The Hobby-Eberly Telescope Chemical Abundances of Stars in the Halo (CASH) project aims to characterize the nature of the early universe through the study of metal-poor stars in the stellar halo of the galaxy. Once completed, this will be the largest set of abundances determined for metal-poor stars from high resolution spectra. In this paper, we present chemical abundances and trends of eleven elements for the first ~80 stars of the ~500 star study. These 80 stars serve as a pilot sample to test the automated stellar parameter and abundance determination pipeline newly developed for the CASH project called CASHCODE. Among the pilot sample, two stars with [Fe/H]<-3.5 were discovered and their abundance analysis is discussed. / text

The discovery of the Spite plateau in the abundances of 7Li for metal-poor stars led to the determination of an observationally deduced primordial lithium abundance. However, with the determination of the baryon density, Omega_B_h^2, from the Wilkinson Microwave Anisotropy Probe (WMAP) data, a discrepancy arose between observationally determined and theoretically determined abundances of 7Li. This is what has become known as the “lithium problem”. Of all the uncertain factors in determining a stellar Li abundance, the effective temperature is the most important. This thesis is concerned with determining an accurate effective temperature scale for metal-poor halo dwarfs, paying specific attention to eliminating any possible systematic errors. This is done by utilising the exponential term, Chi/T, of the Boltzmann equation. Two assumptions are adopted; firstly the simplifying assumptions of local thermodynamic equilibrium (LTE), and secondly the more sophisticated techniques of non-local thermodynamic equilibrium (NLTE). The temperature scales are compared to others derived using different techniques; a photometric scale, where I find comparable Teff in LTE and hotter temperatures by an average of ~ 150 K in NLTE; a scale derived using Balmer lines, for which I have comparable values in LTE and hotter Teff values, by typically 110 K – 160 K, in NLTE; and finally a scale derived using an infrared flux method (IRFM). Here I find their Teff values are hotter by ~ 250 K for LTE and ~ 190 K in NLTE. Lithium abundances are then calculated for the program stars and a mean Li abundance is derived. I find values ranging from A(Li) = 2.10 dex – 2.16 dex with the LTE scales and A(Li) = 2.19 dex – 2.21 dex for the NLTE scales. These mean Li abundances are compared to other observationally deduced abundances, for which I find comparable results in LTE and higher values in NLTE, and to the WMAP + big bang nucleosynthesis calculated Li abundance. I find that my new values are still considerably lower than the WMAP value and are therefore unable to reconcile the lithium problem. Second to this primary investigation, I use Ti as an independent test of the derived Teff values and log g’s. I find that Ti is not a useful constraint on the temperatures or, therefore, on the lithium problem. I also assess the impact of the new Teff scales on the different models of Galactic chemical evolution (GCE), comparing newly calculated abundances with GCE determined abundances. It was found that trends exist in several of the elements; however, these were not statistically relevant. Also a larger degree of scatter was found in the abundances compared to the Arnone et al. (2005). This scatter was not to the degree found in the Argast et al. (2000). Reasons for the differences have been discussed.

The principal theory concerning the origin of the elements heavier than the Fe-peak, such as Ba, strongly suggest that for old, metal-poor environments, the rapid (r-) process is the most likely path taken in their synthesis, while the slow (s-) process becomes more substantial in younger, more metal-rich stellar populations. In this work I test this theory by evaluating the isotope ratios of Ba. It is understood that Ba consists of seven stable isotopes, five of which are synthesised by the two neutron-capture processes. The two odd isotopes, 135,137Ba, as well as 138Ba are synthesised via both the r- and s-processes while two of the even isotopes, 134,136Ba are synthesised via the s-process only. The relative contribution of the r- and s-process to these isotopes can be understood via nucleosynthesis calculations and is described using the parameter fodd, where fodd = [N (135Ba) + N (137Ba)] /N (Ba). Low values of fodd (~0.11) indicate an s-process regime, while high values of fodd (~0.46) indicate an r-process regime. In the Ba II 4554 A line the even isotopes lie close to the line centre, while the odd isotopes, which are hyperfine split because of their non-zero nuclear spin, lie in the wings of the line. From an analysis of the line profile shape, one can determine whether Ba has been synthesised primarily through the r-process or s-process; a broad, asymmetric line would indicate a high r-process contribution, while a line with a deeper core and shallower wings would indicate a high s-process contribution. Using the radiative transfer code ATLAS, which assumes local thermodynamic equilibrium (LTE) and employs 1-dimensional (1D) KURUCZ06 model atmospheres, I synthesised line profiles for six metal-poor stars: HD140283, HD122563, HD88609, HD84937, BD-04 3208 and BD+26 3578 - for a range of isotope ratios. All six are of sufficiently low metallicity that Ba was expected to have an r-process origin. These were fit to high resolution (R\equiv \lamda/\Delta\lamda = 90 000 - 95 000), high signal-to-noise to the Ba II 4554 A line which has multiple components. In the first test, synthetic spectra were computed using the non local thermodynamic equilibrium (NLTE) radiative transfer code MULTI. The synthetic line profiles were fit to a number of lines in HD140283. Although this technique might have improved the fit in the line core, it was found that such a treatment did not improve upon fitting errors associated with the best fit 1D LTE synthetic profiles. The second test used a 3-dimensional (3D) radiative transfer code (LINFOR3D) that employed 3D, time-dependent atmospheres produced with CO5BOLD. The 3D synthetic pro les were fit to a selection of Fe lines and improvements over the poor fits produced by the 1D LTE synthesis were seen. It was found that the 3D synthesis could almost completely reproduce the line asymmetries seen in the observed stellar spectrum. This result suggests that further work to refine the 3D calculations and synthesis code would be valuable.

