The aims of the work were as follows: • synthesis of branched dimers with stable amorphous state possessing tiophenylsulphide, sulphide and hydroxygroups in the linking fragment of chromophores from aromatic and heteroaromatic alde6 hyde phenylhydrazones. A thorough study of physical and optoelectrographic properties of these charge-transporting compounds; • synthesis of new crosslinkable charge transporting molecular glasses exhibiting high charge carrier mobilities, high morphological stability; • design and synthesis of new hole transporting molecular glasses and polymers (from 9-(2,3-epoxypropyl)carbazole); • investigation of the interaction of 1(2)-aminoanthraquinone and 1- chloro-2,3-epoxypropane (CEP) with the aim to use the products for the creation of hydroxygroups possessing electron-transporting materials, having stable amorphous state.