Muskeg or peat deposits cover large areas in northern Manitoba. Test sections of a newly constructed highway on peat were instrumented to investigate their performance and to develop more economical means of construction method. Test Section ‘A’ was constructed with geotextile base layer while Section ‘B’ was with geotextile and corduroys (timber logs). The test sections were constructed during winter for ease in mobilizing construction equipment at the site when the ground was frozen and were instrumented to observe its behaviour and performance. Settlements were measured using monitoring plates and pins. Ground temperatures were measured using thermistors. Porewater pressures were measured using vibrating wire piezometers. Peat in the study area has an average thickness of 4m, with the upper layer classified as fibrous and the lower layer as amorphous with strong to complete decomposition. Standard laboratory tests were conducted on bored samples from the site. Hydraulic conductivity tests were carried out at different vertical pressures to determine its permeability. Thermal conductivity was determined at frozen and unfrozen state of peat. Conventional incremental oedometer tests were conducted to determine the compressibility parameters and secondary compression indices of the peat layers. Constant-rate-of-strain (CRS) tests were also performed to supplement the results obtained from the conventional method. Isotropically-Consolidated Undrained (CIŪ) triaxial tests were carried out to determine the shear strength of peat. A commercially-available computer program was used in the numerical modelling to simulate the field performance of the instrumented sections. The results from numerical modelling were reasonably close to the measured values in the field. Laboratory-scale physical modelling was undertaken to understand further the operating mechanisms involved in the performance of the two test sections under a more controlled environment. Artificial transparent clay that has similar deformation properties with most of the natural clays and peats was used as foundation material. It allows determination of spatial deformations beneath the embankment using Particle Image Velocimetry (PIV) technique. The load-settlement behaviour in the field was also reasonably simulated in the laboratory-scaled physical model. Deformation patterns from PIV indicate that embankment with geotextile layer and corduroy has smaller settlements and lateral movements in the foundation compared to that of the embankment with only geotextile layer.

Reclamation success is highly dependent upon final soil quality of stockpiled soils, such as those found Cold Lake Oil Sands Region. Stockpiled soils, however, are generally poor in quality. Soils were amended with, biochar (BC), humalite (HU), a sub-bituminous coal; and peat (PT), as well as 50:50 blends of biochar:humalite (BCH) and biochar:peat (BCP). These amendments were applied at rates of 0, 6.55, 13.1 and 26.2 g C kg-1 each. Biochar, PT, and BCP applied at the rate of 26.2 g C kg-1 were found to reduce N2O emissions by 34, 54, and 70%, respectively, relative to the control. Within the bioassay, BC and PT amendment resulted in a 38 and 40% increase in dry matter yield (DMY) respectively. Finally, amendment typically resulted in significant net decreases in Olsen P values, while nitrate and ammonium concentrations were high in PT amended soils. In general, PT had the best overall performance. / October 2015

No description available.

