Spelling suggestions: "subject:"organometallic chemistry"" "subject:"irganometallic chemistry""
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Stereodifferentiating reactionsWilliams, Jonathan Michael Jeremy January 1989 (has links)
No description available.
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Coordination chemistry of new ferrocenyl phosphane ligands and novel N-heterocyclic carbene ligand precursors containing cyclopentadienyl or fluorenyl derivativesTurberville, Simon January 2003 (has links)
No description available.
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Synthesis and characterization of [(C₅R₅)M(CO)₂(L₂)+:R=H, Me, and Ph; M=Cr and Mo; L₂=dmpe and dppeDearman, Brian. January 2002 (has links)
Thesis (M.S.)--Marshall University, 2002. / Title from document title page. Document formatted into pages; contains x, 31 p. Includes bibliographical references (p. 29-31).
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The chemistry of organolanthanide complexes containing functionalized phosphine ligands林觀陽, Lin, Guanyang. January 1996 (has links)
published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
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Metal-organic polyhedra : subcomponent self-assembly, structural properties, host-guest behavior and system chemistryMeng, Wenjing January 2012 (has links)
No description available.
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Metallomics of Mercury: The Role of SeleniumKhan, Mohammad 26 October 2010 (has links)
Mercury-selenium (Hg-Se) interaction is perhaps the most documented bioantagonism. Since its discovery in the 1960s, extensive studies have been carried out on the wide occurrence, chemical mechanisms, and toxicological significance of this bioantagonism. However, major knowledge gaps exist in the underlying mechanism at the molecular level which is the objective of this present research.
To study molecular level mechanism of this bioantagonism, four new MeHg-selenoamino acid namely, methylmercury-D,L-selenopenicillaminate, methylmercury-L-selenoglutathionate, and two methylmercury-L-selenomethioninate complexes (one via a Hg-Se bonding and the other via Hg-N bonding) were synthesized and characterized by NMR, FT-IR and mass spectrometry. Their structural and electronic properties were studied by X-ray crystallography and quantum mechanical calculations. These studies reveal that all four complexes chemically and structurally resemble their sulfur analogues. This suggests that mimicry could play a role in the MeHg-Se antagonism. Chemical coupling values from NMR suggest that MeHg+ has stronger affinity for Se than for S.
It has long been proposed and analytically proven that mercury selenide, HgSe(s), is the end product of the Hg-Se bioantagonism. However, the pathway of its formation in biological systems was poorly understood. Experiments carried out in this study suggested that HgSe(s) could be formed from both inorganic Hg and MeHg in the presence of Se.
In the case of MeHg, we found that its binding with selenoamino acids could result in the demethylation of MeHg and formation of HgSe nanoparticles. NMR and gas chromatography – mass spectrometry (GC-MS) studies confirmed the presence of bis(methylmercury) selenide (BMSe) and dimethylmercury as reaction intermediates based on which a demethylation pathway was proposed.
Inorganic Hg interacts with selenite in presence of glutathione (GSH) and form HgSe1-xSx (0 < x < 1) nanoparticles via a black solution or precipitate. The dissolution/precipitation is reversible upon adjustment of pH. UV-visible spectra, TEM and XPS analyses revealed that the black solution is HgSe1-xSx nanoparticles with diameter < 5 nm which at high pH and upon separation becomes sparingly soluble. This study provides a new plausible explanation of tissue distribution patterns of HgSexS1-x in biological systems.
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Carbide and nitride clustersSabounchei, S. J. S. Z. January 1990 (has links)
No description available.
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Ambidentate ligands : the preparation and study of phosphine crown systemsFarazi, Vida January 1987 (has links)
The aza crown, sym-1,2-benzo-aza-17-crown-5, was synthesized from 6-aza-3,9-dioxa-1,11-undecanediol, and , -dibromo-o-xylene in the presence of potassium tert-butoxide. This new crown ether was reacted with 4-bromobenzyl bromide and chloroacetyl chloride to form the N-substituted 4-bromobenzyl and chloroacetyl derivatives, respectively. The aza crown and its derivatives were identified with spectroscopic data. The bidentate phosphine amine, Ph2P(CH2)3NH2, was prepared via reduction of 3-(diphenylphosphino)propionitrile by lithium tetrahydroaluminate. Schiff-base reactions between the amine group in Ph2P(CH2)3NH2 and the aldehyde group in benzaldehyde and 4-formyl-benzo-15-crown-5 provided the respective phosphine derivatives. These products were identified with spectroscopic and analytical data. Finally, palladium derivatives of these phosphine-Shiff base ligands (Ph2P(CH2)3NCHR; R = Ph, benzo-15-crown-5) were synthesized from the reactions between (Ph2CN)2PdCl2 and the ligands.
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Metallomics of Mercury: The Role of SeleniumKhan, Mohammad 26 October 2010 (has links)
Mercury-selenium (Hg-Se) interaction is perhaps the most documented bioantagonism. Since its discovery in the 1960s, extensive studies have been carried out on the wide occurrence, chemical mechanisms, and toxicological significance of this bioantagonism. However, major knowledge gaps exist in the underlying mechanism at the molecular level which is the objective of this present research.
To study molecular level mechanism of this bioantagonism, four new MeHg-selenoamino acid namely, methylmercury-D,L-selenopenicillaminate, methylmercury-L-selenoglutathionate, and two methylmercury-L-selenomethioninate complexes (one via a Hg-Se bonding and the other via Hg-N bonding) were synthesized and characterized by NMR, FT-IR and mass spectrometry. Their structural and electronic properties were studied by X-ray crystallography and quantum mechanical calculations. These studies reveal that all four complexes chemically and structurally resemble their sulfur analogues. This suggests that mimicry could play a role in the MeHg-Se antagonism. Chemical coupling values from NMR suggest that MeHg+ has stronger affinity for Se than for S.
It has long been proposed and analytically proven that mercury selenide, HgSe(s), is the end product of the Hg-Se bioantagonism. However, the pathway of its formation in biological systems was poorly understood. Experiments carried out in this study suggested that HgSe(s) could be formed from both inorganic Hg and MeHg in the presence of Se.
In the case of MeHg, we found that its binding with selenoamino acids could result in the demethylation of MeHg and formation of HgSe nanoparticles. NMR and gas chromatography – mass spectrometry (GC-MS) studies confirmed the presence of bis(methylmercury) selenide (BMSe) and dimethylmercury as reaction intermediates based on which a demethylation pathway was proposed.
Inorganic Hg interacts with selenite in presence of glutathione (GSH) and form HgSe1-xSx (0 < x < 1) nanoparticles via a black solution or precipitate. The dissolution/precipitation is reversible upon adjustment of pH. UV-visible spectra, TEM and XPS analyses revealed that the black solution is HgSe1-xSx nanoparticles with diameter < 5 nm which at high pH and upon separation becomes sparingly soluble. This study provides a new plausible explanation of tissue distribution patterns of HgSexS1-x in biological systems.
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Low valent and low co-ordinate complexes of transition metals and lanthanidesArnold, Polly Louise January 1997 (has links)
No description available.
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