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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
11

Využití řídké reprezentace signálu při snímání a rekonstrukci v nukleární magnetické rezonanci / Exploitng sparse signal representations in capturing and recovery of nuclear magnetic resonance data

Hrbáček, Radek January 2013 (has links)
This thesis deals with the nuclear magnetic resonance field, especially spectroscopy and spectroscopy imaging, sparse signal representation and low-rank approximation approaches. Spectroscopy imaging methods are becoming very popular in clinical praxis, however, long measurement times and low resolution prevent them from their spreading. The goal of this thesis is to improve state of the art methods by using sparse signal representation and low-rank approximation approaches. The compressed sensing technique is demonstrated on the examples of magnetic resonance imaging speedup and hyperspectral imaging data saving. Then, a new spectroscopy imaging scheme based on compressed sensing is proposed. The thesis deals also with the in vivo spectrum quantitation problem by designing the MRSMP algorithm specifically for this purpose.
12

Využití moderních analytických metod pro studium vybraných koordinačních sloučenin boru / Application of modern analytical methods for the study of selected boron coordination compounds

Hrušková, Helena January 2019 (has links)
This thesis is focused on the study of boron coordination compounds, specifically boron pyrogallol and 2,3-dihydroxynaphthalene ligand complexes. In the introductory part of the work are discussed the properties of boron compounds, their preparation, the possibility of separation by capillary electrophoresis and methods of structural characterization. In the first part of the thesis, the methods of preparation of complexes are discussed and for each complex the optimal yield response is chosen. The resulting products were studied by low resolution mass spectrometry. In the second part of the thesis, structures of complexes, including their modeling in the Gaussian program, were described more precisely. Furthermore, the complexes were characterized by high resolution mass spectrometry. The complexes were also studied by 11 B, 1 H and 1 H COSY NMR and IR spectroscopy. The third part was devoted to the separation of these substances from the mixture after the reaction. CE-UV and CE-MS techniques were used for this purpose. To convert the results, the separation method was developed in ammonium formate buffers that are compatible with both instruments. The equilibration between complexes and ligands was also monitored by CE-UV. A special chapter is the study of pyrogallol autooxidation by UV-VIS and...
13

Stavební bloky supramolekulárních polymerů založených na vodíkové vazbě / Building blocks of hydrogen-bonded supramolecular polymers

Roudná, Štěpánka January 2011 (has links)
The connection of molecular monomers through non-covalent interaction (e.g. hydrogen bonding, π-π interaction, coordination bonding) enables the formation of supramolecular polymers. The major advantage of these bonds is their reversibility and consequently their ability to self-assembly or to disconnect depending on given conditions. This thesis examines the self-assembly through quadruple hydrogen bonding, which is strong and the resulting structures stable. Ureidopyrimidinon A and aromatic amines were always used as the starting compound for the preparation of monofunctional and bifunctional ureidopyrimidinones.
14

Vývoj analytických metod pro stanovení fosforylovaných složek bakteriálních buněčných membrán / Development of analytical methods for determination of phosphorylated components of bacterial cell membranes

Mikulecká, Jana January 2013 (has links)
Phospholipids are dominant components of bacterial cell membranes, where they create double layers. Bacteria differ in their phospholipid composition determination of which can help in identification of important groups of microorganisms. Phospholipid composition of bacteria is influenced by many environmental factors, therefore its variation can be observed within one bacterial stem also. Because of its simplicity, thin layer chromatography is usually applied to identification and determination of bacterial phospholipids. Disadvantage of this method are the high demands of time, carefulness and skills of the analytical personnel. The increasing interest in the phospholipid double-layer promotes the detailed investigation of their fatty acid composition because the more detailed analyses allows for more information yield about bacteria. Gas chromatography hyphenated with mass spectrometry seems to be the best choice for these purposes. Fatty acid identity and total fatty acid content in phospholipid molecules could be determined by this method. Additionally, number, position and isomerism of double bonds and presence of other functional groups on hydrocarbon chain could be determined. Whereas a suitable and...
15

Vliv parcelačního atlasu na kvalitu klasifikace pacientů s neurodegenerativním onemocněním / Influence of parcellation atlas on quality of classification in patients with neurodegenerative dissease

Montilla, Michaela January 2018 (has links)
The aim of the thesis is to define the dependency of the classification of patients affected by neurodegenerative diseases on the choice of the parcellation atlas. Part of this thesis is the application of the functional connectivity analysis and the calculation of graph metrics according to the method published by Olaf Sporns and Mikail Rubinov [1] on fMRI data measured at CEITEC MU. The application is preceded by the theoretical research of parcellation atlases for brain segmentation from fMRI frames and the research of mathematical methods for classification as well as classifiers of neurodegenerative diseases. The first chapters of the thesis brings a theoretical basis of knowledge from the field of magnetic and functional magnetic resonance imaging. The physical principles of the method, the conditions and the course of acquisition of image data are defined. The third chapter summarizes the graph metrics used in the diploma thesis for analyzing and classifying graphs. The paper presents a brief overview of the brain segmentation methods, with the focuse on the atlas-based segmentation. After a theoretical research of functional connectivity methods and mathematical classification methods, the findings were used for segmentation, calculation of graph metrics and for classification of fMRI images obtained from 96 subjects into the one of two classes using Binary classifications by support vector machines and linear discriminatory analysis. The data classified in this study was measured on patiens with Parkinson’s disease (PD), Alzheimer’s disease (AD), Mild cognitive impairment (MCI), a combination of PD and MCI and subjects belonging to the control group of healthy individuals. For pre-processing and analysis, the MATLAB environment, the SPM12 toolbox and The Brain Connectivity Toolbox were used.
16

Optimalizace homogenity základního magnetického pole v MR tomografii / Optimization of Basic Magnetic Field Homogeneity in MR Tomography

Hadinec, Michal January 2010 (has links)
This thesis is concerned with problems of measuring and mapping of magnetic field in MR tomograph, for purpose of magnetic flux density homogeneity optimization. Attention is paid to mapping techniques on rotary symmetric volume and to ways of magnetic fields optimization with utilization of passive and active correction systems. Theoretical analysis of magnetic field decomposition with utilization of spherical harmonics and numerical decomposition is made. Mapping and approximation techniques of basic magnetic field are verified by experiments in the laboratory at the Institute of Scientific Instruments AS CR in Brno.

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