The main objective of this thesis is to investigate the transient response and steady-state performance of a counter-cross flow liquid-to-air membrane energy exchanger (LAMEE). The LAMEE is constructed from several semi-permeable membranes which separate the air and liquid streams. In addition to heat transfer, moisture transfer occurs between the air and liquid streams since the membranes are permeable to water vapor. The LAMEE performance is assessed experimentally and the results are used to verify a numerical model. The verified numerical model is also used to extrapolate the transient and steady-state performance parameters to other test conditions. The transient response of the LAMEE is important since there are times when the LAMEE operates under transient conditions due to daily start-up or changing operating conditions such as flow rates, temperatures or humidities. The transient response of the LAMEE is investigated experimentally and numerically. The number of heat transfer units (NTU), and the ratio of solution and air heat capacity rates (Cr*) are two important parameters that affect the LAMEE performance. The results show that the transient sensible, latent and total effectivenesses increases with time after a step change in the conditions of the inlet liquid desiccant. The experimental and numerical transient effectiveness values and trends are compared for different NTU and Cr* values under summer and winter test conditions and the results show satisfactory agreement. In addition to the transient effectiveness, the time constant of the LAMEE is assessed as an important transient parameter. The time constant represents the time it takes for the LAMEE to reach 63.2% of the steady-state conditions after a step change in inlet conditions. The transient response of the outdoor air temperature and humidity ratio are normalized and used to determine the sensible and latent time constants. It is found that time constant depends on NTU, Cr* and thermal mass capacity of the LAMEE. The experimental and numerical results show that time constant increases as Cr* decreases or NTU increases. Furthermore, the verified numerical model is used to study the effect of outdoor air conditions on the LAMEE time constant. The numerical results reveal that the latent time constant is influenced by outdoor air conditions and the time constant decreases as H* increases, but the sensible time constant is almost constant for various outdoor air conditions. However, the outdoor air conditions affect the transient response of the LAMEE considerably since the total transient response of the LAMEE is closer to the latent transient response for the conditions studied. The steady-state performance of the LAMEE is studied for different NTU and Cr* values under summer test conditions. The experimental data are compared to numerical and analytical results and acceptable agreement is achieved. It is found that the steady-state effectiveness of the LAMEE increases with NTU and Cr*. The maximum total effectiveness reaches 88% for NTU=10 and Cr*=6.3. The verified numerical model is also used to investigate the effect of outdoor air conditions on the steady-state sensible and latent effectiveness of the LAMEE. The sensible effectiveness is significantly influenced by outdoor air conditions variation while the latent effectiveness is only slightly influenced by these variations. The sensible effectiveness decreases as the operating condition factor (H*) increases, but the latent effectiveness increases with H*.

Volatile Organic Compounds (VOCs) constitute an important class of indoor air contaminants and they may cause adverse health effects for occupants in buildings. Indoor generated contaminants may be transferred between the supply and exhaust air streams of the building’s Heating, Ventilation and Air-conditioning (HVAC) system when air-to-air energy recovery devices are used. The run-around membrane energy exchanger (RAMEE) is a novel exchanger, which uses aqueous magnesium chloride (MgCl2) salt solution (34-35 wt%) as a liquid desiccant to transfer heat and moisture between remote supply and exhaust air streams. In the RAMEE, a gas-phase porous membrane is placed between the air stream and the liquid desiccant stream in each exchanger and the membrane prevents the salt solution from entering the air stream but still allows the transfer of water vapor through the semi-permeable membrane. In the RAMEE, VOCs may transfer between the exhaust and supply air streams due to (i) air leakage or (ii) due to dissolution of VOCs into the liquid desiccant in the exhaust exchanger and their subsequent evaporation into the air stream of the supply exchanger. These two transfer mechanisms were tested in the laboratory using two counter-cross-flow RAMEE prototypes (Prototype #4 and Prototype #6). Tests were conducted at different air and desiccant flow rates at AHRI standard summer and winter operating conditions. Sulfur hexafluoride (SF6) was used as a tracer gas to test air leakage and toluene (C7H8) and formaldehyde (HCHO) were