Late-Archaean deformation at Ora Banda 69km northwest of Kalgoorlie, Western Australia, resulted in upright folds (D2), ductile shear zones (D3), and a regional-scale brittle-ductile fault network (D4). Early low-angle faults (D', D1), documented in the surrounding Coolgardie, Kambalda and Boorara Domains are not developed in the Ora Banda Domain, and the fabrics reflect only the latest ENE-WSW shortening event. The western limb of the regional-scale ESE- plunging Kurrawang syncline (D2), is truncated by the Zuleika Shear Zone (D3), a within- greenstone ductile shear zone located 10km southeast of Ora Banda. The shear zone has a much greater strike length (250km) than depth extent, as seismic imagery reveals a sharp truncation against a mid-crustal decollement at a depth of 6km-depth below surface. The Zuleika Shear Zone is a NW-SE trending band of anastomosing S-C mylonite zones formed in conjugate sets of NW- SE trending sinistral and N-S trending dextral shear zones. Widely distributed flattening strains and more restricted zones of non-coaxial shear in the Zuleika Shear Zone, suggest deformation-path partitioning typical of a transpressional tectonic environment. Latetectonic brittle-ductile faults (D4) cross-cut the Zuleika Shear Zone and surrounding greenstones, and hence are not Riedel structures or other lower order faults genetically related to the ductile shearing. Gold mineralisation of the Zuleika Shear Zone began during the ductile deformation (D3), continued through peak metamorphism that postdates the shearing, and finally ceased after the brittle-ductile faulting event (D4). Gold deposits are primarily located where brittle-ductile faults intersect the Zuleika Shear Zone. / Brittle-ductile faults (D4), are developed in three principal structural orientations: N-S (dextral), NE-SW (dextral) and E-W (sinistral). These faults display mutual cross-cutting relationships and were formed synchronously during a single regional shortening event. The brittle-ductile fault network is developed unevenly over the region, being localised in packets of high fracture-density referred to as structural zones. The Ora Banda structural zone is an area of high density faulting in the vicinity of Ora Banda, composed of a network of interlinked faults in which alternating ductile and brittle conditions produced cataclasite, breccia and quartz vein systems overprinting mylonite and schistosity. Other areas of high fracture-density (eg. Grants Patch and Mount Pleasant structural zones), are located within the NW-SE trending Ora Banda mafic sequence and spaced at 10km intervals to the southeast of Ora Banda. This spatial periodicity of high fracturedensity within the mafic sequence may have developed as a result of layer-parallel extension during ENE- WSW regional shortening. Gold deposits are concentrated in the Ora Banda, Grants Patch and Mount Pleasant structural zones. Gold distribution within the Ora Banda structural zone traces out the distribution of brittle-ductile faults, indicating that the fault network was the major pathway for fluid flow during mineralisation. Hydrothermal minerals are integral components of fault fabrics within the structural zone, and textures indicate that the faults were formed under conditions of high fluid pressure and, for much of the deformation, may have been fluid-generated. / At Ora Banda the Enterprise gold deposit (40 tonnes Au) highlights the control of mesoscopic- scale fractures on gold distribution. On aeromagnetic imagery, the Enterprise fault zone appears as a narrow fault structure, but at a mesoscopic-scale, it is a broad zone of interlinked brittle-ductile faults and quartz veins. Fabrics developed in the layered, differentiated dolerite host rocks of the Enterprise fault zone, range from cataclasite to banded mylonite with a major component of net- veined breccia (mesofracturing). Kinematic analyses of fault slip lineations reveal an 055 directed (ENE-WSW) maximum shortening axis during brittle-ductile faulting. Microfabrics of the faults show extensive recrystallisation with significant post-deformation recovery that may be related to late to post - tectonic intrusion of the adjacent Lone Hand Monzogranite. Deformation mechanisms indicate that the D4 event occurred at a low-to-moderate temperature, in a low strain-rate enviromnent typical of mid to upper-greenschist facies crustal conditions. Gold mineralisation in the Enterprise deposit is controlled by faults with high-grade shoot development at the intersection of faults and host rock contacts that may represent gradients in tensile rock-strength. Although gold distribution indicates that faults are a major control on mineralisation, at a microscopic-scale, the control is by a linked network of microfractures that pervades the host rocks. / Fry analysis of gold deposits within the Ora Banda mafic sequence shows clustering into groups with about 10km spacing. Coincidence of high fracture-density zones and gold deposits in 1Okm spaced-corridors reveals the regional-scale nature of gold mineralisation within the brittle-ductile fault network. Fluid-pressure gradients generated by pressure release during high-density fracturing, may have effectively increased fluid-rock ratios by focussing of metamorphic fluids through these areas. The largest gold deposits in the Ora Banda mafic sequence are hosted by 060-090 trending brittle-ductile faults with dilational textures (hydraulic breccia), and minor evidence of slip with negligible offsets. The orientation of these structures is sub-parallel to the regional axis of maximum shortening, hence an environment of fluid overpressuring in the presence of a far-field stress system produced conditions where fluid pressure is greater than or equal to the combined minimum compressive stress and the tensile rock strength. Such conditions are conducive to multiple failure episodes with fluid-pressure cycling and transient permeability as a consequence of fault reactivation. Formation of the brittle-ductile fault network occurred as a result of a delicate balance between deviatoric stress and fluid pressure, hence incremental fault development contributed to, and was a consequence of, the gold mineralisation event. / The geometric relations of shear zones, brittle-ductile faults and gold mineralised zones are similar across all scales of observation from regional to microscopic and are therefore fractal. Fractal geometry indicates that deformation and gold mineralisation are temporally and genetically associated, and this combined with the textural relationships of the gold ores indicates that the sites of gold deposition were not structurally prepared prior to mineralisation. Development of early ductile to later brittle-ductile structures indicates changing conditions of deformation typical of decreasing crustal depth, or a variation of strain rate with time. The lack of a significant change in orientation of the maximum shortening direction and continuance of gold mineralisation throughout ductile and brittle deformation events, implies that deformation was progressive during a bulk shortening that accompanied uplift of the crust.

