A Ni(II)-dimethylglyoxime ion imprinted polymer {Ni(II)-DMG IIP} was synthesized by the trapping method using the bulk polymerisation format. The structures of the imprinted and non-imprinted polymer were evaluated by infrared spectroscopy and the morphology was observed by scanning electron microscopy. The Ni(II)-DMG IIP was optimised for pH, mass, time and by the uniform design experimental method for the molar ratios of monomer to crosslinker to porogen and template to ligands as well as keeping these parameters constant and varying the quantities of initiator, 2,2'-azobisisobutyronitrile (AIBN). The optimum pH was 8.5, optimum mass was 50 mg, optimum time was 1 min and the optimum molar ratios of crosslinker to monomer, monomer to template and nickel(II) sulfate hexahydrate (NiSO₄.6H₂O) to 4-vinylpyridine to dimethylglyoxime were found to be 3.3:1.0, 0.6:1.0 and 1.0:0.6:3.6 respectively with 30 mg and 8 mL as the optimum amounts of initiator and porogen respectively. Through this optimisation, recovery of Ni(II) was increased from 98 to 100%. Selectivity of the ion imprinted polymer was evaluated by analysing, using an inductively coupled plasma-optical emission spectrometer, for Ni(II) ions that were spiked with varying concentrations of Co(II), Cu(II), Zn(II), Pd(II), Fe(II), Ca(II), Mg(II), Na(I) and K(I) in aqueous samples. Selectivity studies also confirmed that the ion imprinted polymer had very good selectivity characterised by % RSD of less than 5 %. Co(II) was the only ion found to slightly interfere with the determination of Ni(II). The limits of detection and quantification were found to be 3x10⁻⁴ μg/mL and 9x10⁻⁴ μg/mL respectively. The method was evaluated by a custom solution of ground water certified reference material (SEP-3) and sandy soil reference material (BCR-142R) and the concentrations of Ni(II) obtained were not significantly different to the certified ones. The Ni(II)-DMG IIP was then evaluated in aqueous and soil samples where recoveries of 93 to 100% and 98 to 99% respectively were obtained with enrichment factors ranging from 2 to 18 in aqueous and 27 to 40 in soil samples. Finally, the Ni(II)-DMG IIP was used to analyse mine tailings samples and Ni(II) recovery of 99% was obtained with an enrichment factor of 2.

Vegetation establishment on mine wastes is ultimately limited by the edaphic properties of the wastes. This thesis examines, characterizes and interprets the physical properties of some southern British Columbia mine wastes:- to elucidate the feasibility of various reclamation procedures. Vaste areas, including both mill tailings, rock dumps and adjacent natural soils are characterized. The project primarily addresses three areas in British Columbia affected by sulfide mining activities; the Princeton area, the Highland Valley area and the Kimberley area. Waste materials examined were derived from the Similkameen, Copper Mountain, Lornex, Bethlehem and Sullivan mines. Minor examination of the now revegetated Jersey Mine tailings located near Salmo, B.C. was also included. Field work involved mapping waste materials and natural soils and then systematically sampling the various units delineated. Laboratory methods were employed to define and compare the properties of samples collected. Limited water storage capacity was found to be a major problem in waste rock dump material. Mill tailings were found to have acceptable available water storage capacities. Some mill tailings may have aeration porosity deficiencies when wet. Cation exchange capacities, while usually adequate in waste rock dump materials, are sometimes very low in mill tailings; a factor that will present serious fertility problems in revegetation. Some adjacent coarse coniferous forest soils were found to have similar properties to waste rock dump material while some adjacent grass dominated soils were found to have similar properties to the mine tailings. Waste rock dump material appears best suited to eventual revegetation by aborescent species, while mill tailings appear best suited to eventual revegetation by grass or forb species. Soil processes were found to be both active and rapid in both types of waste material. / Land and Food Systems, Faculty of / Graduate

A thesis submitted to the School of Animal, Plant and Environmental Sciences (APES), University of the Witwatersrand, Johannesburg, South Africa in fulfilment of the academic requirements for the degree of Doctor of Philosophy Johannesburg, February 2013 / Decades after the commencement of modern mining in the 1870s, the South African mining industry addressed the impacts associated with its mine waste deposits. In this, it followed the pattern its international peers had set. This study aims at chronicling, for the first time, the mining industry’s efforts to develop scientifically sound and replicable methods of mine waste rehabilitation. Mindful of the limitations in accessing official and public written sources for such an applied science, the study seeks to take a broader approach: It considers factors beyond pure experimental results (of which only patchy records exist), and considers the socio-economic context or the role of certain personalities, in an effort to understand the evolution of the applied technology between the 1930s until the passage of the Minerals Act in 1991. The bulk of this mine waste rehabilitation work during this period was done by the Chamber of Mines of South Africa and its members, the gold and (later) coal miners. The focus will therefore be on these sectors, although other mining sectors such as platinum will be covered when relevant. Following decades of ad hoc experimentation, concern about impending legal pollution control requirements in the 1950s spurred key gold industry players to get ahead of the curve to head off further regulation. Their individual efforts, primarily aimed at dust suppression, were quickly combined into an industry initiative located within the Chamber of Mines. This initiative became known as the Vegetation Unit. Well resourced and managed by a dynamic leader with horticultural training – William