This research is an exploration both of the Precambrian metamorphic geology of south-western Montana and the Wlaser ablation microprobe ^4OAt-³⁹At geochronological technique. Using the high spatial resolution of the UV laser microprobe it has been possible to produce systematic ^4OAt-³⁹Ar ages within individual mica grains. Further, the UV laser has been used to drill into biotite inclusions within garnet to look at the shielding effect of the garnet lattice, and to drill depth profiles into garnet to measure helium diffusion in laboratory experiments. The south-western Montana region of the Precambrian Wyoming Province was believed to have undergone at least three separate periods of metamorphism: M1- granulite facies in the Archaean, M2 - amphibolite facies in the Early Proterozoic, and M3 - greenschist to epidote-amphibolite facies in the Mid-Proterozoic. Because of the relatively low blocking temperature of the 40Ar- 39Ar geochronological system in mica (c.300-350 °C), it is readily reset by regional metamorphic events and previous K-Ar and 4OAr_38 Atgeochronology had found that the Early Proterozoic event dominated the ages obtained. UV laser 40Ar-39At dating of the matrix mica constrained the timing of cooling from the Early Proterozoic metamorphic event to between 1780 to 1740 Ma with a cooling rate between 1 and 8 °C/m.y. 4OAr_39Ar analyses of individual biotite inclusions in garnet also produced similar ages. However, Pb-Pb step leach dating of a small subset of garnet yielded ages between 1808 and 1765 Ma, demonstrating that the garnet did not grow during an Archaean event but, rather, during the Early Proterozoic metamorphic event. Thus, the shielding properties of garnet on biotite inclusions could not be easily assessed in these samples. However, where matrix biotite had been partially reset by the Cretaceous plutons, there was some evidence to suggest that a minority of the biotite inclusions in the same sample had been shielded from resetting. The influence of fractures, defects and other fast diffusion paths is believed to have prevented most of the inclusions from being shielded. No evidence was found to show that the rocks in south-western Montana were metamorphosed during the Archaean and it seems likely that the M1 and M2 events were not greatly separated in time and were both Early ProterozoiC in age. The high spatial resolution of the UV laser microprobe was used in order to date highly altered biotite within rocks that had undergone later (M3) greenschist metamorphism. Biotite was interlayered with chlorite, clinozoisite and prehnite but using the UV laser it was possible to separately analyse areas of unaltered biotite and areas of alteration within a single mineral and produce ages from both. It was thus possible to measure two ages from one sample: an unaltered age consistent with the timing of the Early Proterozoic metamorphism, and a younger age that could be linked to the c.1500-1360 Ma timing of Belt basin formation to the north and west of the region. This technique therefore was able to overcome the difficulties associated with producing meaningful ages from altered samples whilst constraining the timing of the M3 metamorphic event.