The Main Zone is dominated by medium – grained, homogeneous gabbronorite, and anorthosites. The plagioclase compositions of the core is ((Na(0.227 – 0.353), K (0.012 – 0.046), Ca (0.651 – 0.777)) Al (1.630 – 1.752) Si (2.183 – 2.345) O8) and at the rim is ((Na (0.189 – 0.371), K (0.005 – 0.108), Ca (0.651 – 0.777)) Al (1.630 – 1.752) Si (2.183 – 2.345) O8). The composition of orthopyroxene is ((Mg (0.660 – 0.808), Fe (0.206 – 0.309), Ca (0.007 – 0.081)) Si (0.960 – 1.037) O3) and the compositions of clinopyroxene is ((Mg (0.229 – 0.678), Fe (0.092 – 0.427), Ca (0.012 – 0.475) Si (0.776 – 1.012) O3. The Mg# and An# varies with depth, where plagioclase increase in concentration the An# increases and the Mg# decreases. The variations in magma compositions are attributed to interlayering of different lithologies which are the result of fractional crystallisation in the magma chamber. This is supported by linear trends of the major and trace element bivariant plots. The magmatic event forming the Main Zone resulted in lateral expansion of the sheet – like magma chamber. The Main Zone formed through two magmas; first magma forming the lower Main Zone and the second magma, intruded the Main Zone at the level of the Pyroxenite Marker, forming the upper Main Zone. Copyright / Dissertation (MSc)--University of Pretoria, 2012. / Geology / unrestricted

Bedrock geology of the East Brookfield quadrangle (EBQ), based on new 1:24000 scale mapping, consists of an interfolded sequence of Rangeley Fm. and Paxton Fm. metasediments, intruded by Early Mississippian tonalitic to granitic orthogneisses and underlain in the western half by folded orthogneisses of unknown age. Pervasive flattening strains have created planar, generally NNE-SSW striking and consistent moderately west dipping foliations. Generally strike-parallel stretching lineations and boudinage structures, with rarer dip parallel stretching lineations, reflect extrusion of CMZ metasediments and orthogneisses with a flattening component. Mapping in the EBQ demonstrates that a transition between deformational mechanisms of the southern Central Maine Zone is located there. Evidence for previously mapped faults was not observed during mapping. Alternatively, map scale folds terminating in the East Brookfield quadrangle likely accommodated the across-strike shortening and repetition of lithologic units of the CMZ during Acadian orogenesis. Aeromagnetic patterns and outcrop data approximate a map scale, east-verging and west-dipping, shallowly north-plunging isoclinal fold consisting of interlayered mafic and felsic gneisses. Constrictional and flattening strains documented in the deformation features of the East Brookfield quadrangle suggest that it is located on/near the eastern margin of the zone of transpression approximated by the Bronson Hill gneiss domes. Outcrop- to meter-scale folds with hinge axes sub-parallel to parallel with regional lineations suggest constrictional deformation in a transpressional regime. Deformation features associated with map-scale folding, extrusion/extension, and flattening of CMZ lithologies in the East Brookfield quadrangle support a regime of transpressional deformation caused by oblique convergence of Avalonian terrane with Laurentia. U-Pb ages and outcrop structural relationships suggest that regional flattening and folding was syn- to late-orogenic in nature and Carboniferous or younger in age. All previous structural fabrics are transposed by late regional flattening. Lithologies of the East Brookfield quadrangle exemplify the nature of the Acadian granulite-facies high, displaying a peak metamorphic assemblage of Crd + Grt + Sil + Kfs that has undergone retrograde reactions to produce Bt + Sil. Retrograde metamorphism and deformation occurred during strike-parallel extrusion of CMZ lithologies. Retrograde minerals define kinematic/shear sense indicators that record an overall top to the NNE or ENE asymmetry on vertical faces and dextral west side north on horizontal surfaces. Progressive deformation of CMZ lithologies through transpressional mechanisms is proposed as an alternative to the sequential development of Acadian deformational features in three separate stages.

Student Number : 0201438A - PhD thesis - School of Geosciences - Faculty of Science / This project focuses on the Upper Critical and Lower Main Zones in the eastern Bushveld Complex, South Africa. Lithological and stratigraphic information show that there are distinct differences at this level between the eastern and western limbs of the complex. Geochemical studies are centred on the Merensky and Bastard Cyclic Units in which the platiniferous Merensky Reef occurs. A major geochemical hiatus occurs in the Bushveld Complex at the level of the platiniferous Merensky Reef, close to the Critical/Main Zone boundary. The origin of this hiatus and its relation to mineralisation has not been fully resolved. Geochemical parameters are investigated that allow minerals in the Merensky and Bastard Cyclic Units to be classified as originating from either Critical or Main Zone magmas. Modelling of element ratios (Ni/Y, Cr/Ni, Cr/Co, Y/Co, Cr/V, Co/V and Cr/MgO) demonstrates the varying reliability of using ratios as geochemcial tools to constrain magma influxes within a chamber. However, it is shown that the Cr/MgO ratio is effective in determining real differences across the Critical/Main Zone boundary that are independent of lithology. In addition, initial Sr isotope ratios for plagioclase are significantly different in Critical and Main Zone rocks. Geochemical data through the Merensky and Bastard Cyclic Units indicate that orthopyroxene that originated from magma with composition like that of the Critical Zone magma sometimes occurs together with plagioclase that originated from Main Zone magma. In detail, in the pyroxenite at the base of the Merensky Unit, both plagioclase and orthopyroxene display Critical Zone signatures, but in the overlying part of the Merensky Cyclic Unit, plagioclase increasingly shows a Main Zone signature, whereas orthopyroxene continues to display a Critical Zone signature. Similarly, in the Bastard pyroxenite, Sr isotopes and absolute Sr in plagioclase display a range of values from Main Zone to Critical Zone, but orthopyroxene consistently displays Critical Zone affinity. These observations of mineral disequilibrium clearly show that the two major minerals in the Merensky and Bastard Cyclic Units were formed from two different, but coexisting, magmas. A model that accounts for this disequilibrium is proposed here. It invokes the influx of Main Zone magma at the level of the base of the Merensky unit that dispalced the Critical Zone magma upward, but the two magmas did not mix. The latter continued to crystallise orthopyroxene which sank through the Main Zone influx, due to its density contrast. These crystals collected on the crystal pile to form the Merensky pyroxenite. The Main Zone magma, into which the cumulus Critical Zone orthopyroxene accumulated, crystallised interstitial plagioclase that had a Main Zone Sr isotopic ratio. Whole-rock, major element geochemical data show that a variable proportion of the plagioclase in both the Merensky and Bastard pyroxenites is cumulus. It is inferred to have accumulated with orthopyroxene and has a Critical Zone initial Sr isotope ratio. Thus the two pyroxenites now yield a mixed Sr isotopic signature of Critical Zone cumulus and Main Zone intercumulus and possibly cumulus plagioclase that varies along strike. Above the two pyroxenites, the Sr signature of the norites and anorthosites of both cyclic units is dominated by cumulus plagioclase from the Main Zone magma. It is concluded that the variations in initial Sr isotope ratios do not result from mixing of magmas, but result from accumulation of orthopyroxene and plagioclase from a higher, isotopically distinct layer of magma into an underlying layer. The Merensky and Bastard Cyclic Units therefore display features of Critical or Main Zone magma characteristics depending upon which chemical parameter is considered. These cycles are therefore classified as a Transitional Unit.