Cook – the Unit conducted large-scale and diverse experiments between 1959 and 1963 to come up with a planting and soil amelioration methodology. The initial results of this work were almost immediately published in an effort to publicise the industry’s efforts, although Cook cautioned that this was not a mature methodology and that continued research was required. The Chamber of Mines, however, was trying to head off pending air quality legislation and in 1964/65, the organisation publicly proclaimed the methodology as mature and ready for widespread application. With this decision, the Unit’s focus shifted to widespread application while its ability to advance the methodology scientifically effectively collapsed in the 1960s and early 1970s. In addition to this shift of focus and resources to application rather than continued refinement, the Unit was constrained by non-technical and non-scientific factors: Key among them was the industry’s implicit belief, and hope, that a walk-away solution had been found. The Unit’s manager Cook stood alone in driving its application and refinement for most of his time in that position. In his day-to-day work, he lacked an industry peer with whom to discuss rehabilitation results and he compounded this isolation through limited interaction with academia until very late in his career. This isolation was amplified by the lack of relevant technical knowledge among the company representatives on the committee tasked with the oversight of the Vegetation Unit: As engineers, all of them lacked not only technical understanding of the botanical and ecological challenge, some even questioned the legitimacy of the Unit’s existence into the 1980s. In addition, the concentration of all rehabilitation efforts in this single entity structurally curtailed the individual mining companies’ interest in the advancement of the methodology, creating a further bottleneck. Indeed, as late as 1973, the key metallurgy handbook covered mine waste rehabilitation only for information purposes, specifically stating that this was the responsibility of the Chamber’s Vegetation Unit alone. To some extent, the presence of a champion within the Chamber – H. Claussen – obscured some of these challenges until the early 1970s. Indeed, the Unit had acquired additional scientific capacity by this stage, which gave it the ability to renew its research and to advance its methodology. That it failed to do so was mainly due to three factors coinciding: the retirement of its internal champion Claussen, a lack of succession planning for Cook, which left the Unit on ‘auto-pilot’ when he retired, and a rising gold price, which turned industry attention away from rehabilitation towards re-treatment of gold dumps. During this period of transition in the mid 1970s, the Chamber’s approach was thus somewhat half-hearted and vulnerable to alternative, potentially cheaper, rehabilitation proposals such as physical surface sealing advanced by Cook’s eventual successor – Fred Cartwright. Though not grounded in any science, Cartwright’s proposal gained ascendance due to his forceful personality as well as the industry’s desire for an alternative to the seemingly open-ended costs associated with the existing rehabilitation methodology. During this time, the Chamber’s structures singularly failed to protect the industry’s long-term interests: The oversight committee for the Vegetation Unit, remained largely staffed by somewhat disinterested engineers, and relied heavily on a single individual to manage the Unit. Not only did the oversight committee passively acquiesce to Cartwright’s virtual destruction of the Unit’s grassing capacity, it also allowed him to stake the Chamber’s reputation with the regulator by championing an unproven technology for about five years. Only Cartwright’s eventual failure to gain regulator approval for his – still un-proven – technique led to a reluctant abandonment by the Chamber in the early 1980s. Cartwright’s departure in 1983 left the Unit (and the industry) without the capacity to address mine waste rehabilitation, at a time when emerging environmental concerns were gaining importance in social and political spheres in South Africa and across the world. The Unit sought, unsuccessfully, to build alliances with nascent rehabilitation practitioners from the University of Potchefstroom. It furthermore failed to build mechanisms for sharing technical rehabilitation knowledge with fellow southern African or international mining chambers, leading to further stagnation of its method. At the same time, up-and-coming South African competitors such as the University of Potchefstroom seized the opportunity to enter the mine waste rehabilitation field as commercial players during the mid 1980s, at a time when the Unit had been reduced to grassing dumps for a single customer, the Department of Minerals and Energy Affairs (DMEA). Using its status as a part of the Chamber of Mines, the Unit gradually regained its position of prominence through the development of industry guidelines for rehabilitation. Yet, it would never again occupy a position of pre-eminence in practical fieldwork, as industry players, academic capacities and commercial players entered the field in the mid-1980s in response to a growing environmental movement worldwide. When the passage of the Minerals Act in 1991 formally enshrined not merely rehabilitation but environmentally responsible mine closure in law, the Unit had been reduced to a prominent but no longer dominant player in this sector. This lack of pre-eminence ultimately caused the Unit to be among the first Chamber entities to be privatised when the Chamber began to restructure. This ended its role as a central driver of applied rehabilitation techniques for the South African mining sector once and for all. As this privatisation coincided with the broader opening up of South Africa’s society and economy after the unbanning of the ANC, there would never again be an entity (commercial or otherwise) that would dominate the rehabilitation sector as the Chamber’s Vegetation Unit had done in its day.