used to test VOC dissolution and transfer. From an external source, a known concentration of VOC was injected into the exhaust air inlet stream and the transfer fraction of VOC to the supply air stream was calculated. This transfer fraction or Exhaust Air Transfer Ratio (EATR) defined by ANSI/ASHRAE Standard 84 (2012) at steady state conditions was used to quantify and compare the transfer fraction of contaminants in both prototypes. The uncertainty in the transfer fraction was calculated and all the uncertainty bounds were calculated for 95% confidence interval. The transfer fraction of sulfur hexafluoride was 0.02 +/- 3.6% for both prototypes tested, which means that the air leakage between the air streams is negligible. The transfer of toluene, which has a low solubility in water, was less than the uncertainty in the measurement. EATR* values for toluene were 2.3-3.4% and the uncertainties were 3.4-3.6%. The transfer of formaldehyde between the exhaust and the supply air streams was the highest and the EATR* values just exceeded the uncertainties in the EATR* measurement. The highest EATR* values for the transfer of formaldehyde in Prototype #4 and Prototype #6 were 6.4 +/- 3.6% and 5.3 +/- 3.6%, respectively. At steady state, the measured EATR* values for both prototypes were insensitive to changes in the air flow rate, the liquid desiccant flow rate, the latent effectiveness and the environmental conditions but time delays to reach steady state were significant. These results imply that there is a negligible transfer of contaminants due to air leakage between the air streams, a negligible transfer of low water soluble VOCs (such as toluene), but possibly a small detectable transfer of very water soluble VOCs (such as formaldehyde) between the exhaust and supply air streams of the RAMEE.

In this study, a novel counter-cross-flow run-around membrane energy exchanger (RAMEE) system was designed and tested in the laboratory. The RAMEE system consists of two (2) counter-cross-flow Liquid-to-Air Membrane Energy Exchangers (LAMEEs) to be located in the supply and exhaust air streams in the building Heating Ventilation and Air-Conditioning (HVAC) system. Inside each exchanger, a micro-porous membrane separates the air and liquid streams and allows transfer of the sensible and latent energy from the air stream to the liquid stream or vice-versa. The system exchanges sensible and latent energy between supply and exhaust air streams using a desiccant solution loop. The supply and exhaust air streams in the RAMEE can be located far apart from each other or adjacent to each other. The flexibility of non-adjacent ducting makes the RAMEE system a better alternative compared to available energy recovery systems for the retrofit of HVAC systems.<p> Two counter-cross-flow exchangers for the RAMEE system were designed based on an industry recommended standard which is to obtain a target overall system effectiveness of 65% for the RAMEE system at a face velocity of 2 m/s. The exchanger design was based on heat exchanger theory and counter-cross-flow design approach. An exchanger membrane surface aspect ratio (ratio of exchanger membrane surface height to exchanger length) of 1/9 and the desiccant solution entrance ratio (ratio of desiccant solution entrance length to exchanger length) of 1/24 were employed. Based on different heat transfer case studies, the energy transfer size of each exchanger was determined as 1800 mm x 200 mm x 86 mm. ProporeTM was used as the membrane material and Magnesium-Chloride solution was employed as the desiccant solution.<p> The RAMEE performance (sensible, latent and total effectiveness) was evaluated by testing the system in a run-around membrane energy exchanger test apparatus by varying the air stream and liquid solution-flow rates at standard summer and winter operating conditions. From the test data, the RAMEE effectiveness values were found to be sensitive to the air and solution flow rates. Maximum total effectiveness of 45% (summer condition) and 50% (winter condition) were measured at a face velocity ¡Ö 2 m/s. A comparison between the experimental and numerical results from the literature showed an average absolute discrepancy of 3% to 8% for the overall total system effectiveness. At a low number of heat transfer units, i.e. NTU = 4, the numerical and experimental results show agreement within 3% and at NTU = 12 the experimental data were 8% lower than the simulations. The counter-cross-flow RAMEE total system effectiveness were found to be 10% to 20% higher than those reported for a cross-flow RAMEE system by another researcher.<p> It is thought that discrepancies between experimental and predicted results (design and numerical effectiveness) may be due to the mal-distributed desiccant solution-flow, desiccant solution leakage, lower than expected water vapor permeability of the membrane, uncertainties in membrane properties (thickness and water vapor permeability) and heat loss/gain effects. Future research is needed to determine the exact cause of the discrepancies.

