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Thesis (Ph. D.)--Civil and Environmental Engineering, Georgia Institute of Technology, 2009. / Committee Chair: Weber, Rodney; Committee Co-Chair: Bergin, Michael; Committee Member: Mulholland, James; Committee Member: Nenes, Athanasios; Committee Member: Russell, Armistead. Part of the SMARTech Electronic Thesis and Dissertation Collection.

Every year millions of construction workers are exposed to dust in levels that create a hazard to them (Fundukian, 2011). Their environment is contaminated by activities such as cutting, chipping, grinding and sanding building materials. The Occupational Safety and Health Administration (OSHA) refers to this general collection of building materials debris and fine particulates as nuisance dust. Some of the particles in nuisance dust possess properties that make them especially hazardous, such as their shape or specific gravity. It has been found by the Center for Disease Control (CDC) that inhalation of quantities of silica dust above the permissible exposure limit (15.0 mg/m3) causes a deterioration of the outside lining of the lung.This research seeks to limit this exposure by a pretreatment process using acid application and then absorbed moisture content that reduces airborne particulate during the removal of cement stucco surfacing materials. Successful pretreatment would allow removal of CSSM from substrates such that the release of airborne particulates does not exceed the permissible exposure limits (PEL) found in the 29 CFR-Table Z-3 for mining applications (15-mg/m3). / Includes bibliography. / Thesis (M.S.)--Florida Atlantic University, 2015 / FAU Electronic Theses and Dissertations Collection

published_or_final_version / Environmental Management / Master / Master of Science in Environmental Management

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This thesis characterizes properties of ambient secondary organic aerosol (SOA), an important and abundant component of particulate matter. The findings presented in this thesis are significant because they represent the results from ambient measurements, which are relatively scarce, and because they report on properties of SOA that, until now, were highly uncertain. The analyses utilized the fraction of particulate organic carbon that was soluble in water (WSOCp) to approximate SOA concentrations in two largely different urban environments, Mexico City and Atlanta. In Mexico City, measurements of atmospheric gases and fine particle chemistry were made at a site ~ 30 km down wind of the city center. Using box model analyses and a comparison to ammonium nitrate aerosol, a species whose thermodynamic properties are generally understood, the morning formation and mid-day evaporation of SOA are investigated. In Atlanta, simultaneous measurements of WSOCp and water-soluble organic carbon in the gas phase (WSOCg) were carried out for an entire summer to investigate the sources and partitioning of WSOC. The results suggest that both WSOCp and WSOCg were secondary and biogenic, except possibly in several strong biomass burning events. The gas/particle partitioning of WSOC in Atlanta was investigated through the parameter, Fp, which represented the fraction of WSOC in the particle phase. Factors that appear to influence WSOC partitioning in Atlanta include ambient relative humidity and the WSOCp mass concentration. There was also a relationship between the NOx concentration and Fp, though this was not likely related to the partitioning process. Temperature did not appear to impact Fp, though this may have been due to positive relationships WSOCp and WSOCg each exhibited with temperature. Neither the total Organic Carbon aerosol mass concentration nor the ozone concentration impacted WSOC partitioning.

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