<p> Granitic and associated metamorphic rocks of Precambrian age in southeastern Ontario, Canada have been studied in order to determine the relationship of K, Rb and Tl and their behaviour during the process of partial melting and magmatic differentiation and metasomatism. </p> <p> Analytical results for major elements and rubidium and thallium abundances for 52 samples are given. </p> <p> From the present data, it appears possible that the series of migmatite and granodiorite gneiss originated by partial melting of paragneiss, together with pink granite which developed by late magmatic processes from a granodiorite melt, as was proposed by Chesworth (1967). </p> <p> Consideration of the geochemical data shows that the principal aspects of the distribution of Rb and Tl during partial melting are controlled by the mineralogical composition of the residuum which remains after partial melting. If mica is present in the residuum a newly-formed melt could have higher or the same K/Rb, K/Tl and Rb/Tl ratios as the parent rock and thus the "classical rule" of lower K/Rb and K/Tl in the anatectic melt is not valid. </p> <p> Enrichment of Tl in rocks affected by metasomatic processes is demonstrated. The marked decrease of K/Tl and Rb/Tl in the contact rocks (calc-silicate marbles) is caused by stronger migration of Tl, relative to K and Rb, from the intruded pink granite. </p> <p> The high mobility of thallium compounds is an important factor in the distribution of Tl during metasomatic and magmatogenic processes. </p> / Thesis / Master of Science (MSc)

Thermobarometry, detailed petrography, electron microprobe analysis, and fluid inclusion microthermometry were used to quantify the history of a high grade Proterozoic terrane exposed within the northeastern Colorado Front Range. Pressure-temperature calculations identified two blocks from different crustal levels exposed adjacent to one another within the Poudre Canyon west of Fort Collins. They are the eastern, higher pressure, block (HPB; 734 degree C, 7.1 kbar) and the western, lower pressure, block (LPB; 655 degree C, 5.2 kbar). The blocks followed a clockwise uplift path and were juxtaposed by ductile shear near the end of the decompressive stage of uplift. Final assembly of the separate blocks to the same crustal level was constrained by mineralogic and textural considerations and by the isochores of identical low density carbon dioxide inclusions trapped by both blocks. Both blocks experienced peak metamorphism within the sillimanite-K-feldspar zone accompanied by partial melting, are characterized by stromatic migmatites, and show textural evidence for localized reactions related to decompression and cooling. Differences between the blocks include the type of melt-generating reactions and the pronounced late muscovite in the LPB. Gibbs' Method calculations indicate that local (outcrop scale) textural and mineralogical differences between HPB Mg-enriched pelites are caused by small differences in bulk composition and locally variable H2O content. The quartzo-feldspathic biotite gneisses in the LPB generated migmatites by wet melting, whereas the pelitic schists and gneisses in the HPB generated migmatites by dehydration melting of muscovite and biotite. Biotite dehydration melting enriched the leucosomes in HPB pelitic migmatites in K-feldspar and garnet. The minor presence of late muscovite in the HPB relative to the LPB was controlled by the different positions of their uplift paths relative to the muscovite breakdown reaction. / Ph. D.

