Metal matrix composites (MMCs) of Al - 4 wt.% Cu reinforced with different volumetric fractions of B4C particles were produced by hot pressing. The effect of aging temperature on the age hardening response of the composites was studied and compared with the characteristics exhibited by the matrix alloy. Reinforcement addition was found to considerably affect the age hardening behavior. Detailed transmission electron microscopy and differential scanning calorimetry observations were made to understand the aging response of the composites. The low strain rate and high strain rate deformation behavior of the MMCs were determined utilizing low velocity transverse rupture tests and true armor-piercing steel projectiles, respectively. Increasing the volume fraction of B4C led to a decrease in flexural strength. The flexural strength vs. strain rate plots showed a slight increase in strength followed by a decrease for all samples. The mechanical performance of the composites and the unreinforced alloy were greatly improved by heat treatment. The MMCs were found to be inferior to monolithic ceramics when used as facing plates in armors.

In the course of thermal treatments, materials are usually subjected to continuous heating and cooling cycles during which microstructural evolution and mechanical interactions occur simultaneously at different length and time scales. Modeling of these processes necessitates dealing with inherent complexities such as large material property variations, complex couplings and boundary conditions, coupled heat and mass transfer mechanisms and phase transformations. In this study, a mathematical framework based on finite element method (FEM) capable of predicting temperature history, evolution of phases and internal stresses during heat treatment of metals and alloys was developed. The model was integrated into the commercial FEA software MSC.Marc&reg / by user subroutines. The accuracy of the model was verified by simulating the quenching of eccentrically drilled steel cylinders. Simulation results were justified via SEM observations and XRD residual stress measurements. According to the results, the model can effectively predict the trends in the distribution of microstructure and residual stresses with a remarkable accuracy.

Roller Compacted Concrete (RCC) has rapidly evolved from a concept to a material and a process which is used throughout the world for faster and more economical construction of dams. Currently, there are more than 250 RCC dams, completed or under construction, in the world. On the other hand, currently, there are only two RCC dams completed (Su&ccedil / ati and Cindere Dams) and two under construction (Beydag and &Ccedil / ine Dam) in Turkey. RCC dams are constructed in a series of compacted layers usually 30 cm in thickness. Therefore, appropriate bonding of successive layers is important and as a result, in between successive layers a bedding mix is often used to fill the surface voids in both the compacted layer below and the covering layer above, as well as to bond the two successive layers together. This study presents an experimental investigation on the bonding efficiency of RCC with different bedding mixes. The Beydag Dam RCC mixture was taken as the model for the preparation of laboratory-made RCC specimens. In the experimental study, 15 cm cubic specimens were prepared in two layers. Each layer was compacted using an electro pneumatic demolition hammer for 30 seconds. Four different time intervals between placement and compaction of two successive layers and two different bedding mix types were the selected cases for investigation. While preparing the specimens, the second layer was placed and compacted 0, 4, 8, 12 and 16 hours after the first layer was compacted. In between the two layers, two types of bedding mixes are placed in between previously compacted and freshly placed layer for joint treatment. One of the bedding mixes, having 200 kg/m3 cement content is termed poor while other one is termed rich having 400 kg/m3 cement content. RCC specimens are then subjected to compressive strength, splitting tensile strength and permeability tests. As a result of the experimental program, it was found that / a rich bedding mix was a more effective bonding agent between compacted RCC layers than the poor bedding mix for all time intervals between layers. Furthermore, it was concluded that bonding efficiency of RCC is not too dependent on time interval between layer compactions up to 16 hours. Finally, splitting tensile strength and sorptivity tests are shown to be applicable test methods for determination of bonding efficiency of RCC specimens if there is a definite bedding layer in between freshly placed and formerly compacted RCC.

