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Forensic entomology is a well-established science linking arthropod biology and ecology to legal investigations. Specifically, immature development on a decomposing corpse may give insight into the minimum time elapsed since death. Until recently, biological variation within a single species has been overlooked when estimating colonization events. Variation in the form of phenotypic plasticity, or the ability of a single genotype to produce multiple phenotypes under alternative stresses, has been documented in genetic and ecological literature and spans across all phyla. Taking this into account, different subpopulations of forensically pertinent insect species should also possess the ability to adapt to changing environments as geographic distribution increases. Thus, plastic responses of a species to alternative stresses may be measured in biological parameters, such as development time. In this research, three geographically distinct strains of the blow fly Cochliomyia macellaria Fabricius (Diptera Calliphoridae) were reared in two distinct environments in order to measure development time, as well as pupal and adult masses. Strains exhibited genetic variance when compared to each other, and each strain exhibited variable responses across environments (phenotypic plasticity). Plasticity in the form of genotype by environment (GxE) interactions was also exhibited by C. macellaria, although consistent adherence to any single rule explaining ontogenetic trends was not apparent. This research supports the existence of intraspecific variation in a common blow fly of forensic importance. Results of this study will impact the forensic entomology community by encouraging the generation of either strain;specific developmental datasets or statistical models to minimize variation caused by genetic, environment, or GxE effects in order to compare developmental data across strains.

In this thesis, two objectives related to Near Edge X-ray Absorption Fine Structure (NEXAFS) spectroscopy have been studied. The first objective was to develop surface sensitivity in Scanning Transmission X-ray Microscopy (STXM) at the Canadian Light Source (CLS) and the Advanced Light Source (ALS). The second objective was to study sulphur 1s NEXAFS spectra of organosulphur compounds relevant to petroleum by experimental and computational methods. Towards the first objective, Total Electron Yield (TEY) detection has been implemented in a STXM microscope, by conventional sample current and single electron counting detection modes. This provides improved surface-sensitive detection, simultaneous with existing bulk-sensitive transmission detection in the STXM microscopes. Both approaches provide improved surface sensitive imaging and spectroscopy, although channeltron-based detection is superior. TEY-STXM provides surface sensitive imaging of ultrathin films such as phase-separated Langmuir-Blodgett monolayer films, phase separated polymer thin films, as well as differentiation of surface and bulk oxides of patterned metal thin films. The challenge for TEY-STXM measurements is the poor vacuum environment in the STXM chamber at the CLS, which greatly impacts the function of the channeltron as well as the rate of the photodeposition. Although the effect of photodeposition can be minimal in bulk spectroscopy of organic samples, it is a challenge in spectroscopy of organic thin films, where the photodeposits can dominate the weak signal originating from the surface. Chapter 4 of this thesis discusses the details of this study along with the challenges encountered in the development of this new TEY-STXM technique. The second goal of my research was the detailed study of sulphur 1s NEXAFS spectra of organosulphur compounds by experimental and computational methods to obtain a complete database of sulphur 1s NEXAFS spectra. The speciation and quantification of sulphur compounds is of great interest in different areas such as fossil fuel studies, biology, geology, and archaeology. Sulphur 1s NEXAFS spectroscopy can be used for speciation and quantification of these compounds. For this purpose a firm understanding of NEXAFS spectra of sulphur compounds is required. Therefore, the sulphur 1s NEXAFS spectra of different sulphur functionalities have been studied including thiols, thioethers, disulphides, sulfoxides, sulfones, and thiophenic compounds in gas and condensed phases. These highly resolved spectra have been further analyzed with the aid of ab initio calculations. The highly resolved experimental spectra showed fine features predicted by calculations. The combination of experiment and calculation has been used to improve assignment of spectroscopic features relevant for the speciation and quantification of sulphur compounds.