Um dos maiores desafios da Astrofísica é tentar compreender a complexidade da composição química das estrelas. Elementos com massas atômicas acima de A>60 são formados pelos chamados processos de captura de nêutrons (processo-s e processo-r). A presença destes em espectros de estrelas de baixa massa (longo período de vida) e com pouco conteúdo metálico sugere episódios de enriquecimento por estrelas massivas nos primórdios da Galáxia. Portanto, o estudo das estrelas chamadas \"pobres em metais\" enriquecidas por elementos formados por captura de nêutrons pode reproduzir as condições físicas dominantes à época de sua formação. O objetivo deste trabalho é explorar os padrões de abundâncias das estrelas muito pobres em metais observadas no survey HERES. Através deste estudo, é possível inferir correlações entre elementos químicos e restringir a operação dos processos de captura de nêutrons na Galáxia. Para tanto, utiliza-se técnicas estatísticas como a análise de conglomerados, que permite o estudo da formação de grupos naturais baseado na relação entre as abundâncias elementais. Este estudo fornece uma análise compreensiva de uma amostra de 382 estrelas pobres em metais, além de introduzir duas novas subclasses para estrelas pobres em metais enriquecidas em elementos formados por captura de nêutrons. / One of the most challenging subjects of Astrophysics is trying to understand the complexity of the chemical composition of stellar objects. Spectroscopic observations are widely used nowadays in order to achieve these goals, as they provide the chemical composition of the atmosphere of the stars. Elements with atomic masses above A>60 are formed by the so called neutron capture processes (r-process and s-process). Its presence on low-mass star spectra (which have long life-time) and low metal content suggests episodes of enrichment by high-mass stars that took place in the early times in the Galaxy formation. Then, the study of those \"metal-poor\" stars enriched by neutron-capture elements may help reproduce the physical conditions of the environment from where they were formed. The main goal of this project is to explore the abundance patterns of the very metal-poor stars observed by the HERES survey. This study allows the analysis of the correlations between chemical elements and place some constraints on the operation of the neutron capture processes in the early Galaxy. This approach made use of statistical tools, such as agglomerative nesting, which can identify the formation of natural groups based on relations among elemental abundances. In this context, this study provides a comprehensive analysis of a 382 metal-poor stars sample, and introduces two new subclasses for metal-poor stars with determined abundances of neutron-capture elements.

No description available.

