The global demand for potable water has increase the use of chemicals to clean or prevent undesirable biofouling in reverse osmosis membranes. Biofouling is the growth and accumulation of biomass that generates an unacceptable performance decline. To date, a thoroughly efficient and green method to remove, prevent or treat biofouling in water treatment systems has not been developed. The studies carried out during my Ph.D. aim to develop greener and more efficient biofuling prevention/cleaning methods. The first two studies introduce a polyelectrolyte coating with the atypical characteristic of being removed and reapplied under operating conditions. After the biofilm develops on the coating, both biomass and coating can be removed with brine. The application of the coating can be done in-situ without hindering membrane performance. Using this procedure, both biofilm and coating could be simultaneously removed, leaving a clean surface. The biofouled coated membrane had two-fold higher permeate flux recovery compare to the non-coated. The sacrificial polyelectrolyte coating offers a greener solution for biofouling treatment in membrane systems. As an alternative to harsh chemicals, natural deep eutectic solvents (NADES) are presented as an alternative for biofilm treatment. Our results indicate that the NADES could solubilize up to ≈70% of the main components of the biofilm. The biofilm is weakened by the biomolecule’s solubilization, which could enhance biofilm removal. NADES have a great potential to be used for biofilm and avoid the currently used solvents. The last chapter is focused on understanding the structural characteristics and stability of NADES composed of betaine, urea, and water. The NADES composition and the water content is of significant relevance for its stability and supramolecular structure. Our experimental and computational results show that water is of crucial importance to the NADES supramolecular structure and stability. Understanding the NADES characteristics leads to finding better applications and giving insights into the interaction that these solvents have with other molecules, such as biopolymers or proteins. Even though there is still further research to be done, the studies presented on this thesis are a step forward towards finding and understanding greener solutions for biofilm treatment in water treatment systems.

Nanomaterials such as graphene oxide and carbon nanotubes, have demonstrated excellent properties for membrane desalination, including decrease of maintenance, increase of flux rate, simple solution casting, and impressive chemical inertness. Here, two projects are studied to investigate nanocarbon based membrane desalination. The first project is to prepare hybrid membranes with amyloid fibrils intercalated with graphene oxide sheets. The addition of protein amyloid fibrils expands the interlayer spacing between graphene oxide nanosheets and introduces additional functional groups in the diffusion pathways, resulting in increase of flux rate and rejection rate for the organic dyes. Amyloid fibrils also provide structural assistance to the hybrid membrane, which supresses cracking and instability of graphene oxide sheets. The second project is to fabricate polymer nanocomposite membranes with carbon nanotubes encapsulated by polymerized surfactants. The designed polymerizable surfactant forms lyotropic liquid crystalline mesophases in an aqueous medium with hexagonal packing of cylindrical micelles. The adsorption of surfactants on the surface of carbon nanotubes allows a stable dispersion of carbon nanotubes encapsulated in the cylindrical micelles, resulting in the ordered structure. After photo-polymerization, the composite membranes display enhanced dye rejection. Both projects have shown promising ways to improve membrane filtration by using nanomaterials.

This project is a bachelor thesis and aims to study the integration of concentrator photovoltaics (CPV), reverse osmosis (RO) and membrane distillation (MD) for water desalination and purification. In this report, an introduction of the need for efficient water desalination is presented. Following the introduction, relevant literature has been reviewed to build up the fundamental understanding of CPV, RO and MD. A general classification of CPV subsequently introduced. In order to acquire a more comprehensive understanding of CPVs, two case studies were performed with two different types of CPV/T. The cost efficiency of each type of CPV was analysed when integrated with RO and MD systems. The result turns out to be that it was not economically beneficial to have MD in the integrated system. The reason behind is the extensive thermal energy demand of MD. Other affecting parameters, such as location and system types were also discussed. Lastly, improvements and suggestions for further studies were considered. / Detta projekt är en kandidatuppsats och syftar till att studera ett integrerande system bestående av koncentrerade solceller (CPV), omvänd osmos (RO) och membrandestillation (MD) för vattenavsaltning och rening. Rapporten börjar med en introduktion om behovet av effektiv avsaltning av vatten. Relevant litteratur har granskats för att bygga upp den grundläggande förståelsen för CPV, RO och MD. Därefter gjordes en klassificering av CPV. För att få en mer omfattande förståelse av CPV valdes två olika typer av CPV /T för en djupare undersökning. Kostnadseffektiviteten för varje CPV analyserades, när dessa var integrerade med RO- och MD-system. Resultatet visar sig att det tyvärr inte var ekonomiskt fördelaktigt att ha med MD i det integrerade systemet. Anledningen bakom detta var det omfattande termiska energibehovet för MD. Andra avgörande faktorer, såsom plats och systemtyp diskuterades tillika. Slutligen avslutades rapporten med förslag på förbättringar och områden för vidare studier.