In this study, a novel counter-cross-flow run-around membrane energy exchanger (RAMEE) system was designed and tested in the laboratory. The RAMEE system consists of two (2) counter-cross-flow Liquid-to-Air Membrane Energy Exchangers (LAMEEs) to be located in the supply and exhaust air streams in the building Heating Ventilation and Air-Conditioning (HVAC) system. Inside each exchanger, a micro-porous membrane separates the air and liquid streams and allows transfer of the sensible and latent energy from the air stream to the liquid stream or vice-versa. The system exchanges sensible and latent energy between supply and exhaust air streams using a desiccant solution loop. The supply and exhaust air streams in the RAMEE can be located far apart from each other or adjacent to each other. The flexibility of non-adjacent ducting makes the RAMEE system a better alternative compared to available energy recovery systems for the retrofit of HVAC systems.<p> Two counter-cross-flow exchangers for the RAMEE system were designed based on an industry recommended standard which is to obtain a target overall system effectiveness of 65% for the RAMEE system at a face velocity of 2 m/s. The exchanger design was based on heat exchanger theory and counter-cross-flow design approach. An exchanger membrane surface aspect ratio (ratio of exchanger membrane surface height to exchanger length) of 1/9 and the desiccant solution entrance ratio (ratio of desiccant solution entrance length to exchanger length) of 1/24 were employed. Based on different heat transfer case studies, the energy transfer size of each exchanger was determined as 1800 mm x 200 mm x 86 mm. ProporeTM was used as the membrane material and Magnesium-Chloride solution was employed as the desiccant solution.<p> The RAMEE performance (sensible, latent and total effectiveness) was evaluated by testing the system in a run-around membrane energy exchanger test apparatus by varying the air stream and liquid solution-flow rates at standard summer and winter operating conditions. From the test data, the RAMEE effectiveness values were found to be sensitive to the air and solution flow rates. Maximum total effectiveness of 45% (summer condition) and 50% (winter condition) were measured at a face velocity ¡Ö 2 m/s. A comparison between the experimental and numerical results from the literature showed an average absolute discrepancy of 3% to 8% for the overall total system effectiveness. At a low number of heat transfer units, i.e. NTU = 4, the numerical and experimental results show agreement within 3% and at NTU = 12 the experimental data were 8% lower than the simulations. The counter-cross-flow RAMEE total system effectiveness were found to be 10% to 20% higher than those reported for a cross-flow RAMEE system by another researcher.<p> It is thought that discrepancies between experimental and predicted results (design and numerical effectiveness) may be due to the mal-distributed desiccant solution-flow, desiccant solution leakage, lower than expected water vapor permeability of the membrane, uncertainties in membrane properties (thickness and water vapor permeability) and heat loss/gain effects. Future research is needed to determine the exact cause of the discrepancies.

