Porphyry copper and molybdenum deposits in west-central British Columbia are associated with plutons of Late Cretaceous and Tertiary age which intrude Mesozoic volcanic and sedimentary rocks of the Intermontane Tectonic Belt. The porphyry deposits are contained in an area bounded on the west by granitic rocks of the Coast Plutonic Complex, and on the east and southeast by a belt containing Mesozoic granitic stocks and an extensive area of Tertiary volcanic rocks. The porphyry intrusions take the form of small stocks, plugs , dykes, and dyke swarms generally not exceeding 1 square mile in surface area. The intrusions are commonly multiple and range in composition from quartz diorite to granite. Copper and molybdenum sulphides occur as fracture fillings and as veinlet stockworks within and adjacent to the intrusive bodies. Sulphide and alteration minerals exhibit concentric zoning patterns. Volcanic and sedimentary rocks marginal to the intrusions are thermally metamorphosed to biotite hornfels. Results of potassium-argon dating indicate four crudely parallel north to northwest-trending belts of porphyry intrusions, each being distinctive in age, rock composition, and contained metallic mineralization. From west to east these include: (1) Alice Arm intrusions - 50 m.y. molybdenum-bearing quartz monzonite and granite intrusions; (2) Bulkley intrusions - 70 to 84 m.y. copper-molybdenum and molybdenum-bearing porphyries of granodiorite to quartz monzonite composition; (3) Nanika intrusions - 50 m.y. copper-molybdenum and molybdenum-bearing intrusions of quartz monzonite composition; (4) Babine intrusions - 50 m.y. copper-bearing intrusions of quartz diorite and granodiorite composition. Potassium-argon analyses were carried out mainly on biotite separates from the mineralized porphyry phases within the deposits. Dating of inter-mineral and post-mineral porphyry phases, common at many of the deposits, yielded ages equivalent to, or 2 to 3 m.y. younger than, the mineralized phases, indicating that the age of mineralization is essentially synchronous with the age of intrusion. Limits of analytical errors in these potassium-argon analyses are within 3 per cent of the calculated ages. The distribution of potasslum-argon ages for porphyry deposits in west-central British Columbia does not fit the plate tectonic theories proposed for the origin of similar deposits elsehwere in the Cordillera of North and South America, in which deposits are progressively younger in a given direction. Here, four crudely parallel belts of porphyry intrusions display a reversal in age from 50 m.y. to 70 - 84 m.y. to 50 m.y. in an eastward direction. This distribution of ages may have been caused by periodic movement from Late Jurassic to Tertiary time along a subduction zone beneath the Coast Plutonic Complex which forms the west border of the area containing the porphyry deposits. / Science, Faculty of / Earth, Ocean and Atmospheric Sciences, Department of / Graduate

In recent years our understanding of the genesis of porphyry copper systems has advanced to a sufficient level to be able to construct predictive models that enhance exploration for these deposits. Our understanding of primary and secondary geochemical dispersion around these deposits is not so advanced as variables such as climate and topography cause geochemical patterns to be distorted or masked at surface with the result of different deposits having quite different geochemical characteristics. In this study the geology and geochemistry of a porphyry copper-molybdenum from the Canadian Cordillera is examined with the aim of demonstrating how primary geochemical patterns are affected by the development of a supergene enrichment blanket and leached capping. Topographic controls on the extent of leaching and supergene enrichment are also explored. The Berg porphyry copper-molybdenum deposit is in the Tahtsa Mountain Ranges, approximately 84 km southwest of Houston, central British Columbia. Mineralized zones are centered on a circa 50 Ma composite quartz monzonite stock. Hydrothermal alteration zones are similar to those of the classic model by Lowell and Guilbert. Central zones are potassic (orthoclase and biotite) while peripheral zones are propylitic (chlorite, epidote, carbonate). Intense phyllic alteration (quartz, sericite, pyrite) occurs at the north and south margins of the stock. Hypogene mineralization (characterized by pyrite, chalcopyrite and molybdenite) is concentrated in an annular zone straddling the quartz monzonite contact. Best grades are localized in altered quartz diorite and altered and hornfelsed Telkwa Formation (Hazelton Group) volcanic rocks at the east side of the deposit. The nature of these altered hornfelsed rocks has been a subject for much debate in previous studies. One school of thought suggests that they are part of a hornfels aureole associated with the quartz diorite. Others suggest that it is an alteration zone associated with the quartz monzonite stock. Thirteen diamond drill holes on a north south cross section of the deposit were logged (GEOLOG) and sampled. Outcrop samples were collected where possible close to each drill hole. Major elements were determined by XRF, trace metals by flame AAS and fluorine by specific ion electrode. A sequential extraction was used to study the distribution of copper between different host minerals. The origin of the hornfelsed rocks is solved by field mapping and geochemistry. In the field cross cutting relationships show that the quartz diorite predates the stock and that the hornfels zone is spacially related to it. Major element binary and ternary plots demonstrate that significant amounts of potassium have been added to these rocks in the mineralized zone. This implies that biotite alteration was superimposed onto an earlier hornfels. Trace metal data was partitioned into anomalous and background populations with probability graphs. In the hypogene zone Cu, Mo and Ag occur in an annular zone corresponding with the mineralogically defined potential ore zones. Fluorine is anomalous over the area of the potassic alteration zone. Lead and zinc are anomalous in peripheral haloes around the potential orebodies. These zones can be traced to surface through an extensive supergene enrichment blanket and leached capping. Three zones of supergene mineralization are recognized: supergene sulphide (covellite, digenite, chalcocite), supergene oxide (malachite/azurite, cuprite, tenorite, native Cu) and leached capping. Sulphides are the dominant host for Cu throughout most of the deposit but locally on steep slopes where supergene oxide is developed Cu is hosted in carbonate and oxide minerals. Enrichment or depletion of elements in the supergene is demonstrated with interelement ratios. Enrichment factors can be derived in two ways: a) by ratioing supergene values to hypogene values, or, b) by ratioing to a constant (e.g. TiO₂ ) for each zone and then ratioing this value between zones. Enrichment factors of <1 therefore imply depletion and >1, enrichment (1=hypogene grade). Results show that all elements (studied) are enriched in the supergene sulphide and oxide zones. In the leached cap Cu, Mn and Zn are depleted while Mo, Pb and Ag are significantly enriched. These elements are incorporated into immobile limonite mineral's (ferrimolybdite, jarosite, goethite etc.). / Science, Faculty of / Earth, Ocean and Atmospheric Sciences, Department of / Graduate