The introduction of fly-by-wire electronic flight control systems into transport aircraft has given the flying qualities engineer the opportunity to optimise the flying qualities of these aircraft for their specific tasks. With this technology has come the opportunity to introduce new technologies into the cockpit, such as non-linked or backfed sidesticks and non-backfed throttle levers. A comparative survey of airline pilots flying such a very high technology unconventional aircraft and a high technology but conventional aircraft suggests that these technologies may reduce the available channels of communication to the pilot in the very high technology aircraft, resulting in the possibility of reduced situational awareness. A closed loop piloted simulation survey of ten transport aircraft in current operation was undertaken which demonstrated that they all suffered from flying qualities deficiencies, limiting the performance that the pilot could achieve. In particular poor dynamics precluded the pilot adopting tight closed loop, or compensatory, control. Instead it was necessary to adopt a more open loop, precognitive, technique with medium frequency modulation, resulting in a degradation in landing performance. Through appropriate flight control system design it should be possible to produce aircraft that can be flown using the full range of control inputs from open to closed loop. The major study of this thesis assessed, through piloted simulation evaluations, the suitability of a wide range of longitudinal commanded response types for the approach and landing tasks. It was concluded that a response type that closely resembles that of angle of attack is optimum for these tasks due to its conventional characteristics of speed stability on the approach and monotonic stick forces in the flare. Such a system, appropriately implemented, should allow the transport aircraft pilot the full range of piloted control inputs, from open loop, precognitive, to closed loop, compensatory, resulting in improved landing performance.

A dissertation submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in fulfilment of requirements for the degree of Master of Science. Johannesburg, 2016. / This study has explored the CVD synthesis of carbon nanofibres (CNFs) using Eskom’s waste coal fly ash as a catalyst with acetylene and hydrogen as the carbon source and carrier gas, respectively. In the process, a possible growth mechanism for these carbon nanofibres was sought. CNFs were successfully synthesised from fly ash and were found to have an average diameter of 22±7 nm. The growth mechanism of these CNFs was studied using EDS, TEM and laser Raman spectroscopy. It was observed that CNFs grew via root growth on spherical particles of fly ash and by tip growth on irregular-shaped metal oxide agglomerates. Both of these were found, through EDS analysis, to be Fe-rich. CNFs were functionalised between 2-12 h under reflux at 110 °C using a 3:1 (v/v) combination of HNO3 and H2SO4 in order to introduce functional groups onto their surfaces to act as anchors for hydrophilic reactants. The functionalisation of these CNFs was studied using TEM, laser Raman spectroscopy, ATR-FTIR spectroscopy, PXRD, BET, XRF and TGA. ATR-FTIR spectroscopy showed that some carbonyl functional groups were present on the surfaces of these CNFs after functionalisation. The functionalised CNFs (fCNFs) were then treated using a simple hydrothermal method to deposit 10% (m/m) of TiO2 nanoparticles onto their surface. This hydrothermal method employed the drop-wise addition of TiCl4 to a cold water-fCNFs mixture, which was then refluxed at 115 °C for 2-12 h. Laser Raman spectroscopy confirmed the presence of both TiO2 (phase pure anatase) and CNFs. ATR-FTIR spectroscopy provisionally revealed the presence of covalent Ti-O-C bonds. Studies where the duration of exposure to TiCl4 and the functionalisation time of CNFs were examined showed that the particle size and agglomeration of the TiO2 nanoparticles did not affect the surface area of the CNF-TiO2 hybrids significantly. However, CNF-TiO2 hybrids which were shown by TGA to have high fly ash content were observed to have low surface areas. fCNFs functionalised at 2 h had the highest surface area, at all fixed durations of exposure to TiCl4 by comparison with fCNFs which had been functionalised for longer periods. / GR2016