Several deposits in the Mt Isa - Cloncurry region have been studied, including those held by Australian Resources near Selwyn (Plume, Slate Ridge, Mobs Lease and Straight Eight),in particular, with respect to cobalt and gold mineralisation. Cobalt is associated with pyrite, pyrrhotite and arsenic sulfosalts. Other cobalt deposits in the Eastern Fold Belt of the Mt Isa Block were studied; these include the Queen Sally, Lorena and the Great Australia mine. Varying styles of Co-bearing mineralisation were encountered. In the Queen Sally mine a curious vanadium - substituted heterogenite has been found. This is only the world's second reported occurrence of this mineral of the halotrichite group. At the Great Australia, primary Co mineralisation has been shown to be confined to one generation of cobaltian pyrite. Several generations of pyrite are noted for this and other deposits. / Master of Science (Hons)

Le Sud-est de la Côte d'Ivoire connaît depuis un demi-siècle une baisse exponentielle de sa surface forestière, liée à la déforestation et à l'impact du changement climatique. Les précipitations ont régressé de 15% entre 1937 et 2005 et la température de l'air connaît une légère augmentation de 0,08°C/10 ans. Pour comprendre le mécanisme de la recharge des aquifères, montrer l'impact du changement du climat et du couvert végétal sur les eaux et étudier la minéralisation des eaux de fractures du socle, 3 méthodes sont utilisées : la géochimie, la minéralogie et la télédétection. L'étude d'une image Landsat ETM+ a montré que l'aquifère du socle possède des paramètres géométriques favorables à un écoulement d'eau N-S. La minéralisation des nappes diminue d'amont en aval suivie d'une forte acidification des eaux, dues à un phénomène de dilution et de mise en solution du CO2 du sol. Sur le plan géochimique, l'étude révèle que l'enrichissement des nappes en Na+ et Ca2+ par rapport à K+ et Mg2+ est principalement lié à l'hydrolyse de l'albite pour le Na+ et de l'amphibole et de l'épidote pour le Ca2+. L'évolution du couvert végétal, depuis la période tardi-glaciaire, est marquée d'une augmentation de la teneur en 13C des eaux relativement vieilles (15 000 ans B.P) aux eaux récentes (~ 300-100 ans). La même tendance est constatée sur les teneurs en 18O et 2H des eaux du socle, témoignant ainsi des conditions particulièrement froides au début de la période post-glaciaire par rapport à celles d'aujourd'hui. Cette étude a montré que les eaux souterraines captives du socle sous le CT, ont enregistré les conditions paléoclimatiques de la Côte d'Ivoire des 15 000 dernières années.