Use of alternative raw materials, especially industrial by-products, is necessary for a sustainable cement industry. By replacing clinker with industrial by-products, consumption of natural resources and energy is decreased. Therefore, both economical and environmentally friendly cements are produced. Several industrial by-products such as fly ash, silica fume, and slag, one of the most widely used industrial by-products, can be used to produce standard blended cements. Besides its many advantages, slag cements are reported to have lower early compressive strengths. Therefore, the objective of this study is to investigate the early-strength improvement of slag cements. In the experimental study, in order not to change the cement type, the additives were incorporated within the minor additional constituent ranges, i.e. less than 5%. First, CEM III/A type control cement was prepared by blending clinker (K) and slag (S), which were separately ground in a laboratory type ball mill. Ground limestone (L) of varying fineness, silica fume (F), and sodium hydroxide (N) were prepared to be used as minor additional constituent. The ground clinker, slag, and gypsum, and the additives at various ratios were blended to obtain 15 CEM III/A type slag cements other than the control. Finally, the fresh and the hardened properties of the cements were determined. As a result of this experimental study, it was observed that addition of limestone generally increased the early compressive strength of slag cements. However, silica fume and sodium hydroxide either decreased or did not affect the early compressive strength of the slag cements.

The aim of this study was to investigate the microstructure and mechanical properties of pure and Mg2+ and F- doped nano-calcium phosphate (CaP) powders, which were synthesized by precipitation method. After the drying and calcination processes, the samples were sintered at 1100&ordm / C for 1 hour. High densities were achieved except for the 7.5 % mole Mg doped samples. Microstructure of the CaPs were investigated by X- ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy (SEM). Due to the Mg substitution, &amp / #946 / -TCP phase was detected besides HAp, resulting in the formation of HAp/ &amp / #946 / -TCP biphasic composites with different compositions. The substitutions of the ions have been verified by the decrease in the hexagonal unit cell volumes of the doped CaPs. FTIR spectra revealed the characteristic absorption bands of HAp, &amp / #946 / -TCP and the ones that were resulted from the F-OH bonds and substitution of the Mg2+ ions. The SEM results revealed the grain sizes in the range of ~197 nm-740 nm. In general, the micro hardness and diametral tensile strength tests revealed that Mg2+ ions in large amounts (7.5 % mole) had negative effects on the mechanical properties of the samples, while substitution of the F- ions had a positive effect on their mechanical properties.

Cement production which is one of the most energy intensive industries plays a significant role in emitting the greenhouse gases. Blended cement production by supplementary cementitious materials such as fly ash, ground granulated blast furnace slag and natural pozzolan is one of the smart approaches to decrease energy and ecology related concerns about the production. Fly ash has been used as a substance to produce blended cements for years, but bottom ash, its coarser counterpart, has not been utilized due to its lower pozzolanic properties. This thesis study aims to evaluate the laboratory performance of blended cements, which are produced both by fly ash and bottom ash. Fly ash and bottom ash obtained from Seyit&ouml / mer Power Plant were used to produce blended cements in 10, 20, 30 and 40% by mass as clinker replacement materials. One ordinary portland cement and eight blended cements were produced in the laboratory. Portland cement was ground 120 min to have a Blaine value of 3500&plusmn / 100 cm2/g. This duration was kept constant in the production of bottom ash cements. Fly ash cements were produced by blending of laboratory produced portland cement and fly ash. Then, 2, 7, 28 and 90 day compressive strengths, normal consistencies, soundness and time of settings of cements were determined. It was found that blended fly ash and bottom ash cements gave comparable strength results at 28 day curing age for 10% and 20% replacement. Properties of blended cements were observed to meet the requirements specified by Turkish and American standards.

The aim of this thesis is to investigate the effects of bulging and deep drawing processes on St4 cold rolled steel by simulation and experimental characterization. In the simulations, commercial software programs MSC Marc and Simufact.forming were used. The experimental studies cover metallographic investigations, hardness measurements, and residual stress measurements. Residual stress measurements were carried out by different non- destructive characterization methods / X-ray diffraction and Magnetic Barkhausen Noise. The experimental and simulation results were correlated with each other.

