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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
91

The infra-red absorption spectrum of methyl alcohol

Borden, Avis, January 1900 (has links)
Thesis (Ph. D.)--University of Michigan, 1938. / Cover title. "Reprinted from the Journal of chemical physics, vol. 6,no.9, September, 1938." Includes bibliographical references.
92

Regulation of methanol oxidation genes in Methylobacterium extorquens AM1 /

Zhang, Meng, January 2004 (has links)
Thesis (Ph. D.)--University of Washington, 2004. / Vita. Includes bibliographical references (leaves 106-121).
93

Fuel processing catalysis for microchannel applications

Dagle, Robert Alexander, January 2005 (has links) (PDF)
Thesis (M.S. in chemical engineering)--Washington State University. / Includes bibliographical references.
94

The solvation of chromium(III) ion in methanol-water solutions

Jayne, Jerrold Clarence, January 1963 (has links)
Thesis (Ph. D.)--University of Wisconsin--Madison, 1963. / Typescript. Vita. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references.
95

Experimental investigations of the anode flow fields of micro direct methanol fuel cells /

Wong, Chung Wai. January 2005 (has links)
Thesis (M.Phil.)--Hong Kong University of Science and Technology, 2005. / Includes bibliographical references (leaves 100-110). Also available in electronic version.
96

Density functional studies relevant to methanol steam reforming on PdZn

Lim, Kok Hwa. Unknown Date (has links)
Techn. University, Diss., 2006--München.
97

Electrocatalytic and fuel processing studies for portable fuel cells

Matter, Paul H., January 2006 (has links)
Thesis (Ph. D.)--Ohio State University, 2006. / Title from first page of PDF file. Includes bibliographical references (p. 304-330).
98

Fuel reforming for fuel cell application /

Hung, Tak Cheong. January 2006 (has links)
Thesis (M.Phil.)--Hong Kong University of Science and Technology, 2006. / Includes bibliographical references. Also available in electronic version.
99

Síntese e caracterização da peneira molecular SAPO-34 para reação de obtenção de olefinas leves a partir de metanol / Synthesis and characterizaton of molecular sieve SAPO-34 for the production of light olefins from methanol

Anjos, William Lima dos, 1977- 19 August 2018 (has links)
Orientador: Gustavo Paim Valença / Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Química / Made available in DSpace on 2018-08-19T15:00:40Z (GMT). No. of bitstreams: 1 Anjos_WilliamLimados_M.pdf: 3114140 bytes, checksum: 2d5b6af4d6d95550df4f2b5f509c8353 (MD5) Previous issue date: 2011 / Resumo: A peneira molecular SAPO-34 foi sintetizada pelo método de cristalização hidrotérmica com razões molares de 'SiO IND. 2/Al IND. 2 O IND. 3' (SAR) de 0,3, 0,5 e 0,7. As amostras foram secas e calcinadas para serem utilizadas na reação catalítica de conversão de metanol para olefinas leves (eteno e propeno). Os sólidos foram caracterizados e foi observado através da técnica de difração de raios-X que a fase chabasita (CHA) correspondente à peneira molecular SAPO-34 foi formada. A fase AlPO-5 (AFI) também foi observada como fase contaminante deste zeólito. As medidas de área superficial (BET) obtidas através da adsorção de N2 apresentaram valores para a SAPO-34 com SAR de 0,3, 05 e 0,7 de 549, 337 e 122 m2 g-1, respectivamente, sugerindo que ocorrem reduções significativas das áreas superficiais quando o teor de Si é aumentado. Com os resultados de microscopia eletrônica de varredura foram observados estruturas uniformes cúbicas e romboédricas típicas da morfologia da SAPO-34. Os testes catalíticos foram realizados em fase gasosa em reator de leito fixo construído em quartzo nas temperaturas de 600, 625, 650, 675, 700, 725 e 750 K para a SAPO-34 com SAR de 0,3 e 700 e 750 K para SAPO-34 com SAR de 0,5 e 0,7. A massa de catalisador utilizada foi de 0,020 g com pressão de vapor de metanol de 0,04 bar e fluxo de nitrogênio de 160 mL 'min POT.-1', fornecendo um WHSV (Weight Hourly Space Velocity) de 1,47 x10-1 s-1 e um tempo de contato (razão W/F) de 0,05 g h mol-1. Os produtos identificados por cromatografia gasosa com a coluna empacotada Porapak - Q foram água, metano, eteno e propeno, quantificados a partir de curvas de calibração obtidas pela injeção de padrões de alta pureza cromatográfica. O dimetiléter foi quantificado a partir do balanço de massa obtido a partir dos coeficientes estequiométricos da reação em função da água. O catalisador que apresentou maior rendimento inicial a propeno e eteno foi a SAPO-34 com SAR de 0,3 nas temperaturas de 675, 725 e 750 K que foram superiores a 80%, enquanto os outros dois catalisadores (SAR de 0,5 e 0,7) apresentaram rendimentos inferiores a 70%. Foram realizados também estudos de atividade catalítica para determinação das constantes de desativação da equação de Voorhies e determinação da ordem de desativação catalítica / Abstract: The molecular sieve SAPO-34 was synthesized by hydrothermal crystallization with molar ratios of 'SiO IND. 2/Al IND. 2 O IND. 3' (SAR) of 0.3, 0.5 and 0.7. The samples were dried, calcined and characterized in order to be used in the catalytic conversion of methanol to light olefins (ethylene and propylene). The formation of the chabazite (CHA) phase, corresponding to SAPO-34, was proved by X-Ray diffraction analysis, as well as the contamination of the zeolite with the AlPO-5 (AFI) phase. Nitrogen adsorption showed BET surface areas for the SAPO-34 with SAR of 0.3, 0.5 and 0.7 of 549, 337 and 122 m2 g-1, respectively, suggesting that the surface area decreases significantly with a rising Si content. Uniform cubic and rhombohedral structures, typical for the SAPO-34 morphology, were observed by scanning electron microscopy. Catalytic tests were carried out in gas phase in a fixed bed quartz reactor at various temperatures between 600 and 750 K for SAPO-34 with a SAR of 0.3 and at 700 and 750 K for SAPO-34 with SARs of 0.5 and 0.7. The utilized catalyst mass was 0.020 g, the methanol vapor pressure was 0.04 bar and the total flux of methanol and nitrogen added up to 160 mL min-1, resulting in a weight hourly space velocity (WHSV) of 1,47 × 10-1 s-1 and a mass/flow ratio (W/F) of 0.05 g h mol-1. The reaction products, identified by gas chromatography employing a packed Porapak - Q column and quantified with calibration curves obtained by injection of highly pure standard samples, were water, methane, ethylene and propylene. The quantification of dimethyl ether was based on the mass balance and the reaction stoichiometry as a function of water. The catalyst exhibiting the highest initial ethylene and propylene yield was a SAPO-34 with a SAR of 0.3 at temperatures of 675, 725 and 750 K, reaching more than 80% yield, while the other catalysts (SARs of 0.5 and 0.7) showed yields of less than 70%. Studies of catalytic activity also were carried out in order to determine the deactivation constants of the Voorhies' equation and the order of catalytic deactivation / Mestrado / Desenvolvimento de Processos Químicos / Mestre em Engenharia Química
100