<p>The Earth’s surface contains of 71% oceans and a large part of the global carbon cycle takes place in the oceans. In the aquatic environment, the sediment-water interface plays an important role for the mineralisation of organic material. One factor that can affect the mineralisation is resuspension. Resuspension cause mixing of surface sediments and bottom water and result in a redistribution of the sediment when it settles again. Resuspension also increases the transport of oxygen into the sediment, reduces the diffusive boundary layer surrounding particles, and enhance the nutrient uptake. Resuspension can be induced by both wave action and bottom currents and is a common physical process in both shallow coastal areas and in the deep ocean. Human impacts, such as dredging and trawling, can also cause resuspension.</p><p>The effect of resuspension on mineralisation of organic material was studied in two experiments ex situ during December to April 2004/2005. The aim for Experiment 1 was to investigate how the intensity of the resuspension event affects the degradation rate. The aim for Experiment 2 was to investigate how different concentrations of resuspended sediment affect the degradation rate of organic matter. Sediment samples were collected in December and late March at a marine field station, Askö, Sweden. Sediment and bottom water were transferred to and incubated in sealed bottles. For Experiment 1, resuspension was created in bottles with a specially designed rotary table, creating different intensity of water movements. In Experiment 2, bottles with different concentrations of sediment were put on an ordinary rotary table. The mineralisation rates were in both experiments monitored by daily sampling of sediment-water slurry, and analysed for total inorganic carbon by a gas chromatography with a thermal detector, GC-TCD.</p><p>Results from Experiment 1 did not show any clear patterns regarding inorganic carbon formation. Experiment 2 did show clear patterns for two of six replicates of mineralisation of organic material. For these replicates the mineralisation rate were low according to previous studies. However, the sediment concentration seems to not affect the mineralisation rate. For both experiments, valuable information on how to better design experiments to investigate the importance of resuspension and the effect of mineralisation of organic material was yielded. Hence, further studies are needed to continue the investigation of the importance of resuspension for the mineralisation rate of organic material, and its impacts on the nutrient fluxes in the oceans.</p>

The Earth’s surface contains of 71% oceans and a large part of the global carbon cycle takes place in the oceans. In the aquatic environment, the sediment-water interface plays an important role for the mineralisation of organic material. One factor that can affect the mineralisation is resuspension. Resuspension cause mixing of surface sediments and bottom water and result in a redistribution of the sediment when it settles again. Resuspension also increases the transport of oxygen into the sediment, reduces the diffusive boundary layer surrounding particles, and enhance the nutrient uptake. Resuspension can be induced by both wave action and bottom currents and is a common physical process in both shallow coastal areas and in the deep ocean. Human impacts, such as dredging and trawling, can also cause resuspension. The effect of resuspension on mineralisation of organic material was studied in two experiments ex situ during December to April 2004/2005. The aim for Experiment 1 was to investigate how the intensity of the resuspension event affects the degradation rate. The aim for Experiment 2 was to investigate how different concentrations of resuspended sediment affect the degradation rate of organic matter. Sediment samples were collected in December and late March at a marine field station, Askö, Sweden. Sediment and bottom water were transferred to and incubated in sealed bottles. For Experiment 1, resuspension was created in bottles with a specially designed rotary table, creating different intensity of water movements. In Experiment 2, bottles with different concentrations of sediment were put on an ordinary rotary table. The mineralisation rates were in both experiments monitored by daily sampling of sediment-water slurry, and analysed for total inorganic carbon by a gas chromatography with a thermal detector, GC-TCD. Results from Experiment 1 did not show any clear patterns regarding inorganic carbon formation. Experiment 2 did show clear patterns for two of six replicates of mineralisation of organic material. For these replicates the mineralisation rate were low according to previous studies. However, the sediment concentration seems to not affect the mineralisation rate. For both experiments, valuable information on how to better design experiments to investigate the importance of resuspension and the effect of mineralisation of organic material was yielded. Hence, further studies are needed to continue the investigation of the importance of resuspension for the mineralisation rate of organic material, and its impacts on the nutrient fluxes in the oceans.