Fluids, mainly H2O and CO2, are released from H- and C-bearing phases during prograde metamorphism. Because of the buoyancy of these fluids, they rise within the crust towards the surface of the Earth. Metamorphic fluids take advantage of permeable horizons, shear zones, fold hinges, fractures, and are channelled into high-flux zones. Fluid fluxes for channelized fluid flow may exceed background pervasive fluxes by several orders of magnitude. Metamorphic fluids react with the surrounding rock during fluid flow, and altered zones are commonly observed adjacent to high-flux conduits. Fluid-altered rock is texturally, mineralogically, chemically, and isotopically different from rock unaffected by fluid flow. In this thesis, fluid-rock interaction is studied at two localities in the Scottish Highlands: Glen Esk and the Isle of Islay. Glen Esk is one of the type localities used by George Barrow (1853-1932) to propose the concept of metamorphic zones and metamorphic index minerals as an approximate determination of metamorphic grade. In several of the metamorphic zones in Glen Esk, index mineral distribution is highly dependent on proximity to veins. The occurrence of index minerals is therefore not only controlled by pressure and temperature, but also by the availability of metamorphic fluids. Evidence of a retrograde fluid flow event from the North Esk Fault is observed in Glen Esk, for which a time-averaged fluid flux of 0.0003 – 0.0126 m3∙m-2∙yr-1 is calculated. The duration of the fluid event is estimated to between 16 and 334 kyr. On the Isle of Islay, kyanite is observed in rocks of chlorite or lower-biotite metamorphic grade, i.e. much lower temperatures than usually associated with kyanite formation. The favoured explanation for this is retrograde infiltration of extremely high-CO2 fluids, at least locally XCO2 &gt; 0.7, at ~340°C, which altered these rocks and stabilised kyanite in a carbonate-bearing assemblage. Oxygen and carbon stable isotope profiles across the Islay Anticline reveals highly channelized fluid flow along the axial region of this fold, with fluid:rock ratios at least four times higher than in rock farther away from the fold. Although carbon and oxygen isotope ratios of metacarbonate rocks were altered along the Islay Anticline, negative anomalies observed below and above the Port Askaig Tillite Formation cannot solely be attributed to metamorphic fluid flow, which implies that these rocks to varying degree retain their primary paleoclimatological isotopic signatures. / Stora volymer H2O och CO2 frigörs som fluider under prograd metamorfos. Metamorfa fluider har lägre densitet än det omgivande berget, varför de stiger genom jordskorpan mot jordytan. Metamorfa fluider kanaliseras i permabla lager, skjuvzoner, veckaxlar, sprickor och andra högflödeszoner. Kanaliserade fluidflöden kan vara flera storleksordningar högre än bakgrundsvärdet för fluidflöde inom en bergart. Metamorfa fluider reagerar under transport med det omgivande berget och bildar fluidomvandlade zoner i anslutning till högflödeskanaler. Fluidomvandlat berg uppvisar texturella, mineralogiska, kemiska och isotopsammansättningsmässiga skillnader i jämförelse med berg som inte utsatts för fluidomvandling. I denna avhandling behandlas reaktioner mellan fluid och berg som studerats i två lokaler i de skotska högländerna: Glen Esk och Islay. Glen Esk är en av de typlokaler som George Barrow (1853-1932) använde för att lägga fram konceptet om metamorfa zoner och metamorfa indexmineral som används för att ungefärligt uppskatta metamorf grad. I flera av de metamorfa zonerna är förekomsten av indexmineral i hög grad beroende av närhet till kvartsådror, vilket visar att bildandet av indexmineral inte bara styrs av tryck och temperatur, utan också av åtkomst till metamorfa fluider. I Glen Esk finns också spår av ett fluidflöde från North Esk-förkastningen, under retrograda metamorfa förhållanden, för vilket mededfluidflödet över tid uppgår till 0.0003 – 0.0126 m3∙m-2∙år-1. Denna fluidflödeshändelse beräknas ha pågått mellan 16 000 och 334 000 år. På ön Islay i de sydvästra högländerna återfinns bergarter, som trots sin låga metamorfa grad i klorit- eller biotitzonen innehåller mineralet kyanit, dvs. temperaturer långt under vad som vanligen associeras med kyanitbildning. Detta förklaras med infiltration av fluider med extremt hög CO2-halt, åtminstone lokalt så högt som XCO2 &gt; 0.7, vid ca. 340°C. Fluidomvandling av dessa bergarter stabiliserade kyanit tillsammans med karbonatmineral. Syre- och kolisotopprofiler över Islayantiklinen påvisar hög kanalisering av fluider längs dess veckaxeln. Förhållandet mellan fluid och berg var mer än fyra gånger så högt i närheten av veckaxeln jämfört lokaler längre ifrån densamma. Påverkan av metakarbonatbergarters isotopförhållanden har skett längs Islayantiklinen, men fluidpåverkan kan inte ensamt förklara de isotopanomalier som observerats under och ovan Port Askaig-tilliten, varför dessa bergarter kan ha bibehållit sin primära paleoklimatologiska isotopsignatur. / <p>At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 2: Submitted. Paper 3: Manuscript.</p>

