<p>The functionalization of nonwoven electrospun polymeric fibers with metallic nanostructures has enabled the design of novel nanocomposite materials used in a wide range of applications. In particular, designs based on incorporating established antimicrobial species such as copper and silver have potential applications as antimicrobial filtration membranes, leveraging on the convoluted fiber assembly and high surface area–to–volume ratios of the constitutive fibers. Electroless deposition based on spontaneous electrochemical reactions offers a facile and tunable methodology for surface–confined growth of metallic nanostructures on the non–planar substrate architectures presented by nonwoven electrospun fibers. </p> <p>Firstly, this work explores, in a broad sense, the effects of two different seed catalyst chemistries, palladium and silver, on the evolution of copper nanoparticles on electrospun polyacrylonitrile fibers. Copper nanoparticle coverage and conformity; deposition kinetics; modifications in the surface chemistry of the PAN fibers; and thermal stability of the resultant nanocomposites were examined. Secondly, qualitative and quantitative assessment of the interfacial adhesion between the copper nanostructures and PAN fibers were undertaken by exploiting the elastic mismatch between both phases during tensile deformation. For copper nanocubes on nanofibers, the adhesion energy is estimated to be between 0.48 J/m² and 1.0 J/m² using strain and growth based adhesion models.</p> <p>Macroscopically, the compliant nature of the nonwoven fiber mats makes them susceptible to out-of-plane deformation during water filtration processes which may alter their size exclusion configuration for effective filtration. A bulge testing device is built and implemented to simulate and characterize hydraulic flow – induced deformation in the electrospun PAN fiber mats. The pressure–deflection relationships of the mats show a sub-linear dependence in contrast to classical continuum materials. The macroscopic mat behavior was governed by the properties of the constituent fibers, with an apparent mat bending rigidity dependent on the fiber diameters.</p> <p> Lastly, the nonwoven fiber mats functionalized with copper nanoparticles were evaluated for use as potential antimicrobial microfiltration membranes. The fiber mats displayed high water flux and high separation efficiency for model 3 μm particles, with separation factors reaching above 99%.</p>

Kohlenstofffasern sind aufgrund ihrer hohen massespezifischen mechanischen Belastbarkeit ein unverzichtbarer Werkstoff im Leichtbau. Diese werden mittels eines zeitaufwendigen, thermooxidativen Stabilisierungs- und eines inerten Carbonisierungsprozesses hergestellt. Bedingt durch die kommerziell dominierte Forschung basiert der Großteil der veröffentlichten Optimierungsansätze für diese Prozessschritte bis heute auf unvollständigen, empirischen oder nicht-parametrischen, datengetriebenen Modellen. In der vorliegenden Arbeit werden hybride semi-parametrische Ansätze unter Berücksichtigung der Eigenschaften des Precursorsystems und der Prozessparameter für die Modellierung des Stabilisierungsprozesses untersucht. / Carbon fibers are an indispensable material in lightweight construction due to their mass-specific mechanical load capaci-ty. These are produced by means of a time-consuming, thermo-oxidative stabilization process and an inert carbonizationprocess. Due to commercially dominated research, the majority of published optimization approaches for these processsteps to date is based on incomplete, empirical or non-parametric, data-driven models. In the present work, hybrid semi-parametric approaches considering the properties of the precursor system and the process parameters are investigated formodeling of the stabilization process.

The globally increasing energy demand that results from the rapid development of modern society has created intensive attention towards the importance of energy efficiency. The areas of energy storage and energy conversion have become one of the most important topics in scientific community at present. As new generation energy storage elements, supercapacitors have exhibited promising practical prospects in the information, transportation, electronics and other sectors due to their charge and discharge performance at high rate, high power density as well as long cycle life. Energy density, including gravimetric energy density, areal energy density and volumetric energy density, is one of the most critical indicator evaluating the performance of supercapacitors. The electrochemical performance of supercapacitors depends mainly on the electrochemical activities and kinetic properties of electrode materials. Carbonaceous materials are deemed to be highly promising, and therefore are extensively investigated energy storage materials for supercapacitors because of their environmental friendliness, low-cost production and outstanding chemical inertness during charging-discharging processes. The specific surface area has been long thought to be the main factor influencing the capacitance of carbonaceous materials. However, the pore structure is of similar importance. High specific surface areas are always arising from a high content of micropores. However, pore radii in the sub-nanometer range impede the ionic charge transfer ability significantly and thus cause a damping of capacitance. In this thesis, hierarchical porous carbons and their composite materials were fabricated by using polyacrylonitrile as carbon precursor for a tailored step-by-step pore forming method, including phase inversion, CaCO3 activation and KOH activation. The materials were thoroughly characterized by XRD, SEM, TEM, BET, XPS and Raman spectroscopy to ascertain the chemical and structural features. The electrochemical properties were studied by cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) and electrochemical impedance spectroscopy (EIS) in detail to analyze the pore effect, which strongly influence their electrochemical properties. Porous carbons with high specific surface areas up to 2315 m2 g-1 and high pore volume of 1.9 cm3·g-1 were prepared. A step-wise pore forming method was employed to ensure a high specific surface area and high content of macro/mesopore at the same time. The relationship between pore structure, electrochemical capacitance and rate capability was investigated by changing the content of micropores. For a same specific surface area, a higher micropore content led to a lower capacitance and poorer rate capability. Based on these results, the capacitance was optimized to be 286.8 F g-1. The areal energy density of the supercapacitors can be improved by increasing the mass loading in a certain area directly. However, insufficient electrochemical reaction may be caused by a lack of unhindered electrical and ionic charge transfer routes, resulting in inefficient material utilization. This problem is addressed by designing hierarchical pore structures with embedded conductive additives. Thus, hierarchical porous carbons were modified by embedding carbon nanotubes (CNTs), followed by coverage with thin layers of birnessite. Owing to the hierarchical pore design and the very high pore volume, the birnessite coverage did not cause pore blocking. At the same time, an intimate contact between carbon and birnessite was established. A high area energy density of 627.8 μWh·cm-2 was obtained based on an optimized mass loading of 13.9 mg cm-2. The volumetric energy density of supercapacitors was determined by the density and porosity of active materials. Similarly, the dense active materials not always generate high specific capacitance because of an increased dead mass. However, too porous active materials do not provide sufficient volumetric capacitance due to a waste of space. Thus, density and porosity must be balanced by hierarchical pore structure design so that all pores are interconnected and can be accessed by ions. At the same time, the content of these pores should be as low as possible to save space. Based on the results, highly hierarchical porous carbons were synthesized and embedded into conductive carbon foam to combine electronic conductivity with ionic transfer. In that way, a volumetric energy density as high as 19.44 µWh cm-3 at a volumetric power density of 500 mW cm-3 was generated.