Chen Ji = 由純淨有機物質及其混合物產生的具有退極化性質的超瑞利散射的光譜研究 / 陳佶. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2004. / Includes bibliographical references (leaves 91-92). / Text in English; abstracts in English and Chinese. / Chen Ji = You chun jing you ji wu zhi ji qi hun he wu chan sheng de ju you tui ji hua xing zhi de chao Ruili san she de guang pu yan jiu / Chen Ji. / Abstract --- p.i / Chhiese Abstract --- p.ii / Acknowledgments --- p.iii / Table of Contents --- p.iv / List of Figures and Tables --- p.vii / Chapter Chapter 1 --- Introduction --- p.1 / Chapter Chapter 2 --- Basic Theory --- p.5 / Chapter 2.1 --- A brief introduction to nonlinear optics --- p.5 / Chapter 2.2 --- Second Harmonic Generation (SHG) --- p.7 / Chapter 2.3 --- Hyper Rayleigh Scattering (HRS) --- p.9 / Chapter 2.4 --- Comparison between Second Harmonic Generation and Hyper Rayleigh Scattering --- p.10 / Chapter 2.5 --- HRS signal from a liquid --- p.12 / Chapter 2.6 --- Methods for measuring hyperpolarizability βby HRS --- p.13 / Chapter 2.7 --- Theoretical description of the depolarization ratio in HRS for a rod-like molecule --- p.16 / Chapter 2.8 --- Organic molecules with strong quadratic nonlinearities --- p.20 / Chapter Chapter 3 --- Experimental Setup --- p.25 / Chapter 3.1 --- Introduction --- p.25 / Chapter 3.2 --- Detailed descriptions of the main componets --- p.27 / Chapter 3.2.1 --- Laser system --- p.27 / Chapter 3.2.2 --- Scattered light collection system --- p.29 / Chapter 3.2.3 --- Data acquisition system --- p.32 / Chapter 3.3 --- Basic performance tests of the experimental setup --- p.35 / Chapter 3.3.1 --- Temporal stability of the apparatus --- p.35 / Chapter 3.3.2 --- Linearity of the light detection apparatus --- p.36 / Chapter 3.3.3 --- Background noise --- p.38 / Chapter 3.4 --- Sample preparation --- p.40 / Chapter Chapter 4 --- General spectral measurements and measurement of hyperpolarizability β for some organic chemicals --- p.41 / Chapter 4.1 --- Low and high resolution HRS spectra of several common liquids --- p.41 / Chapter 4.2 --- Experimental performance test of HRS by using PNA solution --- p.45 / Chapter 4.3 --- Measurements of the first order hyperpolarizability b for Crystal Violet (CV) by a modified Internal Reference Method (IRM) --- p.50 / Chapter 4.3.1 --- Basic spectral measurement of CV --- p.50 / Chapter 4.3.2 --- Measurement of hyperpolarizability β for CV --- p.52 / Chapter Chapter 5 --- Study of coherent and incoherent hyper-Rayleigh scattering for organic chemicals --- p.57 / Chapter 5.1 --- Introduction --- p.57 / Chapter 5.2 --- Calibration of the experimental setup --- p.59 / Chapter 5.3 --- "Study of depolarization ratio of PNA solution, Nitrobenzene and CCl4" --- p.64 / Chapter 5.4 --- Further study of depolarization ratio for Nitrobenzene and its mixtures --- p.68 / Chapter 5.5 --- More studies on depolarization ratios for CC14 and Nitrobenzene --- p.79 / Chapter 5.6 --- "Spectral study of PNA solution, Nitrobenzene and its mixtures" --- p.83 / Chapter 5.7 --- Summary --- p.85 / Chapter Chapter 6 --- Conclusions --- p.88 / References --- p.91

by Cheung Ka Wing = 由有機物質發放的超瑞利散射的光譜性硏究 / 張家榮. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2000. / Includes bibliographical references (leaves 94-95). / Text in English; abstracts in English and Chinese. / by Cheung Ka Wing = You you ji wu zhi fa fang de chao rui li san she de guang pu xing yan jiu / Zhang Jiarong. / Title Page --- p.i / Acknowledgments --- p.ii / Abstract --- p.iii / Chinese Abstract --- p.iv / Table of Contents --- p.v / Chapter Chapter 1 --- Introduction --- p.1 / Chapter 1.1 --- Nonlinear Optics --- p.1 / Chapter 1.2 --- Tensor Properties of the Polarizability --- p.4 / Chapter 1.3 --- Inversion Symmetry --- p.5 / Chapter 1.4 --- Second Harmonic Generation --- p.6 / Chapter 1.5 --- Outline --- p.10 / Chapter Chapter 2 --- Measurement of the First Hyperpolarizability β --- p.11 / Chapter 2.1 --- Scattering by a Single Small Particle --- p.11 / Chapter 2.2 --- Rayleigh Scattering --- p.13 / Chapter 2.3 --- Fluctuation --- p.15 / Chapter 2.4 --- Hyper-Rayleigh Scattering --- p.16 / Chapter 2.5 --- Coherent and Incoherent Optical Processes --- p.16 / Chapter 2.6 --- Difference between Second Harmonic Generation (SHG) and Hyper Rayleigh Scattering (HRS) --- p.17 / Chapter 2.7 --- Measurement of the First Hyperpolarizability β by Electric Field Induced Second harmonic Generation (EFISHG) --- p.20 / Chapter 2.8 --- Measurement of the First Hyperpolarizability β by Hyper-Rayleigh Scattering (HRS) --- p.22 / Chapter 2.9 --- Two-Component System ´ؤ´ؤInternal Reference Method (IRM) and External Reference Method (ERM) --- p.23 / Chapter 2.10 --- Orientation Average of β --- p.25 / Chapter Chapter 3 --- Experimental Setup --- p.29 / Chapter 3.1 --- Detail Description of the Main Components --- p.29 / Chapter A). --- Laser System --- p.29 / Chapter B). --- Monochromator --- p.33 / Chapter C). --- Photomultiplier Tubes (PMT) --- p.36 / Chapter D). --- Photon Counter --- p.37 / Chapter 3.2 --- Layout of the Optical Design and Alignment Procedures --- p.39 / Chapter 3.3 --- Difficulties in the Experiment --- p.42 / Chapter A). --- Alignment --- p.42 / Chapter B). --- Temporal Stability of the Apparatus --- p.43 / Chapter C). --- The Effects of Using Different Sample Cells --- p.47 / Chapter 3.4 --- Sample Preparation --- p.48 / Chapter 3.5 --- Special Interest on the Organic Compounds --- p.49 / Chapter Chapter 4 --- Measurement on p-nitroaniline --- p.52 / Chapter 4.1 --- The Spectrum of Light Signal from pNA --- p.52 / Chapter 4.2 --- Concentration Dependence Measurement --- p.54 / Chapter Chapter 5 --- Measurement of the Hyperpolarizability of a Fluorescence Dye --- p.58 / Chapter 5.1 --- The Spectrum of Light Signal from DANS --- p.58 / Chapter 5.2 --- Design of an Experimental Technique to Measure β of Fluorescence Dyes that is Absorptive at the Second Harmonic --- p.61 / Chapter 5.3 --- Result of the Measurement on DANS --- p.64 / Chapter Chapter 6 --- Studies of the First Hyperpolarizability β of Two New Compounds --- p.74 / Chapter 6.1 --- The New Compounds --- p.74 / Chapter 6.2 --- Measurement on NC1 --- p.75 / Chapter 6.3 --- Measurement on NC2 --- p.79 / Chapter Chapter 7 --- Probing the Molecular Interaction in a Liquid Using HRS --- p.84 / Chapter 7.1 --- The Spectrum of Light Signal from Nitrobenzene --- p.85 / Chapter 7.2 --- The Signal Depolarization Ratio --- p.86 / Chapter 7.3 --- Results of the Depolarization Ratio Measurement on pNA --- p.87 / Chapter 7.4 --- Results of the Depolarization Ratio Measurement on Nitrobenzene --- p.88 / Chapter Chapter 8 --- Conclusions --- p.91 / References --- p.94

by T.W. Chui. / Thesis (M.Phil.)--Chinese University of Hong Kong, 1998. / Includes bibliographical references (leaves 79-81). / Text in English; abstract also in Chinese. / by T.W. Chui. / Titleage --- p.i / Acknowledgments --- p.ii / Abstract --- p.iii / Table of contents --- p.v / Chapter Chapter 1 --- Introduction --- p.1 / Figure Captions --- p.16 / Chapter Chapter 2 --- Meauserment of first hyperpolarizability / Chapter 2.1 --- Electric Field Induced Second Hamonics (EFISH) --- p.21 / Chapter 2.2 --- Hyper-Rayleigh Scattering (HRS) --- p.23 / Chapter 2.3 --- Internal reference method and External reference method --- p.26 / Figure Captions --- p.28 / Chapter Chapter 3 --- Experimental Setup / Chapter 3.1 --- Design of experimental setup --- p.30 / Chapter 3.2 --- Alignment --- p.32 / Chapter 3.3 --- ower --- p.33 / Chapter 3.4 --- Samples --- p.33 / Figure Captions --- p.35 / Chapter Chapter 4 --- Measurement of first hyperpolarizability of selected molecules / Chapter 4.0 --- Introduction --- p.40 / Chapter 4.1 --- Result of spectral study of the scattered signal from CV --- p.43 / Chapter 4.2 --- Result of the first hyperpolarizability of CV --- p.46 / Chapter 4.3 --- HRS