Scale-up of the solid polymer electrolyte reactor for electro-organic synthesis

Girt, Robert Stephen January 1997 (has links)
Electro-organic reactions are often complicated by the need to add supporting electrolytes and co-solvents. In many cases these additives take part in side reactions causing low yields and hinder the purification stages. The solid polymer electrolyte (SPE) reactor uses an ion exchange membrane to transfer charged species between the electrodes and so eliminates the need for any additives. In this way improvements in electrochemical processing can be achieved. The SPE reactor has only been studied for model organic and aqueous based electrochemical reactions. The aims of this project were to develop the reactor for use as a suitable means of synthesising alcohols and acids based on substituted toluenes. This involved selection of suitable electrode material, polymer electrolyte pre-treatment and reactor modelling. According to published reports the direct electro-oxidation of toluene takes place with maximum yields of 19% with an acetic acid co-solvent and a nitric acid supporting electrolyte. Higher yields are possible with inorganic mediators such as Mn³⁺ and Cr⁶⁺. 30% yields of methoxylated products are possible from electrolysis in methanol although many non volatile by-products are formed. Initial research was spent investigating the oxidation of toluene in sulphuric acid at a lead dioxide rotating disk electrode. It was found that the reaction is mass transfer limited in the potential region below gas evolution. The order of reaction with respect to toluene was 0.5. Electrolysis of toluene on platinum mesh in nitric acid with and without acetic acid was found to produce benzyl alcohol and benzaldehyde with low current efficiencies. Without co-solvent the maximum current efficiency was 10% at 2S0Alm². An SPE reactor fabricated from glass with an active electrode area of Scm2 was used to perform electrode tests. Highest yields of benzaldehyde were obtained using nickel foam, graphite felt and palladium coated mesh electrodes. The current efficiencies were 52.4%, 20.3% and 10.7% respectively. This work highlighted the need for a good membrane-electrode contact. The oxidation of benzyl alcohol in the same reactor using nickel foam Abstract was accomplished with a current efficiency of 85.4% showing that the difficult step in the oxidation of toluene was the first one to benzyl alcohol. Pre-treatment of the membrane by swelling in solvents was considered to be an important factor in the performance of the SPE reactor. Several ion exchange membranes were pre-treated in a variety of aqueous and organic solvents including methanol, toluene, DMF, water and sulphuric acid. Nafion® 117 was found to increase in size more than the other tested membranes in all solvents except water and sulphuric acid. Many of the pre-treated membranes were tested in an SPE reactor made from steel with an active electrode area of 2lcm2 for the oxidation of toluene in methanol. The anode-membrane potential was measured as a function of time and current density with Nafion® 117 having the lowest values of potential. Selection of the pre-treatment method for future use was determined by assessing the performance in the reactor, contamination of products and chemical hazards. Swelling in aqueous solvents was the chosen procedure. The steel SPE reactor was operated in continuous mode with recycle for the oxidation of toluene in methanol. Galvanostatic electrolysis took place at several current densities, temperatures and feed concentrations. Two products were identified as ⍺-methoxytoluene and ⍺,⍺-dimethoxytoluene and these were formed at low current efficiencies between 1.4% and 9%. The main product was thought to be an oligomer of toluene. The gas generated was found to be mainly hydrogen with a small amount of oxygen thought to come from residual water in the pre-treated membrane. A computer simulation of the SPE reactor for toluene oxidation in methanol was based on two series and one parallel reaction. These were first order in reactant species and followed Tafel type kinetics. Mass transfer of dilute reactants was based on Fickian diffusion. Parameters not available in the literature such as membrane potential and electro-osmotic flow were correlated to applied variables using experimental data and multiple linear regression. The importance of electro-osmotic flow in the SPE reactor was demonstrated by considering its effect on product distribution. The model showed that the oligomerisation of toluene was the dominant reaction making the SPE reactor unsuitable for the oxidation of toluene.

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