Hohenheim, Univ., Diss., 2003.

University, Diss., 2004--München.

Techn. University, Diss., 2004--Darmstadt.

La pollution causée par le rejet industriel de métaux lourds a engendré la mise en place de réglementations concernant les concentrations en eaux de surfaces de ces polluants fortement toxiques. Des appareillages permettant la quantification des métaux lourds existent d'ores et déjà mais présentent de nombreux inconvénients comme leur coût, l'emploi d'un personnel qualifié ou encore des mesures différées dues à des échantillonnages spécifiques. L'électroanalyse représente, dans le domaine de la détection des métaux lourds, une des alternatives les plus prometteuses à ce jour.Les travaux présentés portent donc sur la mise au point d'un dispositif complet d'électroanalyse, tenant compte des problèmes de spéciation liés à la présence de la matière organique, permettant la quantification de deux métaux lourds fortement relargués par l'industrie : le plomb et le nickel. / Heavy metals industrial wastes involved the establishment of regulations concerning those toxic pollutants concentrations in surface water. Devices allowing heavy metals quantification already exist. Unfortunately, they revealed some gaps as their price, the need for qualified employees or even deferred results because of specific sampling procedures. Nowadays, in the heavy metals detection field, electroanalysis appears as a promising alternative. The work here discussed concerns the study of a global electroanalysis equipment, taking into account speciation issues related to organic matter presence, allowing heavy metals quantification in industrial runoffs of lead and nickel.

A review of the geotectonic settings of granitoids and various tin-tungsten provinces in Europe, Malaysia and southern Africa shows a close spatial and temporal association of mineralisation to S-type ilmenite series granitoids. Granitoids with these affinities are derived from crustal anatexis and are most commonly found in continental collision and different ensialic, intraplate orogenic settings, (e.g. SW England, Malaysia, Namibia) as well as in association with anorogenic magmatism (Nigeria, Brazil, South Africa). Tin-tungsten mineralisation is related to late- to post-tectonic granites, emplaced into areas of substantial tectonic thickening. Crustal anatexis leads to an observable calcalkaline chemical trend, with a source of gabbroic or amphibolite composition through anatexis to; mafic-intermediate enclaves, para-autochthonous anatectic granitoids (tonalite, granodiorite), to intermediate level quartz monzonite, granodiorite, biotite-granite, to late-tectonic highly fractionated muscovite-bearing granites, and high level porphyry intrusions. Mineralisation is spatially related to apical protrusions of the youngest most differentiated granite. Various mineralised environments are recognised, including endogranitic veins, primary disseminations, pegmatites and pipes, and exogranitic stockwork and fissure veins, and replacement bodies. A common factor to all these deposits is the inherent greisen environment, characterised by postmagmatic metasomatic alteration and mineral deposition. Common alteration mineral assemblages include albite, quartz, muscovite, tourmaline, and fluorite ∓ topaz. Ore mineral assemblages commonly display a paragenetic sequence of oxides (cassiterite, wolframite, scheelite), followed by sulphides (molybdenite, pyrite, pyrrhotite, chalcopyrite sphalerite, arsenopyrite/loëllingite, Pb-Bi(Ag) sulphosalts) and then lower temperature carbonates (calcite, siderite, ankerite). Analysis of Pan African orogenic provinces in southern Africa (Damara and Saldanian Provinces) shows there is good potential for applying integrated exploration techniques in search of endo-exogreisen Sn-W systems. Careful analysis and interpretation of granitoid geochemistry (K₂0, Na₂0, FeO/Fe₂0₃, F, B, Sn, W, Mo, Cu, Rb, Sr, Ti, Zr) should aid delineation of Sn-W and Mo-Cu metallogenic provinces in these regions. Magnetic susceptibility determinations should also aid distinction of S-type ilmenite series (less than 1 x lO⁻⁴emu/g ) from I-type magnetite series (more than 1 x lO⁻⁴emu/g ) granitoids