A dissertation submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the Degree of Master of Science. Johannesburg, 2015. / Fly ash is a by-product generated during the combustion of coal for electricity gen- eration. Previous studies have shown that various waste fly-ashes (Japanese, Saudi Arabian, and Australian) contain trace quantities of transition metal elements which can be used in the synthesis of shaped carbon nanomaterials. A survey of the litera- ture has shown that no attempts to correlate the composition of a particular coal fly ash and the type or quantity of carbon nanomaterials (CNMs) that can be synthesized has been made. Neither has the effect of leached fly ash been tested for the synthesis of CNMs. Hence a study on the effect of the chemical composition of South African fly ash (collected from ESKOM’s Duvha power station in Mpumalanga) upon the chemical vapour deposition (CVD) synthesis of carbon nanostructures is justified. Untreated and chemically treated fly ash samples were used as catalysts in the CVD method to synthesize CNMs. In the latter case selective leaching experiments were conducted on the fly ash samples under acidic, basic and neutral conditions. Op- timal CNM synthetic conditions were achieved by initially flowing H2 gas to re- duce the metal oxides within the fly ash catalyst followed by the introduction of the carbon source (C2H2) at a temperature range of 600 - 800 ◦C. All samples were quantitatively and/or qualitatively characterized. Inductively coupled plasma optical emission spectrometry (ICP-OES) and X-ray fluorescence (XRF) techniques were used to quantify the metal ions which were removed from the fly ash samples. Fur- thermore, qualitative studies were conducted with (PXRD, and laser Raman spec- troscopy), morphological and surface area characterization techniques (SEM, TEM and BET) were used to investigate the synthesis of CNMs from the untreated and chemically treated fly ash samples. Results have shown that carbon nanofibers (CNFs) of different geometric morpholo- gies were synthesized at an optimal yield temperature of 700◦C. A combination of smooth, thin, wide, spiral platelet-like, stacked cup, and fishbone morphologies were reported when the untreated fly ash catalyst was used. Fly ash catalysts under acidic, basic and neutral treatments showed CNFs of varying sizes and specific morpholo- gies. Smooth graphitic platelet-like, stacked cup and platelet-like CNFs were re- ported when the fly ash catalyst was leached with neutral, basic and acidic solutions. Carbon nanofibre sizes with the IG ID ratios were reported as follows 115 nm (1.092), 52 nm (0.799), and 200 nm (0.960) under neutral, basic and acidic mediums respec- tively. Surface areas (41, 14 and 7) m2/g for the CNFs that were synthesised from the neutral, basic and acidic treated fly ash catalysts were related to the selective leaching of metals. The quality and quantity of CNFs obtained under acidic medium were associated with the leaching of iron (5.6%), cobalt (1.7%), calcium (20.4%), copper (12.5%), chromium (4.6%), magnesium (23.3%), manganese (15.2%) and nickel (2%) from the fly ash catalyst. Under a basic medium only chromium (0.2%), calcium (0.3%) and copper (7.4%) were removed. Significantly the best quality of CNFs was ob- tained when fly ash was treated under neutral conditions. Metal ions such as: cal- cium (3.7%), copper (3.8%), chromium (0.1%), and magnesium (1.3%) were mod- erately removed from the ash matrix. Therefore, composition and quantity of the fly ash catalyst had an effect on the synthesis of CNFs.

Thesis. 1976. Sc.D.--Massachusetts Institute of Technology. Dept. of Chemical Engineering. / Microfiche copy available in Archives and Science. / Vita. / Bibliography: leaves 321-328. / by Ashok S. Padia. / Sc.D.

On-going research at Texas A&M University indicated that soil stabilization using calcium chloride filter cake along with Class F fly ash generates high strength. Previous studies were conducted with samples containing calcium chloride filter cake and both Class C fly ash and Class F fly ash. Mix design was fixed at 1.3% and 1.7% calcium chloride and 5% and 10% fly ash with crushed limestone base material. Throughout previous studies, recommended mix design was 1.7% calcium chloride filter cake with 10% Class F fly ash in crushed limestone base because Class F fly ash generates early high and durable strength. This research paper focused on the strength increase initiated by greater than 1.7% pure calcium chloride used with Class F fly ash in soil to verify the effectiveness and optimum ratio of calcium chloride and Class F fly ash in soil stabilization. Mix design was programmed at pure calcium chloride concentrations at 0% to 6% and Class F fly ash at 10 to 15%. Laboratory tests showed samples containing any calcium chloride concentration from 2% to 6% and Class F fly ash content from 10% to 15% obtained high early strength however, optimum moisture content, different mix design, and mineralogy deposit analysis are recommended to evaluate the role and the effectiveness of calcium chloride in soil stabilization because of the strength decreasing tendency of the samples containing calcium chloride after 56 days.

Thesis (doctoral)--Helsinki University of Technology, 2000. / Includes bibliographical references. Also available on the World Wide Web.

Thesis (M.S.)--West Virginia University, 2001. / Title from document title page. Document formatted into pages; contains vii, 53 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 48-53).