminescence (BLSL) signals. For IRSL and BLSL at 60 °C, it was suggested that most of the IRSL could be bleached by blue light (BL), while the BLSL could only be partially bleached by infrared (IR) stimulation. Besides, the fast and medium components of BLSL were mainly associated with the IRSL. If IR stimulation temperature was raised from 60 to 200 °C, at least two portions of the IRSL signals at 200 °C were observed. One portion could be bleached by BL at 60 °C and the other portion was hardly bleached by BL at 60 °C. Dating of K-feldspar from the various signals provided cross-checking for the reliability of quartz OSL for dating sedimentary samples. / published_or_final_version / Earth Sciences / Doctoral / Doctor of Philosophy

New applications of the optically stimulated luminescence (OSL) dating were carried out with the aim of understanding late Quaternary activities for the Tibetan Plateau. This included studying the slip rate of the Altyn Tagh Fault, northeast Tibetan Plateau, and revealing the environmental changes derived from large inland lake’s evolution, central south Tibet. Two deflected streams across the Altyn Tagh Fault close to Aksay (39°24.572’N, 94°16.012’E) were investigated. Geomorphological analysis suggests that loess covering deflected stream banks has recorded past faulting events. A conceptual model is proposed illustrating the relationship. OSL dating of sixteen loess samples at both streams support the model, suggesting the loess is deposited episodically after fault strikes and subsequent channel wall refreshment. The age and offset indicate a slip rate of 11 ±2 mm/yr for this part of the Altyn Tagh Fault. Another river section near Aksay was also investigated for the slip rate information. Two risers between three terraces are clearly offset; OSL dating of loess covering terrace surfaces yielded terrace ages. Using the upper-terrace age to represent riser displacement duration, the rate is estimated to be 12 ±1 mm/yr. The result suggests that using upper terrace is more suitable in this region. Notably, though, the slow rate is at odds with proposals that assume high-speed extrusion (~23 mm/year) of the Tibetan Plateau being accommodated by the Altyn Tagh Fault. Palaeo-shorelines around the third largest lake in Tibet, Zhari Namco, were for the first time systematically investigated using OSL dating. Twenty-two sediment samples from eleven shorelines indicate that the water level has dropped ~128 m and the lake has undergone stepwise shrinkage since 8.2 ka. Digital elevation model calculation indicates the lake has shrunk from 4605 km2 in size at 8.2 ka to 996 km2 at present, which is equivalent to ~300 km3 of water. This implies a significant reduction in precipitation over the past 8.2 ka, a result of weakening Indian Monsoon or a shift of monsoon circulation path. The result is consistent with other lake-core, ice-core climate proxies and solar insolation changes, implying the dominance of a weakening Indian Monsoon over central Tibet in the Holocene. Using the elevation of the highest shoreline of the four largest lakes in Tibet, the early Holocene Pan-lake hypothesis is proposed for the central Tibet. In addition to these applications of OSL dating, technical studies on sensitivity changes and residual doses have been carried out for potassium rich feldspar (K-feldspar). Recent development of infrared stimulated luminescence (IRSL) signals from K-feldspar has shown great potential for extending the datable range for OSL dating. Sensitivity changes and residual doses of post-IR IRSL and multi-elevated -temperature post-IR IRSL protocols for K-feldspar were studied. A sensitivity decrease is observed after adopting a high temperature IRSL. IRSL signals stimulated at high temperature are found to contain large residual doses. The residual dose rises with stimulation time, suggesting that the initial part of IRSL signals contains more easy-to-bleach signals comparing with the later part. / published_or_final_version / Earth Sciences / Doctoral / Doctor of Philosophy

Sand ramps are widespread but understudied landforms which have the potential to provide detailed palaeoenvironmental information in dryland regions. This thesis investigates the utility of sand ramps as late Quaternary palaeoenvironmental archives by addressing two research questions: (1) What are the main controls on sand ramp formation in southern Africa? (2) What does the sand ramp record tell us about late Quaternary palaeoenvironments in southern Africa? The distribution of sand ramps in southern Africa was surveyed using Google Earth™ and 75 features were identified in southern Namibia. Ten of these sand ramps, and an additional feature from South Africa, were studied in the field. Sediments and morphology were mapped and a total of 64 OSL dates, 96 sediment samples, 10 heavy mineral assemblages and OSL sensitivity data from 8 samples were examined. The distribution of sand ramps suggests formation is dependent on (1) sediment supply, (2) accommodation space, (3) persistent unidirectional wind and (4) a variable semi-arid to arid climate. Chronologies and sediment analyses indicate individual sand ramp accumulation is locally controlled by sediment supply modulated by the availability, and nature, of the accommodation space. Comparison between the Namibian and South African sand ramps suggests considerable regional variation in the factors controlling sediment supply. The Namibian sand ramps show an affinity to local ephemeral river channels. Periods of dated sand ramp activity in multiple features are interpreted as periods of increased regional fluvial activity. Significant activity occurred at ~21-12 ka (with peaks at 21-18.5 ka and 14.5-12 ka), ~8.5-7.5 ka and ~2 ka. Some activity is also indicated at 85-65 ka and 45-35 ka. These results correspond well to regional records. Overall, this study demonstrates that sand ramps can provide palaeoclimatic information on both the local and regional scale but only if a number of caveats are taken into consideration.