Thesis (DTech (Chemical Engineering))--Cape Peninsula University of Technology, 2017. / Industrial wastewater management pertaining to the mining industry has become increasingly stringent, with companies being required to develop environmentally benign wastewater management practices worldwide. The industries that utilise cyanide compounds for the recovery of precious and base metals in a process known as the cyanidation process, have contributed substantially to environmental deterioration and potable water reserve contamination due to the discharge of poorly treated, or untreated, cyanide containing wastewater. Hence, a biotechnological approach was undertaken in this study to remediate free cyanide (CN-) and thiocyanate (SCN-), which are the major chemical contaminants which are normally found in cyanidation wastewaters. Furthermore, this biotechnological approach was investigated to understand the fundamental aspects of using this approach such that the information gathered can be utilized in pilot plant studies. Therefore, bioprospecting of potential CN- and SCN--degrading organisms was undertaken using two approaches; (i) culture-dependent approach and (ii) culture-independent approach. Using the culture-dependent approach, Pseudomonas aeruginosa STK 03, Exiguobacterium acetylicum and Bacillus marisflavi were isolated from an oil spill site and river sediment samples, respectively. STK 03 was evaluated for the biodegradation of CN- and SCN- under alkaline conditions. The organism had a CN- degradation efficiency of 80% and 32% from an initial concentration of 250 and 450 mg CN-/L, respectively. Additionally, the organism was able to degrade SCN-, achieving a degradation efficiency of 78% and 98% from non- and CN- spiked cultures, respectively. Furthermore, the organism was capable of heterotrophic nitrification but was unable to denitrify aerobically, with the autotrophic degradation of CN- by STK 03 being abortive.

All mine dumps are a point source of either physical, chemical or both forms of pollution. Physical pollution includes the physical site coverage of the dump, slumping of parts of the dams and dust that may originate from it (air pollution). Chemical pollution from, or related to the mine dumps include the dominant acid drainage (which contains heavy metals), radioactivity, electromagnetic radiation, noise and chemicals released from the mineral processing stage. In one way or the other, exposure to these pollution forms is detrimental to the human health and his environment. It is this fact that urges the public, government and the responsible mining companies to find ways of monitoring the pollution and stopping it, preferably at the source. Where it can not be stopped, techniques of reducing it, or containing it have been, and are still being developed. Personal protection is the priority. Pollution exposure to the general public is minimised as much as possible. Pollution control techniques that employ less expensive, natural, self-sustaining elements suitable for the environment such as wetlands and vegetation are recommended. The artificial short term and often expensive alternatives are of secondary priority. However, choice of which technique to use is based on the merit of each problem, knowing that chemicals act faster but are effective for a short period as compared to the natural systems. Pollution management is the critical part of the whole process. This involves decision making on courses of action and financial allocation on the part of both the polluter and the monitoring department/agent. The ability to effectively manage pollution programmes is achieved these days with the aid of computers. It is emphasised that pollution control should be handled in an integrated, multi-disciplinary approach manner. This is because pollution is a question of life and death, hence every individual remains accountable to it. Keeping the public and the concerned parties educated, informed and welcoming their concerns on the environmental issues related to the mine dumps generated in a mining venture is essential in the modern days of environmental public awareness, or otherwise face the public lath.