Liquid desiccant air conditioning (LDAC) has received much attention in recent years. This is mainly because LDAC systems are able to control latent loads in a more energy efficient way than conventional air conditioning systems. Although many research studies have been conducted on LDAC technologies, the following gaps in the scientific literature are addressed in this thesis: (1) carryover of desiccant droplets in air streams, (2) direct comparisons between different configurations of LDAC systems, (3) fundamentals of capacity matching in heat-pump LDAC systems, (4) optimal-control strategies for heat-pump LDAC systems, and (5) importance of transients in evaluating the performance of a LDAC system. Items (1) to (4) are addressed using TRNSYS simulations, and item (5) is addressed using data collected from a field test. The use of liquid-to-air membrane energy exchangers (LAMEEs) as dehumidifiers and regenerators in LDAC systems eliminate the desiccant droplets carryover problem in air streams. This is because LAMEE separate the air and solution streams using semi-permeable membranes, which allow the transfer of heat and moisture but do not allow the transfer of the liquid desiccant. A preliminary configuration for a membrane LDAC system, which uses LAMEEs as the dehumidifier and regenerator, is proposed and investigated under fixed operating conditions in this thesis. The influences of key design and operating parameters on the heat and mass transfer performances of the membrane LDAC system are evaluated. Results show that the membrane LDAC technology is able to effectively remove latent loads in applications that the humidity to be controlled. A comprehensive evaluation is conducted in this thesis for the thermal, economic and environmental performances of several configurations of membrane LDAC systems. The solution cooling load is covered using a cooling heat pump in all systems studied, while the solution heating load is covered using one of the following five different heating systems: (1) a gas boiler, (2) a heating heat pump, (3) a solar thermal system with gas boiler backup, (4) a solar thermal system with heat pump backup, and (5) the condenser of the solution cooling heating pump. Each of the membrane LDAC systems studied is evaluated with/without an energy recovery ventilator (ERV) installed in the air handling system. The influence of operating the ERV under balanced/unbalanced operating conditions is studied. It is found that the most economic membrane LDAC system is the one which uses the evaporator and condenser of the same heat pump to cover the solution cooling and heating loads, respectively (i.e. heat-pump membrane LDAC system). No clear guidance was found in the literature for sizing the evaporator and condenser in a heat-pump LDAC system to simultaneously meet the solution cooling and heating loads. When the heating and cooling provided by the heat pump exactly match the heating and cooling requirements of the solution, the system is “capacity matched”. A parametric study is conducted on a heat-pump membrane LDAC system to identify the influence of key operating and design parameters on achieving capacity matching. It is concluded that the solution inlet temperatures to the dehumidifier and regenerator are the most influential parameters on the moisture removal rate, capacity matching and coefficient of performance (COP). Three control strategies are developed for heat-pump membrane LDAC systems, where these strategies meet the latent loads and achieve one of the following three objectives: (1) meet the sensible loads, (2) achieve capacity matching, or (3) optimize the COP. Results show that the COP of a heat-pump LDAC system can be doubled by selecting the right combination of solution inlet temperatures to the regenerator and dehumidifier. The importance of transients in evaluating the performance of a LDAC system is addressed in the thesis using a data collected from a field test on a solar LDAC system. It is found that the sensible, latent and total cooling energy, and the total primary energy consumption of the LDAC system are changed by less than 10% during an entire test day when transients are considered. Thus, it can be concluded that steady-state models are reliable to evaluate the energy performances of LDAC systems.

A liquid-to-air membrane energy exchanger (LAMEE) is a novel flat-plate membrane-based energy exchanger where heat and moisture transfer between air and solution streams occurs through a semi-permeable membrane. The LAMEE consists of many air and solution flow channels, each separated by a membrane. A small-scale single-panel LAMEE consists of a single pair of neighboring air and solution channels. This PhD thesis focuses on developing, testing and modeling the small-scale single-panel LAMEE, and investigating the similarity between the small-scale LAMEE and a full-scale LAMEE. This PhD thesis presents a methodology to investigate similarity between small-scale and full-scale energy exchangers. A single-panel energy exchanger test (SPEET) facility is developed and built to measure the performance of the small-scale single-panel LAMEE under different test conditions. Also, the small-scale LAMEE is numerically modeled by solving coupled heat and mass transfer equations for the air, solution and membrane of the LAMEE. The effects of membrane vapor diffusion resistance and enhanced air side convective heat transfer coefficient are numerically investigated. The numerical model of the small-scale LAMEE is validated with the experimental data for summer test conditions, and effectiveness values agree within ±4% in most cases. Moreover, the effects of different heat and mass transfer directions, and salt solution types and concentrations are experimentally and numerically investigated. The results show that the LAMEE effectiveness is strongly affected by the heat and mass transfer directions but negligibly affected by salt solution type and concentration. The solution-side effectiveness for liquid-to-air membrane energy exchangers is introduced in this thesis for the first time. The results show that the solution-side effectiveness should be used to evaluate the sensible and total effectiveness of LAMEE regenerators. Finally, the similarity between the small-scale and full-scale LAMEEs is investigated experimentally and numerically. The results show that the small-scale LAMEE effectiveness results can be used to predict the performance of a full-scale LAMEE within ±2% to ±4% in most cases.