measurement with DANS --- p.47 / Figure Captions --- p.51 / Graphs --- p.52 / Tables --- p.57 / Chapter Chapter 5 --- Studies of the depolarization ratio of HRS and fluorescence light from CV / Chapter 5.0 --- Introduction --- p.59 / Chapter 5.1 --- Experimental setup for the measurement of depolarization ratio --- p.60 / Chapter 5.2 --- Measurement of depolarization ratio forNA at 532nm --- p.61 / Chapter 5.3 --- Measurement of depolarization ratio for CV at 532nm --- p.62 / Chapter 5.4 --- Measurement of depolarization ratio for fluorescence light from CV --- p.63 / Figure Captions --- p.68 / Graphs --- p.71 / Tables --- p.75 / Chapter Chapter 6 --- Conclusions --- p.77 / References --- p.79

by S.W. Wong. / Thesis (M.Phil.)--Chinese University of Hong Kong, 1996. / Includes bibliographical references (leaves 76-77). / by S.W. Wong. / Title Page --- p.i / Dedication --- p.ii / Acknowledgments --- p.iii / Abstract --- p.iv / Table of Contents --- p.v / Chapter Chapter 1 --- Introduction --- p.1 / Chapter Chapter 2 --- A Brief Introduction to Nonlinear Optics --- p.7 / Chapter Chapter 3 --- Experimental Measurement of the First Hyperpolarizability β for pNA by Hyper-Rayleigh Scattering in Solution --- p.24 / Chapter 3.1 --- Introduction --- p.24 / Chapter 3.2 --- Theory of Measurement of β by HRS --- p.26 / Chapter 3.3 --- Experimental Setup --- p.31 / Chapter 3.4 --- Preparation of Sample --- p.34 / Chapter 3.5 --- Results --- p.35 / Chapter Chapter 4 --- Studies of Depolarization Ratio in HRS --- p.44 / Chapter 4.1 --- Background --- p.44 / Chapter 4.2 --- Theory --- p.45 / Chapter 4.3 --- Results --- p.55 / Chapter 4.4 --- Discussion and Conclusion --- p.57 / Chapter Chapter 5 --- Measurement on other Nonlinear Optical Compounds --- p.63 / Chapter Chapter 6 --- Conclusion --- p.73 / References --- p.76

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This thesis describes investigations into the photophysical properties of luminescent materials and their application in optoelectronic devices such as light emitting diodes and photodetectors. The materials used were all solution processable because of the interest in low cost processing of organics. I have investigated the photophysics of 1,4,5,8,9,12-hexamethyltriphenylene, a triphenylene derivative which has its luminescence enhanced by the addition of methyl groups. These groups change the planar shape of the triphenylene molecule into a twisted one, changing the symmetry of the molecule and increasing its dipole moment in absorption and emission by ~4 fold. This increased its rate of radiative deexcitation by ~20 times. In addition, the twisted shape of the molecule prevents intermolecular interactions and concentration effects from affecting the luminescence. This results in an efficient solid-state photoluminescence quantum yield of 31%. This thesis also includes an investigation into phosphorescent polymer dendrimers, designed to have suitable viscosities in solution for inkjet printed OLED applications. A photophysical study of the intra-chain aggregation effects on the luminescence was undertaken in both homopolymers and copolymers with high energy gap spacer units. Using double dendrons to increase the steric protection of the luminescent cores, the best homopolymers achieved 12.1% external quantum efficiency (39.3 cd/A) at 100 cd/m² brightness and the best co-polymer achieved 14.7% EQE (48.3 cd/A) at 100 cd/m². This compares favourably with 11.8% EQE for the best phosphorescent polymer and 16% for the best solution processed dendrimer OLED previously reported. Finally I have applied a solution processed enhancement layer to silicon photodiodes to enhance their ultraviolet response. Using a blend of materials to give favourable absorption and emission properties, 61% external quantum efficiency was achieved at 200 nm, which is better than the 20-30% typical for vacuum deposited lumogen enhancement layers used commercially.