Ph.D. / Mining operations significantly influence the environment due to direct and indirect discharges of waste products into the aquatic systems. The primary aim of this study was to assess the current situation in the platinum mining area and develop a management plan to ensure that existing and potential environmental impacts caused by platinum mining and processing are mitigated. To do this, an assessment was carried out to investigate changes in critical aquatic invertebrate and fish community distributions and assess how they relate to measured environmental factors. Five sites were selected, one reference site which is upstream of heavy mining activities and four sites within heavy mining and processing activities. Standard techniques for water, sediment, invertebrate and fish sampling were used. Macro-invertebrates sampled were identified to family level whereas fish were identified to species level. Multivariate analysis used was cluster analysis by non-metric multidimensional scaling (NMDS) for both macro-invertebrates and fish. Three methods of ordination were used to analyze the biotic and abiotic data namely N-MDS, Correspondence Analysis (CA) and Canonical Correspondence Analysis (CCA). Cluster analysis of macro-invertebrates data revealed three major groups based on sampling period (low flow or high flow) and the last cluster according to the locality. Multidimensional scaling ordination of high and low flow for macro-invertebrate communities confirmed the groupings detected by cluster analysis. Cluster analysis for fish communities revealed two groups at 50% similarity; the first group is the combination of reference and exposure sites for both high and low flow sampling regimes. No fish were sampled at site 4 during both low and high flow regimes. Multidimensional scaling ordination of high and low flow fish communities confirmed the groupings detected by cluster analysis. Analysis using a similarity profile (SIMPROF) test indicated that fish communities are statistically (p=5%) the same. It was found that macro-invertebrates and fish respond differently to environmental variables.

Thesis (MScIng)--University of Stellenbosch, 2007. / ENGLISH ABSTRACT: Due to economic and environmental constraints mining operations are placed under increasing pressure to effectively manage and operate tailings disposal operations. Restrictions imposed on water usage and tailings operations footprint have led to higher density and wider particle size distribution slurries conveyed to tailings areas. One means of efficiently disposing the tailings is co-disposal. In this method a concentrated fine vehicle slurry is used to convey a coarser fraction. This produces a higher density of tailings, with a number of advantages both upstream and downstream of the tailings process. Limited research has been conducted on the effect of coarse particles on the non-Newtonian rheological properties of these slurries. This lack of information complicates the design and reliable operation of these systems. This project aims at gaining a clearer understanding as to the mechanisms involved in the addition of coarse particles to a fine clay slurry vehicle; and to provide a means of estimating the measured slurry rheological properties. A number of experiments were designed to test the slurry (both Kaolin only, and Kaolin-coarse particle mixtures) rheological properties using a Couette viscometer (for the dynamic flow properties of yield stress and plastic viscosity) and a vane instrument (for the static yield stress measurements). The slurries were prepared in varying Kaolin clay solids concentrations with reverse osmosis water. Glass beads and two types of industrial sand were used as the coarse fractions. All of the coarse particles had a similar size but varied significantly in shape. Slurry pH and temperature readings were monitored throughout the tests. Tests were done initially on clay only slurries. The rheological properties of these slurries were repeatable, and no noticeable variations of properties with time were observed. The yield stress (both static and dynamic) and plastic viscosity data were well correlated with established relationships. Coarse particles were added to the clay only slurries, and then removed. The remaining clay only slurry exhibited the same rheological properties as the initial clay only slurry. The presence of coarse particles increased all the measured rheological properties (i.e. dynamic yield stress, Bingham viscosity, and static vane yield stress) in a fashion resembling the effect of adding clay to a clay only slurry. In addition, the change in measured rheological property by addition of coarse particle was independent of the clay fraction in the clay slurry. Furthermore, with both