Several cruises of current measurements along various cross-Taiwan Strait transects were conducted by using shipboard Acoustic Doppler Current Profiler (ADCP) during 2001-2003. The main purpose of these experiments is to obtain seasonal variations of flow structures and volume transport in the central and southern regions of the Taiwan Strait. In each cruise the semidiurnal tidal currents were eliminated from the ADCP currents by two different methods, i.e., the phase averaging method and the TSNOW calculation. The subtidal current in the Taiwan Strait generally flows in the parallel-strait direction. In summer when the southwest monsoon prevails, the water in the strait originates from the South China Sea (SCS) or the Kuroshio. This northward-flowing water is divided into two parts by the archipelago of Penghu; the majority keeps flowing northward along the Penghu Channel (PHC), the minority flows northwestward around the Penghu Island. The flows in the surface layer of the PHC reach a maximum speed of 60 cm/s or greater. In winter, strong NE winds push the fresh and cold China Coastal water southward, along the western part of the Taiwan Strait. The SCS or Kuroshio water still flows northward on the eastern part of the strait. The maximum northward current still occurs in the PHC and is around 20 cm/s or less in the winter. Our results from the phase averaging method of all six cruises indicate that the net transports along the Taiwan Strait are all flowing northward, with a maximum value of about 2.5 Sv in summer (August 2001) and a minimum value of about 0.5 Sv in winter (March 2003). The standard deviation of the volume transport is 0.3 Sv. Due to its greater depths and strong currents, the volume transport in the PHC amounts to approximately 75% of the total transport of the Taiwan Strait. Based on the phase averaging results, the transport is related to the along-strait wind by a simple regression: , the sign convention is positive for southwesterly wind and transport.

In previous studies the slotted orifice plate has demonstrated superior performance characteristics to those of the standard orifice plate. In this study, these comparisons are investigated further. The response characteristics of the slotted orifice plate to the standard orifice plate and V-Cone for two-phase flows of water and air at various qualities, flow rates, and pressures are shown visually. The effect of oil as it flows through a slotted orifice plate and standard orifice plate are visually documented. The effect of manufacturing accuracy on the slotted orifice plates is investigated as to the effect on the coefficient of discharge, percent change in pressure, and Reynolds number. The slotted orifice plate mixes two-phase flow better than the standard orifice plate and V-Cone. There is a manufacturing effect on the slotted orifice plates; the larger the area of the slots, the larger the discharge coefficient.

The slotted plate flow meter has been widely tested as an obstruction flow meter during the past several years. It has been tested for both single-phase flows as well as for two-phase flows. Previous studies have revealed that the slotted plate flow meter is always better in performance and accuracy than the standard orifice plate flow meter. This study is primarily based on how a slotted plate responds to horizontal two-phase flow with air and water being used as the working fluids. The plates under consideration are those with beta ratios of 0.43 and 0.467. Experiments have been performed with six different configurations of the slotted plate test sections. The performances of the slotted plate flow meters will be compared to that of a standard orifice plate flow meter and then with a venturi. The effects of varying the upstream quality of the two-phase flow on the differential pressure and the coefficient of discharge of the slotted plates, the standard orifice plate and the venturi will be evaluated. Response characteristics at low differential pressures will be investigated. Tests for repeatability will be performed by studying the effects of the gas Reynolds number and the upstream quality on the differential pressure. The differential pressures across the slotted plates, the standard orifice plate and the venturi will be compared. Reproducibility will be evaluated by comparing the data obtained from all six different configurations. One of the main objectives of this study is to arrive at the best suitable procedure for accurately measuring the flow rate of two-phase flow using the slotted plate flow meter.

