The Peace River Valley (British Columbia, Canada) is an area of intensive unconventional oil and gas (UOG) exploitation, an activity that can release contaminants with possible adverse effects on the fetus. My project aimed to estimate the importance of this exposure. For this aim, we 1) measured concentrations of 21 trace elements in tap water and biological (hair, urine, nails) samples from 85 pregnant women in this region; 2) compared them with those from the general population and health-based guidance values; 3) assessed their correlations between matrices; and 4) evaluated their associations with the density and proximity of UOG wells (i.e., wells within radii of 2.5 km, 5 km, 10 km, and with all wells in British Columbia around residences). Spearman's rank correlation and multiple linear regression analyses adjusted covariates were performed. Our results showed higher urinary and hair levels of certain trace elements compared to reference populations (e.g., Co, Ba, Sr, Mn, V, Ga). Concentrations in tap water correlated strongest with concentrations in hair, followed by nails and urine. Positive (e.g., Al, Mn, Cu, Ga, Cd, Ba, Cr, Sr, U) and negative (e.g., Fe) associations were observed between the density and proximity of UOG wells and the concentrations of certain trace elements in tap water, hair, and nails. Our results suggest that pregnant women living in an active area of UOG exploitation are likely to be more exposed to certain trace elements than the general population, but the association with density and proximity to wells remains uncertain. / La vallée de la rivière de la Paix (Colombie-Britannique, Canada) est une zone d’exploitation de pétrole et de gaz naturel par méthodes non-conventionnelles (PGNNC), une activité qui est susceptible de libérer des contaminants avec des effets nocifs possibles sur le foetus. Mon projet visait à estimer l’importance de cette exposition. À cette fin, nous avons 1) mesuré les concentrations de 21 éléments traces dans des échantillons de cheveux, d'ongles, d'urine et d'eau du robinet de 85 femmes enceintes de cette région, 2) comparé celles-ci avec celles de la population générale et des valeurs-guides, 3) évalué leur corrélation entre matrices et 4) évalué leur association avec la densité et proximité des puits (mesures pour des rayons de 2,5 km, 5 km, 10 km, et sans limite autour des résidences). Des analyses de corrélation de Spearman et de régression linéaire multiple ajustées pour certaines variables ont été effectuées. Les concentrations urinaires et capillaires étaient plus élevées pour certains éléments traces par rapport aux populations de référence (p. ex. Co, Ba, Sr, Mn, V, Ga). Les concentrations dans l'eau du robinet étaient plus fortement corrélées avec les concentrations dans les cheveux, suivis des ongles et de l'urine. Des associations positives (p. ex. Al, Mn, Cu, Ga, Cd, Ba, Cr, Sr, U) et négatives (p. ex. Fe) ont été observées entre la densité/proximité des puits de PGNNC et les concentrations de certains éléments traces dans les échantillons d'eau, de cheveux et d’ongles. Nos résultats portent à croire que les femmes enceintes vivant dans une zone active de PGNNC sont susceptibles d’être plus exposées à certains éléments traces que la population générale, mais le lien avec la densité et la proximité des puits demeure incertain.

Northeastern British Columbia was occupied by the Cordilleran (CIS) and the Laurentide (LIS) ice sheets, however, the timing and extent remains contentious. The late Quaternary and Holocene history of this area is examined by exploring geomorphic, stratigraphic, geochemical and geochronologic components of glacial, deglacial, paraglacial and non-glacial landsystems. New tools, such as GIS, LiDAR, and new geochronologic methods, such as optical dating are used to understand the Quaternary geology and geomorphology of the region. Bedrock topography represents the base of the Quaternary section and modelling shows that paleovalleys, common in this region, host extensive Neogene sedimentary records. Stratigraphies from the Murray and Pine valleys indicate glaciation prior to the Mid-Wisconsinan (MIS 3) and during the Late Wiconsinan (MIS 2). Glacial landforms record Late Wisconsinan ice-sheet coalescence and reflect the complex interaction of the LIS and CIS margins. During deglaciation, the LIS and CIS separated and glacial Lake Peace (GLP) formed. Shoreline features enable reconstruction of lake and ice configurations. Four phases of GLP are preserved. Optical ages from Phase II indicate GLP occupied the area some time between ca. 16 – 14 ka yrs ago. The apparent tilt on the shorelines provides a measure of isostatic adjustments and suggests asynchronous retreat of first the LIS, then the CIS. The transition from paraglacial to boreal conditions was driven by climate change and is recorded by vegetation sucession and cessation of paraglacial processes. Optical ages from stabilized dunes and radiocarbon ages from organics date the transition between 12 – 11.5 ka yrs ago with full boreal conditions established by 10 ka yrs ago. The Holocene is dominated by erosional processes, however some systems are aggrading. A case study on a floodplain demonstrates that resistivity (Ohmmapper) surveys provide a grain-size proxy to suppliant GPR studies, which is essential for geophysical fluvial architectural analysis. In the study, the discrepancy between planform style (classic meander model) and subsurface geophysical surveys (indicative of vertical accretion associated with braided and wandering fluvial styles) reiterates cautions that planform may not always be a functions of depositional process and one may not be used to predict the other. / Graduate / 0372 / 0373 / 0368