the clay only slurries and clay and coarse sand slurries, a constant linear relationship existed between the static and dynamic yield stress. Several correlations from the literature were found to provide reasonable prediction of the rheological property variations observed. These empirical and semi-empirical models however did little to explain the mechanisms involved in coarse particle addition. A new correlation has been proposed, Residual Clay Concentration, which predicts the change in rheological property based on an additional clay concentration, which in turn is a linear function of the coarse particle concentration. The accuracy of this model further strengthens the belief that the coarse particle acts in a similar fashion to a floc. By means of a case study example the importance of selecting an appropriate model for design was illustrated. The Residual Clay Concentration method provided the most conservative results. This combined with its theoretical basis strengthens the models recommendation for use in design. / AFRIKAANSE OPSOMMING: As gevolg van ekonomiese en omgewings beperkinge word mynwese nywerhede onder toenemende druk geplaas om doeltreffende afvalstroom bestuur en operasie toe te pas. Beperkinge geplaas op water gebruik en afvalstroom area-groote ly tot hoër digthede en wyer partikel-grooteverspreidings van flodders vervoer na afval areas. Een manier om van die afval doeltreffend ontslae te raak en te berg is deur medeberging. In die metode word ‘n gekonsentreerde fyn flodder gebruik as draer van ‘n growwer partikel-fraksie. Dit ly tot ‘n hoër digtheid flodder, met verskeie voordele in beide die op – en afstroom prosesse. Beperkte navorsing is gedoen op die effek van growwe partikels op die nie-Newoniese rheolgiese eienskappe van hierdie flodders. Hierdie tekort aan informasie maak die effektiewe, betroubare bedryf en operasie van die sisteme meer ingewikkeld. Hierdie projek is daarheen gemik om ‘n beter begrip te ontwikkel met betrekking tot die meganismes betrokke in die byvoeging van growwe partikels aan ‘n fyn klei-agtige flodder draer; en om ‘n manier te voorsien wat die rheologiese eienskappe kan beraam. Verskeie eksperimente was ontwerp om die flodders (beide slegs Kaolien, en Kaoliengrowwe partikel mengsels) se rheologiese eienskappe te toets deur die gebruik van ‘n Couette-viskometer. Die Couette viskometer was gebruik om die dinamiese eienskappe (van grens-spanning, en plastiese viskositet) te meet. ‘n Vaan apparaat is gebruik om die eienskap van statiese grens-spanning te meet. Die flodders was voorberei in verskeie Kaolien konsentrasies met tru-osmosis water. Glas krale en twee tipes industriële sand is gebruik as die growwe fraksies. Al die growwe partikels het soortgelyke groottes gehad, maar het grootliks verskil in vorm. Die flodder pH en temperatuur lesings is deurentyd nagegaan. Toetse was aanvanklik gedoen op die klei-alleenlike flodders. Die gemete reologiese eienskappe van die flodders was herhaalbaar, en geen opmerkbare veranderinge van die eienskappe met betrekking tot tyd is gemeet nie. Die grens-spanning (beide statiese en dinamiese) en plastiese viskositeit is goed gekorrelleer met gevestigde verhoudinge. Growwe partikels is aan die klei-alleenlike flodders bygevoeg, en daarnae verwyder. Die oorblywende klei-alleenlike flodder het dieselfde gemete rheologiese eienskappe getoon as die oorspronklike klei-allenlike flodder. Die teenwoordigheid van growwe partikels het na ‘n toename van al die gamete rheologiese eienskappe gelei wat fisies baie soortgelyk is aan die byvoeging van klei tot ‘n klei-alleenlike flodder. Verder, met beide die klei-alleenlike en klei-growwe partikel flodders het ‘n konstante liniëre funksie tussen die statiese en dinamiese grens-spannings bestaan. Verskeie verhoudings uit die literatuur het goeie korrelasie bewerkstellig met die waargenome rheologie veranderinge. Hierdie empiriese en semi-empiriese modelle doen egter min om die megansimes betrokke in die toevoeging van growwe partikels te verduidelik. ‘n Nuwe korrelasie is voorgestel, naamlik die Residu Klei Konsentrasie. Hierdie model voorspel die verandering in reologiese eienskappe gebaseer op ‘n addisionele klei konsentrasie, wat ‘n liniëre funkise is van die growwe partikel konsentrasie. Die goeie korrelasie gesien met die model versterk die idée dat die growwe partikel in ‘n soortgelyke manier as ‘n flok gedra in die teenwoordigheid van ander flokke. Deur middel van ‘n tipiese industriële voorbeeld is die belangrikheid in die keuse van die regte korrelasie geillustreer. Die Residu Klei Konsentrasie metode het die mees konservatiewe resultate gelewer. Hierdie feit gekombineerd met die model se soliede teoreitiese beginsels versterk dit as voorgestelde korrelasie vir ontwerp.