Cretaceous continental extension was accommodated by the development of the Paparoa Metamorphic Core Complex, resulting in the separation of New Zealand from Gondwana. High grade (Lower Plate) and low grade (Upper Plate) rocks are separated by the Ohika and Pike Detachment Faults. The two detachment faults have distinctly different histories, with greater exhumation along the Pike Detachment Fault. The onset of crustal extension is proposed to have commenced along the Pike Detachment Fault at 116.2 ± 5.9 Ma (Rb/Sr dating). Both geochemical and geochronological approaches are adopted for this thesis, through the in situ analysis of oxygen and hafnium isotope ratios, trace metals and U-Pb content. Chemical changes are tracked during the petrogenesis of the Buckland Granite, with mafic replenishment observed in the later stages of crystallisation. Crystallisation temperatures of the Buckland Granite are calculated using zircon saturation thermometry, with an average Ti-in-zircon temperature of 697℃ (upper-amphibolite facies). Inherited zircons in Lower Plate rocks show distinct age peaks at c. 1000, 600 and 300 Ma, illustrating the incorporation of heterogeneous local crust (Greenland Group and Karamea Batholith). Model ages (TDM) are calculated for inherited zircons of the Lower Plate rocks, which record the time at which magma bodies (zircon host rocks) were extracted from the mantle. Maximum and minimum model ages for the Buckland Granite average at 3410 Ma and 2969 Ma, with the maximum TDM value of 3410 Ma coinciding with the proposed major crustal formation event of the Gondwana supercontinent at c. 3.4-3.5 Ga. Two distinct U-Pb zircon age peaks are observed in the Buckland Granite at 102.4 ± 0.7 and 110.3 ± 0.9 Ma. The 110.3 ± 0.9 Ma age is interpreted as the crystallisation age of the pluton, while the 102.4 ± 0.7 is proposed to represent a younger thermal (magmatic?) event associated with the 101-102 Ma Stitts Tuff.

No description available.

Thesis (M.Sc.)--Memorial University of Newfoundland, 2005. / The CD-ROM contains Appendices 1-4 in MSWord format. Includes bibliographical references. Also available online.

Thesis (Ph. D.)--University of Texas at Austin, 2000. / Vita. Includes bibliographical references.

Thesis (Ph.D.)--Memorial University of Newfoundland, 2002. / Bibliography: leaves R1-R38. Also available online.

The Aegean region contains numerous metamorphic core complexes that reflect post-collision extensional tectonics. The largest of these is the Menderes Massif of western Turkey, which covers an area of ~40,000 km². The Selimiye Shear Zone bounds its southern border and is a key location for studying the metamorphic history of the massif. Models of the tectonic evolution of the region requires an understanding of the peak pressure-temperature (P-T) conditions recorded by rocks in the massif, and the time (t) at which they achieved those conditions. However, limited P-T-t data exists in the Southern Menderes Massif. Here, P-T-t data was obtained from garnet-bearing rocks collected perpendicular to strike along seven transects spaced about 35 km across the Selimiye Shear Zone. Garnets in nine samples from four transects were analyzed using high-resolution back-scattered electron (BSE) imagery, X-ray element (Fe, Mg, Mn, Ca and Y) maps, and quantitative compositional analyses. Both zircon and monazite grains were dated in rock thin section using Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) and Secondary Ion Mass Spectrometry (SIMS) to ascertain the timing of events recorded by the rocks. Some garnet X-ray element maps show zoning consistent with multiple stages of growth, diffusion, and retrogression. Distinct zones in each sample are visible on high contrast BSE images and can be related to Y, Fe, and Mn contents. The conventional garnet + biotite geothermometer and garnet + plagioclase + muscovite + biotite geobarometer were used to estimate peak metamorphic P-T conditions. These range from 556±10°C to 671±27°C, and 15.3±0.2 kbar to 22.4±0.5 kbar. The temperatures are similar to previous estimates, but the pressures appear about ~10 kbar higher the previous estimates. U-Pb zircon ages range from 2022±30 Ma (13.4% disc.) to 254±5 Ma (13.4% disc.). Based on Th/U contents, the oldest ages are likely related to inherited grains from magmatic sources. The youngest zircon age is the first reported Triassic grain from the Southern Menderes Massif and may relate to the closure event of the Paleo-Tethyan Ocean. A younger history is recorded by U-Pb and Th-Pb monazite ages, which range Cretaceous to Miocene. Monazite geochronology is hindered by the contamination of high amounts of common Pb, but U-Pb and Th-Pb age calculations show Miocene to Jurassic ages. The textures of monazite (i.e. drusy, filling cracks of garnet and in reaction with allanite) imply that ages could record crystallization and/or fluid dissolution/reprecipitation mediated events in the Oligocene. Data reported here support the observation that polymetamorphic events are recorded in the Southern Menderes Massif rocks in close proximity to the Selimiye Shear Zone. Two options are possible environments of continental exhumation of rocks along the zone: (1) a polymetamorphic history that records relict high-pressures from previous metamorphic events or (2) a single-stage exhumation of high-pressure rocks. / text

