Copies of author's previously published works inserted. / Bibliography: p. 119-127. / 12, 127, [8], 35 p., [3] leaves : ill. (chiefly col.) ; 30 cm. / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / This thesis demonstrates the combined use of stimulated Brillouin scattering (SBS) for aberration correction, auto alignment and pulse compression as an ideal technology for studies of nonlinear optical processes, in particular nonlinear optical scattering (NLS). / Thesis (Ph.D.)--University of Adelaide, Dept. of Physics and Mathematical Physics, 1998

Thesis (Ph.D.) -- University of Adelaide, Dept. of Physics and Mathematical Physics, 1998. / Copies of author's previously published works inserted. Bibliography: p. 119-127.

Thesis (Ph.D.)--Washington State University. / Includes bibliographical references.

Thesis (Ph. D.)--University of Wisconsin--Madison, 1982. / Typescript. Vita. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references (leaves 145-153).

Thesis (Ph. D.)--Washington State University, December 2006. / Includes bibliographical references.

Thesis (M.S.) -- Worcester Polytechnic Institute. / Keywords: Hydrogen bonding; octupolar; nonlinear optics; crystal engineering. Includes bibliographical references (p.).

Thesis (Ph. D.)--University of Washington, 2006. / Vita. Includes bibliographical references (leaves 164-174).

Copies of author's previously published works inserted. Bibliography: p. 119-127. This thesis demonstrates the combined use of stimulated Brillouin scattering (SBS) for aberration correction, auto alignment and pulse compression as an ideal technology for studies of nonlinear optical processes, in particular nonlinear optical scattering (NLS).

A number of metallophthalocyanines (MPcs) and metal-free phthalocyanines (H₂Pcs) have been synthesized and characterized using various characterization tools such as ¹H-NMR, TOF mass spectrometry, FT-IR, UV-visible spectrophotometry and CHNS elemental analysis. Some of the MPcs were covalently linked to nanomaterials such as silica nanoparticles (SiNPs), single-walled carbon nanotubes (SWCNTs), magnetite nanoparticles (MNPs) and quantum dots (QDs), or embedded in polymer thin-films using poly(methyl methacrylate) (PMMA) and poly(acrylic acid) (PAA) as the polymer sources. The phthalocyanine-nanomaterial composites (Pc-NMCs) were characterized with FT-IR, UV-visible spectrophotometry, transmission electron microscopy (TEM), thermogravimetry analysis and X-ray diffractometry. The nonlinear optical (NLO) properties (using the open-aperture Z-scan technique) of the MPcs and the Pc-NMCs were investigated. In general, most of the investigated MPcs showed good optical limiting behaviors, except for a few, like the non-peripherally-substituted 2-pyridyloxy phthalocyanines, which showed inhibited NLO response as a result of the ring-strain effects. The absence of a metal center was found to greatly reduce the inherent high nonlinearities expected of some of the phthalocyanine complexes. The octaphenoxy derivatives (61a – 61e) were found to exhibit reverse saturable absorption (RSA) that depends on the singlet-singlet transitions, hence making them less reliable optical limiters. The optical limiting properties of the MPcs were improved in the presence of nanomaterials such as the QDs, MNPs and SWCNTs, with MPc-QDs showing the best optical limiting behavior of the three. SiNPs have no significant effect on the optical limiting behavior of the MPcs. The optical limiting properties of the MPcs were greatly enhanced in the presence of PMMA or PAA polymers. The PAA polymer showed better optical limiting behavior compared to PMMA

This work presents the nonlinear properties of six Sn(IV) Phthalocyanines. Three of the phthalocyanines are linked by an alkylthiol substituent and the rest are linked with a phenoxy substituent. For all six compounds non-linear optic analysis was carried out in four solvents: chloroform, toluene, dichloromethane, and tetrahydrofuran, and their differences were recorded. Calculation of the linear, singlet excited, triplet excited and two photon absorption cross-sections were also carried out and the results compared. To form a comparison the first order hyperpolarizabilities, DFT calculations were also performed and the results compared to see if the behaviour between the two properties can be predicted using DFT.