The generation and propagation of fluorescence light within biological tissue offers the potential for biomedical diagnostics and analyte sensing. Arising from an exogenous fluorescent dye injected as a contrast agent or immobilized in a polymer implant, the fluorescent decay kinetics can be sensitive to the tissue??s biochemical environment, providing quantitative in vivo information of the confined tissue site. The impact of light propagation and decay kinetics upon the measured signals is important for consideration, simply because tissue scatters light, giving rise to nanosecond photon time-of-flights that are comparable to fluorescence relaxation kinetics. The goal of this study is to develop a time-dependent model describing (i) the generation of fluorescence from dyes exhibiting multi-exponential or more complex kinetics and (ii) its propagation in scattering media. In the preliminary study, fluorescence lifetime spectroscopy is investigated in tissue-like scattering solution. Two fluorescent dyes, 3,3-diethylthiatricarbocyanine iodide (DTTCI) and Indocynanine Green (ICG), which exhibit distinctly different lifetimes and each exhibits single-exponential decay kinetics, were employed. Measurements of phase-modulation as a function of modulation frequency were made at varying concentration ratios of the two dyes to experimentally simulate fluorescence multi-exponential decay kinetics in non-scattering and scattering solutions. The results suggest that frequency-domain measurements of fluorescent decay kinetics along with models of light propagation may be enhanced by scatter in order to probe kinetics more sensitively than in non-scattering solutions. The next study involved fluorescence lifetime sensing in scattering and non-scattering solutions with a pH sensitive dye, Carboxy Seminaphthofluorescein-1 (C-SNAFL-1), which is known to exhibit multi-exponential decay kinetics. The results demonstrate accurate pH sensing in scattering solution via fluorescence kinetics using a simplified propagation model incorporating an average lifetime. Finally, fluorescence lifetime sensing in immobilized systems were investigated. C-SNAFL-1 was immobilized in poly(ethylene glycol) (PEG) microparticles that were immersed in buffered polystyrene solutions. The results demonstrate the ability to perform pH sensing with fluorescence lifetime without the confounding effect of fluorophore loading or the use of 'reference' measurement within multiply scattering systems. In addition, the stability of the immobilized fluorescence sensor and the reliability of fluorescence lifetime measurement verify the prospect of this technology for implantable purposes.

Considered in this thesis is multi-input multi-output (MIMO) systems with non-minimum phase (NMP) zeros and unstable poles where some of the unstable poles are located to the right of the NMP zeros. In the single-input single-output (SISO) case such systems pose serious difficulties in controller synthesis for performance and stability. In spite of the added degrees of freedom the MIMO case also poses difficulties as has been shown in the stabilization of the X-29 aircraft. When using the MIMO QFT technique the synthesis starts by considering a set of equivalent SISO plants derived from the plant transfer function matrix that are used to develop a controller. In effect the design problem is reduced to several MISO designs with the diagonal entries of as the equivalent SISO plants. Developed is a transformation scheme that can be used to condition the resulting equivalent SISO plants so that the difficult problem of NMP zeros lying to the left of unstable poles is avoided. Examples illustrate the use of the proposed transformation.

The carrier envelope (CE) phase of a femtosecond laser was stabilized. The laser produces an ultra stable comb of frequency spanning the visible region and basically is an optical frequency synthesizer and ready for the frequency domain applications. In this context, the CW stability of the Ti:sapphire laser is discussed to provide a procedure for the femtosecond laser adjustments. In addition, the pulse trains emitted by the femtosecond laser are described analytically to provide a theoretical basis for carrier envelope phase stabilization. An f to 2f interferometer was used to detect the carrier envelope offset frequency, and a fast photo diode was employed to measure the repetition rate. Two similar designed phase lock loops are used to stabilize both the carrier envelope offset frequency and the repetition rate to the respective reference frequencies. The stability reaches 100mHz for the carrier envelope offset frequency and 10mHz for the repetition rate for a period of up to an hour. Doppler free iodine saturation spectroscopy was set up to provide a precise frequency reference to which a CW dye laser can be locked on. The near future goal is to accurately measure this frequency stabilized dye laser with the optical frequency synthesizer.

Electrohydrodynamic (EHD) pumping of single and two-phase media is attractive for terrestrial and outer space applications since it is non-mechanical, lightweight, and involves no moving parts. In addition to pure pumping purposes, EHD pumps are also used for the enhancement of heat transfer, as an increase in mass transport often translates to an augmentation of the heat transfer. Applications, for example, include two-phase heat exchangers, heat pipes, and capillary pumping loops. In this research, EHD induction pumping of liquid film in annular horizontal and vertical configurations is investigated. A non-dimensional analytical model accounting for electric shear stress existing only at the liquid/vapor interface is developed for attraction and repulsion pumping modes. The effects of all involved parameters including the external load (i.e. pressure gradient) and gravitational force on the nondimensional interfacial velocity are presented. A non-dimensional stability analysis of EHD induction pumping of liquid film in a vertical annular configuration in the presence of external load for repulsion mode is carried out. A general non-dimensional stability criterion is presented. Stability maps are introduced allowing classification of pump operation as stable or unstable based on the input operating parameters. An advanced numerical model accounting for the charges induced throughout the bulk of the fluid due to the temperature gradient for EHD induction pumping of liquid film in a vertical annular configuration is derived. A non-dimensional parametric study including the effects of external load is carried out for different entrance temperature profiles and in the presence of Joule heating. Finally, a non-dimensional theoretical model is developed to investigate and to understand the EHD conduction phenomenon in electrode geometries capable of generating a net flow. It is shown that with minimal drag electrode design, the EHD conduction phenomenon is capable of providing a net flow. The theoretical model is further extended to study the effect of EHD conduction phenomenon for a two-phase flow (i.e. a stratified liquid/ vapor medium). The numerical results presented confirm the concept of liquid film net flow generation with the EHD conduction mechanism.

