One of prospective procedures of absorbing thermal energy and releasing it during the required time is the application of phase change materials known as PCMs in building envelopes. High thermal energy storage (TES) materials has been a technology that effects the energy efficiency of a building by contributing in using onsite resources and reducing cooling or heating loads. Currently, many TES systems are emerging and contributing in building assemblies, however using an appropriate type of TES in a specific building and climate requires an in-depth knowledge of their properties. This research aims to provide a thorough review of a broad range of thermal energy storage technologies including their potential application in buildings. Subsequently, a comparative study and simulation between a basecase and an optimized model by PCM is thoroughly considered to understand the effect of high thermal storage building's shell on energy efficiency and indoor thermal comfort. Specifically this study proposes that the incorporation of PCM into glazing system as a high thermal capacity system will improve windows thermal performance and thermal capacity to varying climatic conditions. The generated results by eQUEST energy modeling software demonstrates approximately 25% reduction in cooling loads during the summer and 10% reduction in heating loads during the winter for optimized office building by PCM in hot arid climate of Arizona. Besides, using PCM in glazing system will reduce heat gain through the windows by conduction phenomenon. The hourly results indicates the effect of PCM as a thermal energy storage system in building envelopes for building's energy efficiency and thermal regulation. However, several problems need to be tackled before LHTES can reliably and practically be applied. We conclude with some suggestions for future work.