Um dos maiores desafios da Astrofísica é tentar compreender a complexidade da composição química das estrelas. Elementos com massas atômicas acima de A>60 são formados pelos chamados processos de captura de nêutrons (processo-s e processo-r). A presença destes em espectros de estrelas de baixa massa (longo período de vida) e com pouco conteúdo metálico sugere episódios de enriquecimento por estrelas massivas nos primórdios da Galáxia. Portanto, o estudo das estrelas chamadas \"pobres em metais\" enriquecidas por elementos formados por captura de nêutrons pode reproduzir as condições físicas dominantes à época de sua formação. O objetivo deste trabalho é explorar os padrões de abundâncias das estrelas muito pobres em metais observadas no survey HERES. Através deste estudo, é possível inferir correlações entre elementos químicos e restringir a operação dos processos de captura de nêutrons na Galáxia. Para tanto, utiliza-se técnicas estatísticas como a análise de conglomerados, que permite o estudo da formação de grupos naturais baseado na relação entre as abundâncias elementais. Este estudo fornece uma análise compreensiva de uma amostra de 382 estrelas pobres em metais, além de introduzir duas novas subclasses para estrelas pobres em metais enriquecidas em elementos formados por captura de nêutrons. / One of the most challenging subjects of Astrophysics is trying to understand the complexity of the chemical composition of stellar objects. Spectroscopic observations are widely used nowadays in order to achieve these goals, as they provide the chemical composition of the atmosphere of the stars. Elements with atomic masses above A>60 are formed by the so called neutron capture processes (r-process and s-process). Its presence on low-mass star spectra (which have long life-time) and low metal content suggests episodes of enrichment by high-mass stars that took place in the early times in the Galaxy formation. Then, the study of those \"metal-poor\" stars enriched by neutron-capture elements may help reproduce the physical conditions of the environment from where they were formed. The main goal of this project is to explore the abundance patterns of the very metal-poor stars observed by the HERES survey. This study allows the analysis of the correlations between chemical elements and place some constraints on the operation of the neutron capture processes in the early Galaxy. This approach made use of statistical tools, such as agglomerative nesting, which can identify the formation of natural groups based on relations among elemental abundances. In this context, this study provides a comprehensive analysis of a 382 metal-poor stars sample, and introduces two new subclasses for metal-poor stars with determined abundances of neutron-capture elements.

O principal objetivo deste trabalho é mostrar que é possível buscar por estrelas pobres em metais a partir da premissa de que uma grande fração destas será rica em carbono. Essa hipótese ainda não havia sido verificada pois muitas das chamadas estrelas CEMP (Carbon Enhanced Metal-Poor) foram negligenciadas em estudos anteriores devido à forma como foram executadas as buscas por estas estrelas. Estes objetos são importantes pois assumem o papel de registros fósseis das primeiras gerações estelares, uma vez que retêm em suas atmosferas informações vitais acerca da composição química do meio em que foram geradas. Por não apresentarem bandas moleculares intensas de carbono em seus espectros, muitas dessas estrelas não foram selecionadas para estudos em média/alta resolução. Este trabalho fornece, a partir do estudo da parte estelar do projeto HES (Hamburg/ESO Survey), que contém 4.404.908 objetos, dois novos índices de linha para a região da banda G do CH, em 4304 Å. Estes, pelo fato de possuírem uma largura de banda de 200 Å, conseguem superar falhas dos índices anteriormente definidos e representam com fidelidade as principais características desta região. Após uma análise detalhada da base de dados, e do cálculo dos novos índices de linha para todos os objetos disponíveis, foram identificadas com o telescópio SOAR 132 estrelas pobres em metais inéditas na literatura, sendo que 51% destas possuem metalicidades abaixo de [Fe/H] < -1.0 e apresentam consideráveis enriquecimentos em carbono ([C/Fe] > +0.5). Já para as estrelas encontradas com [Fe/H] < -2.5, a fração de estrelas com abundâncias de carbono [C/Fe] > +1.0 chega a 80%. Estimativas de abundâncias de elementos químicos tais como bário e estrôncio revelam que, mesmo com parâmetros atmosféricos e abundâncias de carbono semelhantes, as estrelas analisadas por este trabalho possuem mais de um tipo de cenário possível para sua formação. Neste ínterim, os objetos adicionados à literatura contribuem tanto para o aumento da estatística de estrelas pobres em metais quanto para testes de modelos teóricos de enriquecimento químico da Via Láctea. Finalmente, este trabalho também gerou uma lista de 6123 candidatas a estrelas CEMP inéditas na literatura. / The main goal of this work is to show that is possible to search for metal-poor stars based on the premise that a large fraction of these will be carbon-rich. This hypothesis had not yet been verified because many of the so-called CEMP (Carbon Enhanced Metal-Poor) stars were neglected in previous studies due to the design of the search for metal-poor stars with carbon enhancements. Those objects play a major role as fossil records of the very first generation of stars, since they carry in their atmospheres vital informations concerning the chemical composition of the medium where they were formed. By not showing strong carbon molecular bands in their spectra, many of those stars were not selected for follow-up studies in medium/high resolution. This work provides, based on the study of the stellar part of the HES (Hamburg/ESO Survey), two new line indices for the G band (4304 Å) that, by having a line band of 200 Å, can overcome the flaws of the previously defined indices and also truly represent the main features of this region. After an extensive analysis of the database and the calculation of the line indices for all the available objects, 132 new metal-poor stars were identified with the SOAR telescope, being that 51% of those stars with [Fe/H] < 1.0 present considerable carbon enhancements ([C/Fe]> +0.5). For the observed stars with [Fe/H] < 2.5, the fraction of objects with [C/Fe] > +1.0 rises up to 80%. Abundance estimates for barium and strontium show that, even with similar atmospheric parameters and carbon abundances, the stars analysed in this work have more than one possible formation scenario. Finally, this work also contributes with a 6123 CEMP star candidate list of unpublished objects.

