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Synthesis and structural characterization of half- and full-sandwich group 4 metallacarboranes.January 2002 (has links)
Kwong Wai-chuen. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2002. / Includes bibliographical references (leaves 98-102). / Abstracts in English and Chinese. / Acknowledgement --- p.I / Abstract (in English) --- p.II / Abstract (in Chinese) --- p.III / Abbreviation --- p.V / List of Compounds --- p.VI / Contents --- p.VII / Chapter Chapter 1. --- Introduction / Chapter 1.1 --- Metallacarboranes of the C2B4 Systems --- p.1 / Chapter 1.1.1 --- Group 1 Metallacarboranes of the C2B4 Systems --- p.3 / Chapter 1.1.2 --- Group 4 Metallacarboranes of the C2B4 Systems --- p.6 / Chapter 1.2 --- Group 4 Metallacarboranes of the C2B9 Systems --- p.17 / Chapter 1.3 --- Group 4 Metallacarboranes of the C2B10 Systems --- p.35 / Chapter 1.4 --- Applications of Group 4 Metallacarboranes --- p.44 / Chapter 1.5 --- Research Objectives --- p.47 / Chapter Chapter 2. --- Synthesis and Structural Characterization of Group4 Metallacarboranes of the C2B9 Systems / Chapter 2.1 --- Synthesis and Structural Characterization of {{466}4:η2-[(C6H5CH2)2C2B9H9]2ZrCl(THF)} {Na(THF)3} --- p.48 / Chapter 2.2 --- Synthesis and Structural Characterization of [η4:η2- {(C6H5CH2)2C2B9H9} 2ZrCl(THF)] [Li(THF)4] --- p.54 / Chapter 2.3 --- Synthesis and Structural Characterization of ZrCl[N(SiMe3)2]3 --- p.57 / Chapter 2.4 --- "Synthesis and Structural Characterization of η2-(C6H5CH2)2C2B9H9]M(NEt2)2(NHEt2HCH2Cl2) (M = Ti, Zr)" --- p.62 / Chapter 2.5 --- "Synthesis and Structural Characterization of [μ-{ o-C6H4(CH2)2 }C2B9H9]2M(THF)2 (M = Zr, Hf)" --- p.68 / Chapter 2.6 --- Conclusion --- p.71 / Chapter Chapter 3. --- Synthesis and Structural Characterization of Group4 Metallacarboranes of the C2B10 Systems / Chapter 3.1 --- "Synthesis and Structural Characterization of {{471}-l,,2-(o-C6H4(CH2)2)- 1,2-C2B 10H10]2Zr} {Na(THF)3}2 and {[μ-l,2-(o-C6H4(CH2)2)-l,2- C2B10H10]2ZrCl2} {Na(THF)3}2(THF)" --- p.72 / Chapter 3.2 --- Conclusion --- p.78 / Chapter Chapter4. --- Summary --- p.79 / Chapter Chapter5. --- Experimental Section --- p.81 / References --- p.98 / Appendix / Chapter I. --- Crystal Data and Summary of Data Collection and Refinement --- p.103 / Chapter II. --- Atomic Coordinates and Thermal Parameters --- p.109 / Chapter III. --- Bond Distances and Angles --- p.117
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Synthesis, structural characterization and reactivity of 13- and 14-vertex carboranes. / CUHK electronic theses & dissertations collectionJanuary 2011 (has links)
Zhang, Jian. / Thesis (Ph.D.)--Chinese University of Hong Kong, 2011. / Includes bibliographical references (leaves 263-289). / Electronic reproduction. Hong Kong : Chinese University of Hong Kong, [2012] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Abstract also in Chinese.
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Synthesis, structural characterization and reactivity of twelve-, thirteen-, and fourteen-vertex carboranes. / CUHK electronic theses & dissertations collectionJanuary 2013 (has links)
Zheng, Fangrui. / Thesis (Ph.D.)--Chinese University of Hong Kong, 2013. / Includes bibliographical references (leaves 181-197). / Electronic reproduction. Hong Kong : Chinese University of Hong Kong, [2012] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Abstract also in Chinese.
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Synthetic applications of chiral furanylboronates. / CUHK electronic theses & dissertations collectionJanuary 2002 (has links)
Chan Kin Fai. / "April 2002." / Thesis (Ph.D.)--Chinese University of Hong Kong, 2002. / Includes bibliographical references (p. 151-157). / Electronic reproduction. Hong Kong : Chinese University of Hong Kong, [2012] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Mode of access: World Wide Web. / Abstracts in English and Chinese.
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Part I. Synthetic studies of furanosesquiterpenoid tetrahydrolinderazulenes. Total synthesis of (plusmn)-echinofuran, and, Part II. Synthetic applications of chiral furyl boronates. Asymmetric synthesis of optically pure substituted furylamines. / Part I, Synthetic studies of furanosesquiterpenoid tetrahydrolinderazulenes ; Total synthesis of (±)-echinofuran; and, Part II, Synthetic applications of chiral furyl boronates. Asymmetric synthesis of optically pure substituted furylamines / Synthetic studies of furanosequiterpenoid tetrahydrolinderazulenes / Total synthesis of (±)-echinofuran / Synthetic applications of chiral furyl boronates / Asymmetric synthesis of optically pure substituted furylamines / CUHK electronic theses & dissertations collectionJanuary 2003 (has links)
"July 2003." / Thesis (Ph.D.)--Chinese University of Hong Kong, 2003. / Electronic reproduction. Hong Kong : Chinese University of Hong Kong, [2012] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Mode of access: World Wide Web. / Abstracts in English and Chinese.
