The Star Fire Coal Mine is a large strip mining operation (10,000 acre permit) that produces mine spoil consisting of sandstones, shales, siltstones, and underclays of the Pennsylvanian Breathitt Formation. Chemical analysis of groundwater from the saturated mine spoil show unusually high magnesium concentrations, with magnesium constituting between 27 and 47 percent of the major cations. Excess magnesium in water is detrimental to plant metabolism, and its content in groundwater may limit its use for irrigation and other uses during a post-mining land use plan. Petrological methods (thin section point count analysis and x-ray diffraction) and geochemical methods (electron microprobe analysis and water extraction experiments) were performed to determine the source of magnesium in sandstone and shale samples of the Breathitt Formation. Based on mineral percents and concentrations of magnesium found in samples used for waterrock interaction samples, magnesium-rich siderite was found as the primary contributor of magnesium to the groundwater. / Department of Geology