Research was conducted at Cyprus Pima Mine, an open pit copper mine located southwest of Tucson, Arizona, in 1980 and 1981 to study the establishment of annual and perennial grasses on the slopes of copper mine tailing ponds. In 1980, the north and south slope exposures were hydroseeded with barley (Hordeum vulgare L.). Plots were capped with topsoil prior to planting or left uncapped, and mulched with wheat straw after planting or left unmulched. Desert soil was classified as Palos Verdes-Sonoita Complex and Detrital-Sonoita Complex. Barley provided a quick, temporary cover and served as a mulch for later plantings. The number of seedlings established was the same for both exposures. Barley grew taller on the north slope possibly due to cooler temperatures. Barley growth was more vigorous on mulched areas. In 1981, the same north and south slopes were hydroseeded with Lehmann lovegrass (Eragrostis lehmanniana Nees.), buffel grass (Pennisetum cilare (L.) Link), blue panicgrass (Panicum antidotale Retz.) and bermudagrass (Cynodon dactylon (L.) Pers.). Prior to planting perennials, barley residue was incorporated into the slopes using a spike-tooth chain drag and a sheepfoot roller, or was left unincorporated. Incorporation of barley residue aided in its breakdown and helped prepare a good seedbed. The spike-tooth chain drag produced better growth than the sheepfoot roller, possibly due to excessive soil compaction with the sheepfoot roller. Capping tailing slopes with desert soil produced the most significant improvements in barley and perennial grass growth. Soil analyses of pure tailing and capped tailing revealed both were low in nitrogen and phosphorus. All plots were amended with these nutrients. Organic matter, although low for both samples, was higher in the capped tailing sample. Organic matter improves soil structure and provides nutrients and its increased presence may have been the main reason for improved growth on capped slopes.

Thesis (Master of Engineering in Chemical Engineering)--Cape Peninsula University of Technology, 2018. / Acid rock drainage (ARD) is one of the most severe environmental challenges currently faced by the mining industry worldwide. ARD is formed from the oxidation of sulphide-bearing minerals, particularly pyrite, in the presence of water and oxygen. ARD generation is accelerated by the presence of naturally occurring iron and sulphur-oxidizing micro-organisms, which regenerate leaching agents that facilitate sulphide mineral oxidation. ARD pollution is characterized by a high concentration of metals and sulphates in solution, low pH and a high salt content (salinity) in the environment, contaminating soil and groundwater. In South Africa, ARD is a major challenge in the gold and coal mining industries, where millions of tons of sulphide waste rock and overburden are generated and discarded. Characterization of these waste materials is required to develop an appropriate disposal strategy to minimise the risk of pollution and the generation of ARD. Potential ARD generation prediction from waste rock depends on the precise characterization of ARD potential using Biokinetic tests. Commonly used ARD prediction methods are static and long-term kinetic tests. Static tests provide data for a worst-case scenario focussing on strong acid chemical leaching potential to give an overall acid forming potential of a sample. Such kinetic tests provide data illustrating the rate of the net acid generation capacity of mine waste. However, these tests are capital intensive and time-consuming and fail to provide adequate information on the effect of micro-organisms on the overall net acid generation capacity of mine waste. The Biokinetic test reported herein and developed at the University of Cape Town, focusses on addressing a worst case scenario provided by static tests in a cost-effective manner and reduced time frames provided for by conventional kinetic tests. This test primarily provides relative rates of ARD generation in the presence of micro-organisms within 90 days. However, the Biokinetic test is at the developmental stage and thus far, has not been consistently used for different waste ores to determine a standardised approach. Therefore, the aim of this study was to investigate the effects of microbial consortia and to develop a standardisation approach for the test for ARD formation potential using gold-bearing and copper-bearing waste rock. Additionally, to refine the Semi-continuous Biokinetic test simulation, a flow-through system where there is minimal seepage in the waste deposit, was also developed. The sulphur content of the gold and copper-bearing samples used in this study was between 2.3 and 3.15%, respectively. These waste rock samples were found to be potentially acid- forming. In the Biokinetic test, finely milled waste rock samples were slurrified, inoculated with consortia and cultured under standard bioleaching conditions. Leaching and acidification rates were monitored.

