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EXPLORING THE TUNABILITY OF MARTENSITIC TRANSFORMATION IN SHAPE MEMORY ALLOYS VIA COHERENT SECOND PHASEShivam Tripathi (11516983) 20 December 2021 (has links)
<p>Shape memory alloys (SMAs) belong to an important class of active materials. Beyond shape memory, these alloys exhibit super-elasticity and pseudo-plasticity, all originating from a reversible phase transformation from a high-temperature austenitic phase to a low temperature martensitic phase. Their unique thermo-mechanical properties make these SMAs desirable for a wide range of applications in automobiles, robotics, aerospace, construction, and medicine. Only a fraction of the known metallic alloys exhibits martensitic transformations, and a relatively small subset exhibits shape memory. Given this limited pool of SMAs, tunability of this martensitic transformation and, hence, thermo-mechanical properties is a way to move forward for effectively designing the next-generation SMAs for specific applications. The modification in composition has always been at the heart of designing new SMAs for future applications. However, a relatively recent discovery of incorporating a second non-transforming phase in base martensitic materials to tune martensitic transformation to achieve unprecedented thermo-mechanical properties has shown great promise.</p><p><br></p><p>The objective of this work is to utilize the second phase to provide design guidelines for next-generation SMAs and to understand the detailed physics behind the experimentally observed unprecedented thermo-mechanical properties in SMAs as a result of the incorporation of coherent second phases. We first investigate Mg-Sc shape memory alloys that are attractive for a wide range of applications due to their low density. Unfortunately, the use of these alloys is hindered by a low martensitic transformation temperature (173 K). We observe from first-principles calculations that epitaxial strains arising from appropriate substrate or coherent second phase selection increase the martensitic transformation and operational temperature to room temperature. Next, we develop a novel approach to induce martensitic transformation in composite systems of two non-transforming materials. While we demonstrate this approach for the technologically relevant ultra-lightweight Mg/MgLi superlattices, however, our approach is general and will open a wide material space for the discovery and design of next-generation SMAs.</p><p><br></p><p>Finally, to bridge the gap between computationally studied single-crystalline materials and experimentally studied polycrystalline systems, we characterize the role of nanoscale precipitates on temperature- and stress-induced martensitic phase transformation in nanocrystalline Ni63Al37 SMAs using multi-million-atoms molecular dynamics simulations. Simulations provide the understanding of underlying atomistic mechanisms of experimentally observed unprecedented thermo-mechanical properties and the guidelines to design low-fatigue ultra-fine grain shape memory alloys. As a result of the exploration of novel thermomechanical properties in SMAs via coherent second phases, we also published a software package</p><p>to discover coherent precipitates within a base multi-component system by coupling highthroughput equilibrium thermodynamics calculations with strain-based lattice matching.</p>
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A Computational Study of Structural and Thermo-Mechanical Behavior of Metallic NanowiresSutrakar, Vijay Kumar January 2013 (has links) (PDF)
This thesis is an attempt to understand ways to improve thermo-mechanical and structural properties of nano-structured materials. A detailed study on computational design and analysis of metallic nanowires is carried out. Molecular dynamic simulation method is applied. In particular, FCC metallic nanowires, NiAl, and CuZr nanowires are studied. Various bottom-up approaches are suggested with improved structural and thermo¬mechanical properties.
In the first part of the thesis, Cu nanowires are considered. Existence of a novel and stable pentagonal multi-shell nanobridge structure of Cu under high strain rate tensile loading is reported. Such a structure shows enhanced mechanical properties. A three-fold pseudo-elastic-plastic shape recovery mechanism in such nanowires is established. This study also shows that the length of the pentagonal nanobridge structures can be characterized by its inelastic strain. It is also reported that an initial FCC structure is transformed into a new HCP structure. The evidence of HCP structure is confirmed with the help of experimental data published in the literature. Subsequent to the above study, a novel mechanism involving coupled temperature-stress dependent reorientation in FCC nanowires is investigated. A detailed map is generated for size dependent stress-temperature induced solid-solid reorientation in Cu nanowires.
In the second part of the thesis, deformation mechanisms in NiAl based intermetallic nanowires are studied. A novel mechanism of temperature and cross-section dependent pseudo-elastic/pseudo-plastic shape and strain recovery by an initial B2 phase of NiAl nanowire is reported. Such a recoverable strain, which is as high as ~ 30%, can potentially be utilized to realize various types of shape memory and strain sensing phenomena in nano-scale devices. An asymmetry in tensile and compressive yield strength behavior is also observed, which is due to the softening and hardening of the nanowires under tensile and compressive loadings, respectively. Two different deformation mechanisms dominated by twinning under tension and slip under compression are found. Most interestingly, a superplastic behavior with a failure strain of up to 700% in the intermetallic NiAl nanowires is found to exist at a temperature of 0.36Tm. Such superplastic behavior is attributed to the transformation of the nanowire from a crystalline phase to an amorphous phase after yielding of the nanowire.