O principal objetivo deste trabalho é mostrar que é possível buscar por estrelas pobres em metais a partir da premissa de que uma grande fração destas será rica em carbono. Essa hipótese ainda não havia sido verificada pois muitas das chamadas estrelas CEMP (Carbon Enhanced Metal-Poor) foram negligenciadas em estudos anteriores devido à forma como foram executadas as buscas por estas estrelas. Estes objetos são importantes pois assumem o papel de registros fósseis das primeiras gerações estelares, uma vez que retêm em suas atmosferas informações vitais acerca da composição química do meio em que foram geradas. Por não apresentarem bandas moleculares intensas de carbono em seus espectros, muitas dessas estrelas não foram selecionadas para estudos em média/alta resolução. Este trabalho fornece, a partir do estudo da parte estelar do projeto HES (Hamburg/ESO Survey), que contém 4.404.908 objetos, dois novos índices de linha para a região da banda G do CH, em 4304 Å. Estes, pelo fato de possuírem uma largura de banda de 200 Å, conseguem superar falhas dos índices anteriormente definidos e representam com fidelidade as principais características desta região. Após uma análise detalhada da base de dados, e do cálculo dos novos índices de linha para todos os objetos disponíveis, foram identificadas com o telescópio SOAR 132 estrelas pobres em metais inéditas na literatura, sendo que 51% destas possuem metalicidades abaixo de [Fe/H] < -1.0 e apresentam consideráveis enriquecimentos em carbono ([C/Fe] > +0.5). Já para as estrelas encontradas com [Fe/H] < -2.5, a fração de estrelas com abundâncias de carbono [C/Fe] > +1.0 chega a 80%. Estimativas de abundâncias de elementos químicos tais como bário e estrôncio revelam que, mesmo com parâmetros atmosféricos e abundâncias de carbono semelhantes, as estrelas analisadas por este trabalho possuem mais de um tipo de cenário possível para sua formação. Neste ínterim, os objetos adicionados à literatura contribuem tanto para o aumento da estatística de estrelas pobres em metais quanto para testes de modelos teóricos de enriquecimento químico da Via Láctea. Finalmente, este trabalho também gerou uma lista de 6123 candidatas a estrelas CEMP inéditas na literatura. / The main goal of this work is to show that is possible to search for metal-poor stars based on the premise that a large fraction of these will be carbon-rich. This hypothesis had not yet been verified because many of the so-called CEMP (Carbon Enhanced Metal-Poor) stars were neglected in previous studies due to the design of the search for metal-poor stars with carbon enhancements. Those objects play a major role as fossil records of the very first generation of stars, since they carry in their atmospheres vital informations concerning the chemical composition of the medium where they were formed. By not showing strong carbon molecular bands in their spectra, many of those stars were not selected for follow-up studies in medium/high resolution. This work provides, based on the study of the stellar part of the HES (Hamburg/ESO Survey), two new line indices for the G band (4304 Å) that, by having a line band of 200 Å, can overcome the flaws of the previously defined indices and also truly represent the main features of this region. After an extensive analysis of the database and the calculation of the line indices for all the available objects, 132 new metal-poor stars were identified with the SOAR telescope, being that 51% of those stars with [Fe/H] < 1.0 present considerable carbon enhancements ([C/Fe]> +0.5). For the observed stars with [Fe/H] < 2.5, the fraction of objects with [C/Fe] > +1.0 rises up to 80%. Abundance estimates for barium and strontium show that, even with similar atmospheric parameters and carbon abundances, the stars analysed in this work have more than one possible formation scenario. Finally, this work also contributes with a 6123 CEMP star candidate list of unpublished objects.