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Design, synthesis, and screening of a library of peptidyl bis-boroxoles as low molecular weight receptors for complex oligosaccharides in neutral water: identification of a selective receptor for the tumour marker TF-antigenPal, Arnab Unknown Date
No description available.
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Synthesis and structural characterization of heterocycles incorporating a carboranyl unit.January 2011 (has links)
He, Xiao. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2011. / Includes bibliographical references (leaves 75-83). / Abstracts in English and Chinese. / Acknowledgement --- p.I / Abstract --- p.II / 摘要 --- p.III / Abbreviation --- p.IV / List of Compounds --- p.VI / List of Figures --- p.VII / Contents --- p.IX / Chapter Chapter 1 --- Introduction --- p.1 / Chapter 1.1 --- Transition Metal-Carboranyl Complexes --- p.2 / Chapter 1.1.1 --- Late Transition Metal-Carboranyl Complexes --- p.2 / Chapter 1.1.2 --- Early Transition Metal-Carboranyl Complexes --- p.6 / Chapter 1.2 --- Transition Metal-Carboryne Complexes --- p.12 / Chapter 1.3 --- Five-Membered Heterocycles Incorporating Main Group Elements --- p.20 / Chapter 1.3.1 --- Synthesis and Reactivity of Boroles --- p.20 / Chapter 1.3.2 --- Synthesis and Reactivity of Phospholes --- p.24 / Chapter 1.3.3 --- Synthsis and Reactivity of Silole --- p.28 / Chapter 1.4 --- Our Objectives --- p.31 / Chapter Chapter 2 --- Nickelacycles Incorporating a Carboranyl Unit --- p.32 / Chapter 2.1 --- Introduction --- p.32 / Chapter 2.2 --- "Synthesis, Characterization and Reactivity of Nickelacycles Bearing (2-CPh2O-l,2-C2B10H10)2-Ligand" --- p.32 / Chapter 2.2.1 --- Synthesis and Characterization --- p.32 / Chapter 2.2.2 --- Reactivity Study --- p.34 / Chapter 2.2.3 --- X-ray Structure --- p.36 / Chapter 2.3 --- "Synthesis and Characterization of Nickelacycles Bearing [2-C(Ph)=N-l,2-C2B10H10]2- Ligand" --- p.44 / Chapter 2.3.1 --- Synthesis and Characterization --- p.44 / Chapter 2.3.2 --- X-ray Structure --- p.45 / Chapter Chapter 3 --- Five-membered Heterocycles of Main Group Elements Incorporating a Carboranyl Unit --- p.47 / Chapter 3.1 --- Synthesis and Characterization of Heterocycles Bearing Phosphorus Element --- p.47 / Chapter 3.2 --- Synthesis and Characterization of Heterocycles Bearing Silicon Element --- p.53 / Chapter 3.3 --- Synthesis and Characterization Heterocycles Bearing Boron Element --- p.58 / Chapter Chapter 4 --- Conclusion --- p.61 / Chapter Chapter 5 --- Experimental Section --- p.63 / References --- p.75 / Appendix --- p.84 / Chapter I. --- Crystal Data and Summary of Data Collection and Refinement --- p.84 / Chapter II. --- X-ray crystallographic data in CIF (electronic form)
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The attempted synthesis of 4,4-dimethyl-3-dimethylamino-2,6-cyclohexanedione carboxamideCockerline, Roger Leith 01 January 1971 (has links)
The use of boron-containing amines for the amino alkylation of amides has been investigated in our laboratories with the aim of preparing compounds which could be used in neutron capture therapy. The purpose of this procedure is to achieve selective irradiation of a neoplactic growth by inducing radioactivity throughout that tissue. Although the results obtained in destroying tumors have not always been encouraging, they have been such - especially in cases not amenable to treatment by surgery or chemotherapy - that further research is warranted in order to develop drugs that can be used effectively in neutron capture therapy (Farr, Robertson & Stickley, 1954). This method of cancer treatment is still in the experimental stages of development, but it will, no doubt, gain the active interest of more clinical workers in the near future.
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Synthesis, molecular structure and reactivity studies of organolanthanide Fluoride and Carborane compounds. / CUHK electronic theses & dissertations collectionJanuary 2000 (has links)
Kwoli Chui. / "August 2000." / Thesis (Ph.D.)--Chinese University of Hong Kong, 2000. / Includes bibliographical references (p. 122-140). / Electronic reproduction. Hong Kong : Chinese University of Hong Kong, [2012] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Mode of access: World Wide Web. / Abstracts in English and Chinese.
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