The Aegean region contains numerous metamorphic core complexes that reflect post-collision extensional tectonics. The largest of these is the Menderes Massif of western Turkey, which covers an area of ~40,000 km². The Selimiye Shear Zone bounds its southern border and is a key location for studying the metamorphic history of the massif. Models of the tectonic evolution of the region requires an understanding of the peak pressure-temperature (P-T) conditions recorded by rocks in the massif, and the time (t) at which they achieved those conditions. However, limited P-T-t data exists in the Southern Menderes Massif. Here, P-T-t data was obtained from garnet-bearing rocks collected perpendicular to strike along seven transects spaced about 35 km across the Selimiye Shear Zone. Garnets in nine samples from four transects were analyzed using high-resolution back-scattered electron (BSE) imagery, X-ray element (Fe, Mg, Mn, Ca and Y) maps, and quantitative compositional analyses. Both zircon and monazite grains were dated in rock thin section using Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) and Secondary Ion Mass Spectrometry (SIMS) to ascertain the timing of events recorded by the rocks. Some garnet X-ray element maps show zoning consistent with multiple stages of growth, diffusion, and retrogression. Distinct zones in each sample are visible on high contrast BSE images and can be related to Y, Fe, and Mn contents. The conventional garnet + biotite geothermometer and garnet + plagioclase + muscovite + biotite geobarometer were used to estimate peak metamorphic P-T conditions. These range from 556±10°C to 671±27°C, and 15.3±0.2 kbar to 22.4±0.5 kbar. The temperatures are similar to previous estimates, but the pressures appear about ~10 kbar higher the previous estimates. U-Pb zircon ages range from 2022±30 Ma (13.4% disc.) to 254±5 Ma (13.4% disc.). Based on Th/U contents, the oldest ages are likely related to inherited grains from magmatic sources. The youngest zircon age is the first reported Triassic grain from the Southern Menderes Massif and may relate to the closure event of the Paleo-Tethyan Ocean. A younger history is recorded by U-Pb and Th-Pb monazite ages, which range Cretaceous to Miocene. Monazite geochronology is hindered by the contamination of high amounts of common Pb, but U-Pb and Th-Pb age calculations show Miocene to Jurassic ages. The textures of monazite (i.e. drusy, filling cracks of garnet and in reaction with allanite) imply that ages could record crystallization and/or fluid dissolution/reprecipitation mediated events in the Oligocene. Data reported here support the observation that polymetamorphic events are recorded in the Southern Menderes Massif rocks in close proximity to the Selimiye Shear Zone. Two options are possible environments of continental exhumation of rocks along the zone: (1) a polymetamorphic history that records relict high-pressures from previous metamorphic events or (2) a single-stage exhumation of high-pressure rocks. / text