A study of the interactions of the specifically interacting organic compound pyridine with a model soil organic matter sorbent (Pahokee peat) was carried out from different nonaqueous organic liquid media, including neat n-hexadecane, acetonitrile, acetone and nhexadecane mixtures with either acetone or acetonitrile. Kinetic and equilibrium studies using an activity-based comparison of the organic compounds in solution was used to study the interactions of soil organic matter (SOM) and pyridine sorption capability in the various non-aqueous organic liquid media. Quantification and qualification of pyridine and the other co-solvents were done using Gas Chromatography (GC). Sorption of pyridine from neat organic solvents was not masked by sorption of the organic solvent. The apparent sorbed amount calculated from the change in solute concentration and reported on a dry weight basis was considered to represent the true sorbed concentration of pyridine in the sorbent phase. Pyridine sorption was found to be non-linear and distribution coefficients decreased with solute concentration, by approximately three times in n-hexadecane, more than five times in acetonitrile, and by ten times in acetone over the experimental concentration range. Pyridine sorption from nhexadecane was also found to be comparable with sorbed amounts from acetone, but much lower in comparison to sorption from acetonitrile. Sorption of pyridine from n-hexadecane mixtures with acetonitrile or acetone demonstrated the solvent assisted effect of pyridine sorption. Sorption uptake of pyridine increased as initial acetonitrile concentration increased, this acetonitrile assisted trend for pyridine sorption was found in the presence of a large excess of n-hexadecane. Sorbed concentrations of pyridine measured in the presence of high concentrations of acetonitrile (close to it's solubility limit) were found to be very similar to pyridine sorption from neat acetonitrile. Sorption behaviour of pyridine in n-hexadecane-acetone mixtures showed that increasing acetone concentrations had no effect on pyridine sorption. Pyridine sorbed from n-hexadecane, n-hexadecane-acetonitrile, and n-hexadecaneacetone mixtures showed a hysteretic desorption to n-hexadecane. After a series of repeated solvent extractions with solvents of increasing solvating power(1,4-dioxane, ethanol, dimethylsulfoxide), a fraction of pyridine remained bound to the peat. This nonrecoverable fraction was approximately the same for the different organic media (OA5± 0.09 in n-hexadecane suspensions, 0.57±O.12 in n-hexadecane-acetonitrile mixtures, and OA6±0.07 in n-hexadecane-acetone mixtures). Acetonitrile sorption by peat from nhexadecane was found to be very non-linear and hysteretic. The acetonitrile sorbed was almost fully recoverable, around 90%, for the initial acetonitrile concentration range varying from 0.14-0.7% by volume. However in the presence of pyridine a significant portion of acetonitrile was not recovered even after multiple extractions of polar organic solvents. Pyridine irreversible binding was not induced by acetonitrile additions and was found to occur to the same extent in both neat n-hexadecane and n-hexadecane-acetone mixtures. The solubilities of acetonitrile and acetone were determined by the flask method at 25°C using GC analysis. Solubility in volume percent for acetonitrile in n-hexadecane, 0.9±0.07, 0.57±0.02 for n-hexadecane in acetonitrile, 24.0±OA for acetone in nhexadecane, and 13 A±O.2 for n-hexadecane in acetone, were found. Log Ostwald coefficient (1.63±O.02) for acetonitrile in n-hexadecane was measured at 25°C using head space analysis and was found to be constant in the acetonitrile concentration range 0.10.8% by volume. Log Ostwald coefficient for pyridine in hexadecane used was 3.02, for the pyridine concentration range 50 mgIL-500 mg/L, this value was constant even with 0.5% by volume additions of acetonitrile. Analyses of sorption isotherms were reported on an activity basis to eliminate the effect of differential solute interactions in the solvent, calculated using the solute equilibrium concentration, the concentration of saturated vapour, and the Ostwald coefficient. Dissolution of peat components into n-hexadecane are known to be negligible. Peat components extracted after 12 hours and 3,5 months acetonitrile and acetone treatment (solid liquid ratio 1: 10) Showed 15 to 20 times less visible absorbance respectively (A. 465, 620, and 665, E4:E6 ratios using DV-Visible Spectroscopy), than the 12 hours aqueous peat extract. Quantification of the dissolved humic materials in the aqueous extract was followed using a Total Organic Carbon analyser. The study found the degree of humification to be much lower in non-aqueous organic solvent extracts (2.5 for acetone extracts, and 3 for acetonitrile extracts) than in aqueous solution extracts (8.2). / Thesis (M.Sc.)-University of Natal, Pietermaritzburg, 2002. / The Moshe Greidinger Scholarship Fund.

Electrical resistivity tomography (ERT) is a commonly used geophysical method to investigate permafrost in the mountain environment, but few studies have employed this method in a permafrost affected peatland. For this thesis, 5 ERT profiles were measured over 17 palsas and peat-plateaus in a palsa peatland environment in Tavvavuoma, northern Sweden, where the primary aim was to investigate the depth to the base of permafrost under the mounds. These depths are also used to estimate the excess ice fraction (EIF), which is indicative of the proportion of segregation ice in the frozen core under the mounds. The internal structure of palsas and the spatial distribution of permafrost was also investigated from the inverted resistivity models. Permafrost thickness was found to range from 5 – 17 m, with the thickest permafrost in the west end of the study area. EIF values range between 0,04 to 0,58, with the lowest values in the same end as the deepest permafrost, where also low mound elevations are found. The deep permafrost combined with low mound elevations are suggested to be attributed to the presence of coarse grained (glaciofluvial) sediments where ice segregation formation is limited, thus small amounts of frost heave. Deep permafrost is possibly underlying at least two thermokarst depressions/fens in the area, which is suggested to obstruct their drainage. The height of the mounds was surprisingly found to decrease with permafrost thickness, a relationship that is likely to be an effect of the varied underlying sediment cover. This thesis demonstrates the applicability of ERT in peatland permafrost research, but also considers the limitations of the method. / Elektrisk resistivitetstomografi (ERT) är en geofysisk metod som har använts flitigt vid undersökningar av alpin permafrost, men få studier har hittills tillämpat denna teknik vid undersökningar av permafrost i myrmarker. Under detta examensarbete på masternivå mättes 5 ERT-profiler över 17 palsar samt torvplatåer i ett palsmyrkomplex med sporadisk permafrost i Tavvavuoma, norra Sverige, med det primära målet att undersöka permafrostens mäktighet under dessa. De beräknade permafrostdjupen används även för att uppskatta isöverskottsfraktionen (EIF), vilket ger en indikation på andelen segregationsis i den frusna kärnan under respektive pals/torvplatå. Palsarnas interna struktur och den rumsliga utbredningen av permafrost i myren diskuteras också kvalitativt utifrån resistivitetsmodellerna. Permafrostmäktigheten under palsar och torvplatåer bestämdes till mellan 5 – 17 meter, med den djupaste permafrosten i den västra delen av studieområdet. Isöverskottsfraktionen varierar mellan 0,04 – 0,58, med de lägsta värdena i samma del av studieområdet som den djupaste permafrosten fanns, här är även palshöjderna låga. Den djupa permafrosten i kombination med låga palshöjder föreslås tillskrivas förekomst av grovkorniga (glaciofluviala) sediment i denna del av studieområdet, där bildningen av segregationsis begränsas. I och med detta begränsas mängden frosthävning, med låga palshöjder som resultat. Djup permafrost kan finnas under minst två thermokarstsänkor i området, vilket kan hindra dränering av dessa. Ett oväntat resultat var att palshöjd minskar med ökat permafrostdjup bland de studerade objekten, vilket bäst kan förklaras med det varierade sedimentunderlaget, som ger mycket olika förutsättningar för segregationsisbildning. Denna masteruppsats visar på tillämpligheten av ERT i myrmarker med permafrost, men beaktar även metodens begränsningar för denna tillämpning.

