Thesis (Doctor of Engineering in Electrical Engineering)--Cape Peninsula University of Technology, 2017. / Remote sensing provides a way of frequently observing broad land surfaces. The availability of various earth observation data and their potential exploitation in a wide range of socioeconomic applications stimulated the rapid development of remote sensing technology. Much of the research and most of the publications dealing with remote sensing in the solar spectral domain focus on analysing and interpreting the spectral, spatial and temporal signatures of the observed areas. However, the angular signatures of the reflectance field, known as surface anisotropy, also merit attention. The current research took an exploratory approach to the land surface anisotropy described by the RPV model parameters derived from the MISR-HR processing system (denoted as MISR-HR anisotropy data or MISR-HR RPV data), over a period of 14+ years, for three typical terrestrial surfaces in the Western Cape Province of South Africa: a semi-desert area, a wheat field and a vineyard area. The objectives of this study were to explore (1) to what extent spectral and directional signatures of the MISR-HR RPV data may vary in time and space over the different targets (landscapes), and (2) whether the observed variations in anisotropy might be useful in classifying different land surfaces or as a supplementary method to the traditional land cover classification method. The objectives were achieved by exploring the statistics of the MISR-HR RPV data in each spectral band over the different land surfaces, as well as seasonality and trend in these data. The MISR-HR RPV products were affected by outliers and missing values, both of which influenced the statistics, seasonality and trend of the examined time series. This research proposes a new outlier detection method, based on the cost function derived from the RPV model inversion process. Removed outliers and missing values leave gaps in a MISR-HR RPV time series; to avoid introducing extra biases in the statistics of the anisotropy data, this research kept the gaps and relied on gap-resilient trend and seasonality detection methods, such as the Mann-Kendal trend detection and Lomb-Scargle periodogram methods. The exploration of the statistics of the anisotropy data showed that RPV parameter rho exhibited distinctive over the different study sites; NIR band parameter k exhibits prominent high values for the vineyard area; red band parameter Theta data are not that distinctive over different study sites; variance is important in describing all three RPV parameters. The explorations on trends also demonstrated interesting findings: the downward trend in green band parameter rho data for the semi-desert and vineyard areas; and the upward trend in blue band parameters k and Theta data for all the three study sites. The investigation on seasonality showed that all the RPV parameters had seasonal variations which differed over spectral bands and land covers; the results confirmed expectations in previous literature that parameter varies regularly along the observation time, and also revealed seasonal variations in the parameter rho and Theta data. The explorations on the statistics and seasonality of the MISR-HR anisotropy data show that these data are potentially useful for classifying different landscapes. Finally, the classification results demonstrated that both red band parameter rho data and NIR band parameter k data could successfully separate the three different land surfaces in this research, which fulfilled the second primary objective of this study. This research also demonstrated a classification method using multiple RPV parameters as the classification signatures to discriminate different terrestrial surfaces; significant separation results were obtained by this method.