The mining industry produces vast quantities of overburden and mill tailings. In many instances the disposal of these wastes on the Earth's surface have caused local, and occasionally even regional, water resources to become contaminated. Contamination typically arises from the oxidation of metal sulfide minerals contained within these wastes. Upon oxidation these minerals release sulfate, their associated metal cations and acidity into solution. This study investigated the potential for groundwater contamination arising from a Pb/Zn tailings impoundment in the North West Province of South Africa (Pering Mine). The tailings is composed predominantly of dolomite, which imparts to the material an alkaline pH and a high acid buffering capacity. Acid-base accounting (ABA) established that the capacity of the tailings to buffer acidity surpasses any acid producing potential that could arise from pyrite (FeS2), galena (PbS) and sphalerite (ZnS) oxidation. These minerals account for about 3 to 6% of the tailings by mass. Total elemental analysis (XRF) showed that the material has high total concentrations of Fe (19083 mg kg-I), Zn (5481 mg kg-I), Pb (398 mg kg-I), S (15400 mg kg-I), Al (9152 mg kg-I) and Mn (29102 mg kg-I). Only a very small fraction of this, however, was soluble under saturated conditions. An estimation of potentially available concentrations, using the DTPA extraction method, indicated that high concentrations of Zn (1056 mg kg-I), and moderate concentrations of Pb (27.3 mg kg-I) and Cu (6.01 mg kg-I) could potentially be available to cause contamination. A number of leaching experiments were undertaken to accurately quantify the release of elements from the tailings material. These experiments were aimed at determining the potential for groundwater contamination and also provided a means whereby the long-term release of contaminants could be modelled using the convection-dispersion equation for solute transport. Four leaching treatments were investigated. Two consisted of using distilled water under intermittent and continuous flow, while a third used intermittent flow of deoxygenated distilled water to assess leaching under conditions of reduced oxygen. The.mobilisation of potential contaminants under a worst case scenario was assessed by means of leaching with an acetic acid solution at pH 2.88 (after the US Environmental Protection Agency's toxicity characteristic leaching procedure). The acid buffering potential of the tailings was considerable. Even after 8 months of weekly leaching with 1 pore volume of acetic acid solution the pH of the effluent was maintained above pH 5.90. The protracted acidity caused very high concentrations of Pb, Zn, Mu, Ca, Mg, Hg and S to be released into solution. Leaching the tailings with distilled water also caused the effluent to have noticeable traces of contamination, most importantly from S, Mg, Mu and Zn. In many instances concentrations significantly exceeded guideline values for South African drinking water. Modelling solute transport with the convectiondispersion equation predicted that sol- and Mu contamination could persist for a very long period of time. (±700 years under continuous saturated leaching), while Mg and Zn concentrations would most likely exceed recommended limits for a much shorter period of time (±300 years under the same conditions). In light of the various column leaching experiments it was concluded that seepage from the Pering tailings impoundment could cause groundwater contamination. A drill-rig and coring system were used to collect both tailings and pore-water samples from eight boreholes spread out across the tailings impoundment. These investigations showed that most of the impoundment was aerobic (Eh ranged from +323 to +454 mY) and alkaline (pH 8.0 to 9.5). This chemical environment favours sulfide oxidation and as a consequence high concentrations of S have been released into the pore-water of the impoundment (S concentrations ranged from 211 to 1221 mg r l ). The acidity released as a by-product of sulfide oxidation was being buffered by dolomite dissolution, which in turn was releasing high concentrations of Mg (175 to 917 mg r l ) and Ca (62.6 to 247 mg r l ) into solution. Metal concentrations in the pore-water were low as a result of the strong metal sorbing capacity of the tailings and possible secondary precipitation. The only metal which significantly exceeded recommended limits throughout the impoundment was Hg (concentrations were between 100 and 6000 times the recommended limit of 0.001 mg r l ). Under the current geochemical conditions it is expected that Hg, S and Mg will likely pose the greatest threat to groundwater. The main concerns associated with mine tailings are that of mine drainage and dust blow off..In order to eradicate the latter problem, the tailings impoundment at Pering Mine was covered with a layer of rocks. Modelling the water balance of the impoundment using the computer model HYDRUS-2D showed that the rock cladding has potentially increased the volume of drainage water seeping from the impoundment. In light of the leaching experiments and field work, which proved that water passing through the tailings became enriched with various potentially toxic elements, it is expected that the problem of groundwater contamination around Pering Mine has been further exacerbated by the rock cladding. It was therefore concluded that there would be a strong likelihood of groundwater contamination in the vicinity of the mine. / Thesis (M.Sc.)-University of KwaZulu-Natal, Pietermaritzburg, 2006.