This work is intended to compare Large Eddy Simulation and Implicit Large Eddy Simulation (LES and ILES) for a turbulent, non-reacting or reacting high speed H2 jet in co-flowing air, typical of scramjet engines. Numerical simulations are performed at resolutions ranging from 32&times / 32&times / 128 to 256&times / 256&times / 1024, using a 5th order WENO scheme. Physical LES are carried out with the Smagorinsky and the Selective Structure Function models associated to molecular diffusion. Implicit LES are performed with and without molecular diffusion, by solving either the Navier-Stokes or the Euler equations. In the nonreacting case, the Smagorinsky model is too dissipative. The Selective Structure Function leads to better results, but does not show any superiority compared to ILES, whatever the grid resolution. In the reacting case, a molecular viscous cut-off in the simulation is mandatory to set a physical width for the reaction zone in the ILES approach, hence to achieve grid-convergence. It is also found that ILES/LES are less sensitive to the inlet conditions than the RANS approach. The first chapter is an introduction to the context of this study. In the second chapter, the governing equations for multispecies reacting flows are presented, with emphasis on the thermodynamic and transport models. In the third chapter, physical LES equations and explicit sub-grid modeling strategies iv are detailed. Some properties of the numerical scheme are also investigated. In chapter four, the numerical scheme and some aspects of the solver are explained. Finally, non-reacting and reacting numerical experiments are presented and the results are discussed.

The improvement in the impermeability of concrete was studied using different methods. The main aim was to investigate impermeability improvement of concrete and to compare these methods. Two different methods were examined to investigate and compare impermeability and strength improvement of concrete by using two different sets of concrete specimens. These methods included the application of coating materials to concrete and the production of concrete using different constituent amounts and types. The first set of concrete specimens was prepared by applying two different coating materials (a coating material including both powder and liquid components / and a coating material including only a liquid component) on reference concrete specimens separately. The second set of concrete specimens was prepared using different proportions of concrete constituents such as cement, water, steel and plastic fibers, mineral and chemical concrete admixtures. Various tests were conducted on both sets of concrete specimens in order to compare the permeability of concrete specimens. However, some of these tests v were not applied on all of the specimens because of test and material specifications. The tests were used to evaluate compressive strength, water absorption, chloride ion penetration and depth of water penetration under pressure. These test methods were carried out on concrete cube specimens and concrete cores taken from those specimens according to the relevant standards. It was found that the permeability of the concrete specimens decreased significantly when the coating material which was composed of the combination of powder and liquid components was applied on concrete specimens. However, permeability did not decrease significantly for concrete specimens coated with the coating material composed of only a liquid component. Significant improvement in the impermeability of the concrete specimens was observed when the amount of cement was increased, the water-to-cement ratio was decreased, mineral admixtures (silica fume and fly ash) and plasticizers were used. This improvement was associated with densification of the concrete microstructure and reduction in capillary pores as a result of pozzolanic reaction and due to reduction in water-to-cement ratio. Coating materials were determined to be effective for concretes with high permeability prior to coating whereas their effect was less significant for lower-initial permeability concretes. Moreover, the effect of coating materials on permeability differed depending on their chemical compositions. The effect of using steel fibers and plastic fibers for the improvement of concrete impermeability was found to be insignificant.

Portland cement hydration is an exothermic process. The heat evolved during the hydration process is especially important in mass concrete, and hot and cold weather concreting. Heat of hydration is affected by several factors like chemical composition of cement, fineness of cement and ambient temperature. The major aim of this thesis is to investigate the effect of cement composition and fineness, amount and composition of the fine portion (&lt / 45 &micro / m) of natural pozzolan-incorporated cement on hydration heat. For this purpose, a portland cement and pozzolan-incorporated blended cements containing different amounts of natural pozzolan (trass) were used. The heat of hydration was measured using isothermal calorimetry. The values of heat of hydration for mixtures with different finenesses containing different amounts of added pozzolan were determined. The results obtained were used to find a correlation between the fineness, composition of cement and heat of hydration. According to this study, pozzolan incorporation in small amounts accelerates hydration. A similar effect was obtained for higher pozzolan amounts. Finer cements react faster and result in higher amounts of early heat evolved compared to coarser cements. In addition, it was found that the sum of the heat of hydration values of fine and coarse portion of cements was less than the total heat of hydration of blended cements. Moreover, a satisfactory correlation could not be established between results of isothermal calorimetry, and adiabatic calorimetry, setting time, and strength.