Liquid-metal Rankine power conversion systems (PCS) coupled with a fission reactor remain an attractive option for space power applications because system specific power and efficiency is very favorable for plant designs of 100 kW(e) or higher. Potential drawbacks to the technology in a reduced gravity environment include two-phase fluid management processes such as liquid-vapor phase separation. The most critical location for phase separation is at the boiler exit where only vapor must be sent to the turbine because blade erosion occurs from high velocity liquid droplets entrained by vapor flow. Previous studies have proposed that rotary separators be used to separate the liquid and vapor from a two phase mixture. However these devices have complex turbo machinery, require kilowatts of power and are untested for high vapor flow conditions. The Interphase Transport Phenomena (ITP) laboratory has developed a low-power, passive microgravity vortex phase separator (MVS) which has already proven to be an essential component of two-phase systems operating in low gravity environments. This thesis presents results from flight experiments where a Rankine cycle was operated in a reduced gravity environment for the first time by utilizing the MVS for liquid and vapor phase separation. The MVS was able to operate under saturated conditions and adjust to system transients as it would in the Rankine cycle by controlling the amount of liquid and vapor within the device. A new model is developed for the MVS to predict separation performance at high vapor flow conditions for sizing the separator at the boiler, condenser, and turbine locations within the cycle by using a volume limiting method. This model factors in the following separator characteristics: mass, pumping power, and available buffer volume for system transients. The study is concluded with overall Rankine efficiency and performance changes due to adding vortex phase separation and a schematic of the Rankine cycle with the integration of the MVS is presented. The results from this thesis indicate the thermal to electric efficiency and specific mass of the cycle can be improved by using the MVS to separate the two phases instead of a rotary separator.

A new correlation for the prediction of the Countercurrent Flow Limitation (CCFL) in a large diameter tube with a falling water lm is proposed. Dierent from previous correlations, it predicts the onset of ooding by considering the relative velocities of the working uids and the lm thickness of the liquid layer. This provides a more complete accounting of the physical forces contributing to CCFL. This work has been undertaken in order to provide a better estimate of CCFL for reactor safety codes such as MELCOR, MAAP, and SCDAP/RELAP. Experiments were conducted to determine the CCFL for a 3-inch inner diameter smooth tube with an annular liquid lm and air injection from the bottom. The size of the test section and the range of working uid ow rates were based on a scaling analysis of the surge line of a PressurizedWater Reactor pressurizer. An experimental facility was designed and constructed based on this analysis in order to collect data on the CCFL phenomenon. In order to capture some of the physical phenomena at the onset of ooding visual pictures were taken at high speed. These pictures provided a new understanding of the process of transition to ooding. The facility also produced a new set of ooding data. This can also lead to a more comprehensive mechanistic model.

By means of molecular simulation, we propose possible packing models for £\ and £\¡¬ phases in poly(9,9-di-n-hexyl-2,7-fluorene) (PFH). Simulated multi-chain unit cell structures are compared with experimental diffraction patterns of PFH where the unit cell structure (and the space group) of the high-temperature £\ crystals was identified as monoclinic (C2) and that of £\¡¬ phase (kinetically favored upon programmed cooling) triclinic (P1). Results show that £\ phase prefers to adopt bi-radial side-chain conformation whereas the £\¡¬ phase prefers tetra-radial one. Both models exhibit embracing behavior between adjacent chains in spite of differences in inter-chain distance. A group of embracing chains aligned along b-axis in £\ phase and the comparatively greater inter-chain distance in £\¡¬ phase are consistent with the observed faceting along (100) planes and the tensile cracking along the a-axis. A qualitative analysis of co-existing £\ and £\¡¬ phases reproduce the [001] SAED pattern quite well. In addition, we also show that arbitrary alternation of 40o and 140o in dihedral angle between neighboring monomers generates equally stable single-chain conformations in this case of linear alkyl side-chains.