In the last part the work, another type of nanowires having Cu-Zr system is considered. A novel stress induced martensitic phase transformation from an initial B2 phase to BCT phase in a CuZr nanowire under tensile loading is reported. It is further shown that such a stress induced martenistic phase transformation can be achieved under both tensile as well as compressive loadings. Tensile-compressive asymmetry in the stress-strain behavior is observed due to two different phase transformation mechanisms having maximum transformation strains of ~ 5% under compressive loading and ~ 20% under tensile loading. A size and temperature dependent tensile phase transformation in the nanowire is also observed. Small nanowires show a single step tensile phase transformation whereas the nanowires with larger size show a two step deformation mechanism via an intermediate R-phase hardening followed by R-phase yielding. A study of energetic behavior of these nanowires reveals uniform distribution of stress over the nanowire cross-section and such stress distribution can lead to a significant improvement in its thermo-mechanical properties. Similar improvement is demonstrated by designing the nanowires via manipulating the surface configuration of B2-CuZr system. It is found that the CuZr nanowires with Zr atoms at the surface sites are energetically more stable and also give a uniform distribution of stresses across the cross-section. This leads to the improvement in yield strength as well as failure strain. An approach to design energetically stable nano-structured materials via manipulating the surface configurations with improved thermo-mechanical properties is demonstrated which can help in fundamental understanding and development of similar structures with more stability and enhanced structural properties. Further ab-initio and experimental studies on the confirmation of the stability of the nanowires via manipulating the surface site is an open area of research and related future scopes are highlighted in the closure.
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Diffusion Studies On Systems Related to Nickel Based SuperalloysDivya, V D 07 1900 (has links) (PDF)
Superalloys offer high temperature strength, excellent creep, corrosion and oxidation
resistances, microstructural stability and good fatigue life at elevated temperatures. The composition of the superalloys has been modified continuously to improve the properties. The addition of Pt improves oxidation resistance without compromising the mechanical properties of
the superalloys. To further enhance the performance of the superalloy components, various coatings are applied on them. The-(NiPt)Al intermetallic compound bond coats, which are presently utilized, have certain drawbacks. Diffusion of Al from the bond coat to superalloy during service leads to accumulation of stress near the bond coat. The refractory elements present
in superalloy precipitate as topological close packed (TCP) phases in the interdiffusion zone. Consequently, a Pt enriched γ(Ni) + γ’(Ni3Al) phase mixture has been proposed as a possible alternative since TCP phases do not form in the interdiffusion zone. In this thesis, diffusion studies are performed on several binary and ternary systems with the primary purpose of understanding the effect of Pt in Ni based superalloys and also in γ + γ’ phase mixture bond coats.
Further, a detailed interdiffusion study is conducted in Mo- and W- based binary and ternary systems to understand the growth of the TCP phases. By performing bulk and multifoil diffusion couple experiments, different diffusion parameters like, inter, intrinsic, tracer, impurity diffusion
coefficients and activation energy that are necessary to understand the diffusion mechanism are determined. Additionally using the nanoindentation technique on diffusion couples, variation of mechanical properties such as, hardness and modulus with composition is studied.
First, interdiffusion in Ni-Pt, Co-Pt, Co-Ni, Ni-Fe and Co-Fe binary systems is examined. In Ni-Pt and Co-Pt, experimental results show that Pt is the slower diffusing species at all compositions. In both the systems, driving force is found to be the reason for higher values of intrinsic diffusion coefficients observed in the range of 40-60 at. % Pt. Contribution of vacancy
wind effect on diffusion parameters is found to be negligible. It is found from the multifoil diffusion couple experiments that Ni is the faster diffusing species in the Co-Ni system.
Bulk diffusion couple experiments are conducted in the Co-Ni-Pt and Co-Ni-Fe systems, by coupling binary alloys with the third element. Uphill diffusion is observed for Co and Ni in Pt rich corner of the Co-Ni-Pt system. Main and cross interdiffusion coefficients are calculated at
the compositions where two diffusion profiles intersect. In both the systems, the main interdiffusion coefficients are positive over the whole composition range and the cross diffusion coefficients show both positive and negative values at different regions. Hardness measured by
performing the nanoindentations on diffusion couples of both the systems, shows the higher
values at intermediate compositions.
The effect of Pt in and’ phases of Ni-Al system are examined by conducting
interdiffusion experiments between Ni(xPt) alloys and (NixPt)40Al alloy of β phase, so that both and’ phases grow in the interdiffusion zone. The interdiffusion coefficients in Ni-Al binary system increases with the Al content in the -phase, and they do not vary significantly with composition in the ’ phase. The average effective interdiffusion coefficients of Ni and Al in the
and ’ phases increase with the addition of Pt. Nanoindentation studies on diffusion couples show that the hardness of both and ’ phase increases with the addition of Pt. In the +’ phase mixture bond coats, effect of Pt on interdiffusion of major alloying elements of CMSX4 superalloys are discussed. A phase mixture of and ’ with increasing Pt content is coupled with
CMSX4 superalloy. The addition of Pt to the +’ phase mixture increases the diffusion rate of Ni, while the diffusion rate of Al, decreases with the addition of 5% Pt, and increases with further addition of Pt. No significant change in the diffusion rates of Co or Cr is observed.
The growth kinetics and diffusion in systems (both binary and ternary) with TCP phases
are examined. Interdiffusion studies performed in Co-Mo system show significant volume change because of the growth of the phase. Intrinsic diffusion coefficient of Mo is found to be higher than that of Co. Diffusion studies conducted in Ni-Mo system show reasonably low activation energy in the phase, indicating the grain boundary controlled diffusion process. The Co-Ni-Mo
and Co-Ni-W ternary phase diagrams are revisited and the phase boundary composition of the TCP phases are found to be different from those reported earlier. Following, the average effective interdiffusion coefficients are calculated and compared with the data calculated in the binary
systems to examine the role of the third element. It is noticed that the average effective interdiffusion coefficients in the Co(Ni,Mo) and Co(Ni,W) solid solution increases with the addition of Ni. On the other hand, these diffusion coefficients decrease with the addition of Ni in thephase in both the systems. The role of the driving force for diffusion and possible change in defect concentrations on different sublattices are discussed.
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