The thesis presents xavier, a novel tool-set for model checking of concurrent x86-64 assembly programs, via Partial Order Reduction (POR). xavier{} presents a realistic platform for systematically exploring and analyzing the state-space of concurrent x86 assembly programs, with the aim of detecting bugs via assertion failures in mainstream programs. Recently, a number of state-of-the-art model checking solutions have been introduced to efficiently explore the state-space of concurrent programs, using POR algorithms. However, such solutions are inefficient while analyzing stateful programming languages, such as the x86 assembly language, due to their low level of abstraction. To this end, xavier{} makes two contributions: i) a novel order-sensitivity based POR algorithm, that is applicable to concurrent x86 assembly, ii) an x86 machine-model that can accurately perform relaxed-consistency emulation of concurrent x86 assembly, without the need for any translations. We demonstrate the applicability of xavier{} through an evaluation on several classical mutual-exclusion benchmarks and mainstream benchmarks from the Userspace Read-Copy-Update (URCU) concurrency library, where the benchmarks range from $250-3700$ lines of x86 assembly. The framework is the first that supports systematic model checking of concurrent x86 assembly programs, and the effectiveness of xavier{} is demonstrated by reproducing a concurrency issue of threads accessing intermediate states in the URCU library, which stems from an assumption violation. / Master of Science / Sound verification of multi-threaded programs necessitate a systematic analysis of program state-spaces that result from thread interactions. Consequently, model-checking cite{godefroid1997model, Clarke2018} has been one of the prominent methods used to tackle the verification of multi-threaded programs. However, existing model-checking solutions are inefficient while analyzing stateful programming languages, such as the x86 assembly language, due to the solutions' higher level of abstraction. Therefore, the thesis presents xavier, a novel tool-set and a realistic platform for systematically exploring and analyzing the state-space of mainstream concurrent x86 assembly programs, with the aim of detecting bugs via assertion failures. To this end, xavier{} makes two contributions: i) a novel order-sensitivity based Partial Order Reduction algorithm, which efficiently explores the state space of concurrent x86 assembly, ii) an x86 machine-model that can accurately emulate the execution of concurrent x86 assembly, without the need for any translations. We demonstrate the applicability of xavier{} through an evaluation on several classical mutual-exclusion and mainstream benchmarks from the Userspace Read-Copy-Update (URCU) concurrency library, where the benchmarks range from $250-3700$ lines of x86 assembly. Moreover, we demonstrate the effectiveness of xavier{} by reproducing a concurrency issue in the URCU library, which manifests as a result of an assumption violation.