All substances above zero kelvin temperature emit fluctuating electromagnetic waves due to the random motions of charge carriers. Controlling the spectral and directional radiative properties of surfaces has wide applications in energy harvesting and thermal management. Artificial metamaterials have attracted much attention in the last decade due to their unprecedented optical and thermal properties beyond those existing in nature. This dissertation aims at tailoring radiative properties at infrared regime and enhancing the near-field radiative heat transfer by employing metamaterials. A comprehensive study is performed to investigate the extraordinary transmission, negative refraction, and tunable perfect absorption of infrared light. A polarizer is designed with an extremely high extinction ratio based on the extraordinary transmission through perforated metallic films. The extraordinary transmission of metallic gratings can be enhanced and tuned if a single layer of graphene is covered on top. Metallic metamaterials are not the unique candidate supporting exotic optical properties. Thin films of doped silicon nanowires can support negative refraction of infrared light due to the presence of hyperbolic dispersion. Long doped-silicon nanowires are found to exhibit broadband tunable perfect absorption. Besides the unique far-field properties, near-field radiative heat transfer can be mediated by metamaterials. Bringing objects with different temperatures close can enhance the radiative heat flux by orders of magnitude beyond the limit set by the Stefan-Boltzmann law. Metamaterials provide ways to make the energy transport more efficient. Very high radiative heat fluxes are shown based on carbon nanotubes, nanowires, and nanoholes using effective medium theory (EMT). The quantitative application condition of EMT is presented for metallodielectric metamaterials. Exact formulations including the scattering theory and Green’s function method are employed to investigate one- and two-dimensional gratings as well as metasurfaces when the period is not sufficiently small. New routes for enhancing near-field radiative energy transport are opened based on proposed hybridization of graphene plasmons with hyperbolic modes, hybridization of graphene plasmons with surface phonon modes, or hyperbolic graphene plasmons with open surface plasmon dispersion relation. Noncontact solid-state refrigeration is theoretically demonstrated to be feasible based on near-field thermal radiation. In addition, the investigation of near-field momentum exchange (Casimir force) between metamaterials is also conducted. Simultaneous enhancement of the near-field energy transport and suppress of the momentum exchange is theoretically achieved. A design based on repulsive Casimir force is proposed to achieve tunable stable levitation. The dissertation helps to understand the fundamental radiative energy transport and momentum exchange of metamaterials, and has significant impacts on practical applications such as design of nanoscale thermal and optical devices, local thermal management, thermal imaging beyond the diffraction limit, and thermophotovoltaic energy harvesting.

This dissertation focuses on near-field radiative transfer, which can be defined as the discipline concerned with energy transfer via electromagnetic waves at sub-wavelength distances. Three specific subjects related to this discipline are investigated, namely nearfield thermal radiation, nanoscale-gap thermophotovoltaic (nano-TPV) power generation and optical characterization. An algorithm for the solution of near-field thermal radiation problems in one-dimensional layered media is developed, and several tests are performed showing the accuracy, consistency and versatility of the procedure. The possibility of tuning near-field radiative heat transfer via thin films supporting surface phononpolaritons (SPhPs) in the infrared is afterwards investigated via the computation of the local density of electromagnetic states and the radiative heat flux between two films. Results reveal that due to SPhP coupling, fine tuning of near-field radiative heat transfer is possible by solely varying the structure of the system, the structure being the film thicknesses and their distance of separation. The coexistence of two regimes of near-field thermal radiation between two thin films of silicon carbide is demonstrated via numerical simulations and an asymptotic analysis of the radiative heat transfer coefficient. The impacts of thermal effects on the performances of nano-TPV power generators are investigated via the solution of the coupled near-field thermal radiation, charge and heat transport problem. The viability of nano-TPV devices proposed so far in the literature, based on a tungsten radiator at 2000 K and indium gallium antimonide cell, is questioned due to excessive heating of the junction converting thermal radiation into electricity. Using a convective thermal management system, a heat transfer coefficient as high as 105 Wm-2K-1 is required to maintain the junction at room temperature. The possibility of characterizing non-intrusively, and potentially in real-time, nanoparticles from 5 nm to 100 nm in size via scattered surface wave is explored. The feasibility of the characterization framework is theoretically demonstrated via a sensitivity analysis of the scattering matrix elements. Measurements of the scattering matrix elements for 200 nm and 50 nm gold spherical particles show the great sensitivity of the characterization tool, although an ultimate calibration is difficult with the current version of the experimental set-up.

Recently, remarkable advances have been made in the understanding of micro/nanoscale energy transport, opening new opportunities in various areas such as thermal management, data storage, and energy conversion. This dissertation focuses on thermally-sensed nanotopography using a heated silicon microcantilever and near-field thermophotovoltaic (TPV) energy conversion system. A heated microcantilever is a functionalized atomic force microscope (AFM) cantilever that has a small resistive heater integrated at the free end. Besides its capability of increasing the heater temperature over 1,000 K, the resistance of a heated cantilever is a very sensitive function of temperature, suggesting that the heated cantilever can be used as a highly sensitive thermal metrology tool. The first part of the dissertation discusses the thermal characterization of the heated microcantilever for its usage as a thermal sensor in various conditions. Particularly, the use of heated cantilevers for tapping-mode topography imaging will be presented, along with the recent experimental results on the thermal interaction between the cantilever and substrate. In the second part of the dissertation, the so-called near-field TPV device is introduced. This new type of energy conversion system utilizes the significant enhancement of radiative energy transport due to photon tunneling and surface polaritons. Investigation of surface and bulk polaritons in a multilayered structure reveals that radiative properties are significantly affected by polariton excitations. The dissertation then addresses the rigorous performance analysis of the near-field TPV system and a novel design of a near-field TPV device.