The Late Triassic platform carbonates of the Transdanubian Range, Hungary were part of a passive margin platform at the southwestern end of the Triassic Tethys now occurs in a single fault-bounded terrain. The Hungarian platform is made up of meter-scale, precessional (~20 k.y.) carbonate cycles. It contains a lower unit, the Main Dolomite Formation (600-1500m thick), which is totally dolomitized. It is overlain by the Transitional Unit (150-400m thick). The overlying Dachstein Limestone is up to 800m thick. The platform is a cyclic succession of subtidal carbonate, laminated tidal flat limestone or dolomitic caps, and reddish or greenish paleosols or reworked paleosols. The Triassic was a time of global greenhouse conditions and Milankovitch climate forcing has been well documented from lakes and off-shelf facies. The Triassic Hungarian carbonate platform records an imperfect Milankovitch eustatic signal. They lack the bundling of 5 precessional cycles into 100 k.y. eccentricity cycles or 20 cycles/400 k.y. bundle. This is interpreted to be due to many missed beats evidenced by caliches and paleosols, and thick amalgamated subtidal carbonates. These result from precessional sea-level fluctuations either not flooding the platform, or flooding it too deeply to allow shallowing up to sea-level in one precessional beat. Spectral analysis of the Hungarian carbonates was used to compare the amplitude spectra of different time series including lithology, gamma ray, self potential and neutron density. The spectra based on lithology were compared to synthetic spectra generated by computer from platforms subjected differing Milankovitch signals. Most dolomitization of the Hungarian carbonates occurred early in tidal flat settinfs during each high frequency cycle. Intertidal-supratidal dolomites are fine grained, Fe²⁺ and Mn²⁺ rich and slightly enriched in δ¹⁸O compared marine calcite cement, and formed from weakly to moderately reducing marine waters. Subtidal dolomites are slightly coarser grained, low in Fe²⁺ and Mn²⁺ and have heaviest d¹⁸O signatures, indicating more evaporative oxidizing brines beneath flats. Repeated emergence stabilized the dolomites to low Sr²⁺ and Na⁺ types similar to Cenozoic dolomites. Later, coarse-grained dolomites with very low Mn²⁺ Fe²⁺ and light δ¹⁸O signatures were formed along the platform margin by thermally driven, warm oxidizing marine water associated with Jurassic rifting of the Pennini Ocean (Neo-Tethys). The overall vertical distribution of early dolomite on the platform does not reflect long term ecstasy. Instead the regional stratigraphic trends in climatically sensitive sediments, as well as stable isotopes, suggest that intense dolomitization of the lower platform reflects a semi-arid, hot subtropical setting and megamonsoonal climate. Global cooling and increased humidity toward the latest Triassic and Early Jurassic, inhibited pervasive early dolomitization, leaving the upper platform little dolomitized. / Ph. D.

The Late Cretaceous–early Paleogene is the most recent period of Earth history with a dynamic carbon cycle that experienced sustained global greenhouse warmth and can offer a valuable insight into our anthropogenically-warmer future world. Yet, knowledge of ambient climate conditions and evolution of the carbon cycle at this time, along with their relation to forcing mechanisms, are still poorly constrained. In this thesis, I examine marine sediments recovered from the South Atlantic Walvis Ridge (ODP Site 1262) and Indian Ocean Ninetyeast Ridge (IODP Site U1443 and ODP Site 758), to shed new light on the evolution of the climate and carbon cycle from the Late Maastrichtian through to the Early Eocene (~67.10–52.35 Ma). The overarching aims of this thesis are: 1) to identify the long-term trends and principle forcing mechanisms driving the climate and carbon cycle during this time period, through construction of 14.75 million-year-long, orbital-resolution (~1.5–4 kyr), stratigraphically complete, benthic stable carbon (δ13Cbenthic) and oxygen (δ18Obenthic) isotope records; 2) to investigate in more detail the climatic and carbon-cycle perturbations of the Early–Middle Paleocene (e.g., the Dan-C2 event, Latest Danian Event and the Danian/Selandian Transition Event) and place these in their proper (orbital) temporal context; 3) to investigate the Late Maastrichtian warming event and its relationship to the eruption of the Deccan Traps Large Igneous Province, as well as its role (if any) in the subsequent Cretaceous/Paleogene (K/Pg) mass extinction; 4) to provide the first orbital-resolution estimates of temperature and carbonate chemistry variability from the low latitude Indian Ocean spanning the Late Paleocene–Early Eocene, through analysis of trace element and stable isotope data from multiple foraminiferal species. Taken together, the results presented in this thesis provide a critical new insight into the dynamic evolution of the climate and carbon cycle during the greenhouse world of the early Paleogene, and shed light on the potential forcing mechanisms driving the climate and carbon cycle during this time.