A hydrological and biogeochemical study was undertaken at the Mer Bleue bog, Ottawa, Ontario, Canada from May 22, 1998 to May 21, 1999. Basin runoff was generated by groundwater discharge at the peatland margin, and groundwater discharge was controlled by hydraulic gradients and horizontal hydraulic conductivities (Kh). Flux of dissolved organic carbon (DOC) measured at the basin outflow was 8.3 g C m-2 yr-1 and compared to within 23% of DOC flux estimated using a Dupuit approximation of seepage during the ice-free season. Annual DOC flux was 11% of the annual carbon sink. / Flownet analysis showed that seasonal patterns of groundwater flow were controlled by boundary condition changes that resulted from precipitation and evapotranspiration events. A pattern of recharge was most common over the hydrological year, but a discharge pattern was observed during a 40 day groundwater flow reversal. Evaluation of the peatland recharge-discharge function using in situ sodium concentrations and a diffusion model revealed that the peatland is a long-term recharge system. It is hypothesized that peatland biogeochemical function is controlled by long-term recharge despite annual occurrence of groundwater flow reversals.

The impact of peatland restoration on Diptera assemblages was studied across multiple organizational levels (taxon, size class, trophic group) among abandoned-mined, restored and natural sites of three bogs and the environmental variables affecting those assemblages were determined. More than 22,000 individuals representing 716 species were collected using pan traps, sweeping and Malaise traps. Restored and abandoned sites were similar to each other and both distinct from natural sites as shown by small-size class, acalyptrate and trophic assemblages. However, abandoned sites showed much lower evenness and generally supported lower species richness than restored and natural sites, due to the dominance of one or two saprophagous species. The coverage of bare peat, Sphagnum mosses and ericaceous shrubs explained most of the variance in species composition. Those results suggest that restoration enhanced the recovery of high species diversity, although more than seven years are needed to recover a complete trophic structure or to enable species with low dispersal ability to recolonize to pre-disturbance levels.

The functional hydrological components of the ombrotrophic mire water balance are, considered in terms of their ecological relevance. It is proposed that numerical models provide a suitable framework for mire hydro-systems and their potential as quantitative tools for mire restoration and conservation management is demonstrated. Existing models previously applied to mires are reviewed. The USGS 3-D groundwater model MODFLOW is selected and a new shallow surface and groundwater model GSHAW5 is developed for application to mires. Extensive ecohydrological case studies are undertaken at two mire sites and the models are tested using data collected at the sites. Field studies at Wedholme Flow, Cumbria, extended over four years and the data collected were combined with historical records to form a 10-year hydrological data set. Studies at Trough End Bog, Northumbria, extended over a 3-year period. Topographic, soil and vegetation surveys were carried out at both sites. Watertable fluctuation was recorded manually on a weekly basis and electronically at a 20-minute interval along with automatic meteorological records. New hydrometric techniques were developed in the Surface Water Monitoring Plot, SWaMP, constructed at Trough End to record hydrological exchanges within the hummock-hollow complex of the mire acrotelm. The models operate on very different spatial and temporal scales. GSHAW5 is applied to reproduce ground and surface exchanges in the acrotel. MODFLOW is used to simulate large-scale exchanges in undisturbed areas and between regenerating and active peat cutting areas. Predictive MODFLOW simulations are used to examine the impact of different peat cutting regimes on mire hydrology and potential regeneration. Both models produce simulations strongly correlated to observed hydrological exchanges. The usefulness of numerical models as tools for mire management is considered in light of the model test results from both case studies. It is concluded that both models provide insight and quantitative estimates of hydrological exchanges not possible by other means. MODFLOW simulations reveal considerable water loss from the Wedholme Flow mire reserve to an active peat cutting area. Simulations of Trough End bog reveal hydrological acrotelm processes strongly related to vegetation assemblages. An extensified GSHAW5 acrotelm model is recommended for the simulation of intact ombrotrophic mires.

Northern peatlands are an important long-term sink for atmospheric carbon dioxide (CO2) and a contemporary source of methane (CH4). Under contemporary climate and environmental change, including enhanced nutrient deposition through industrialization and commercial peat harvesting, the microbial environment in peat is altered. Microorganisms are responsible for the net production of greenhouse gases in these sites, although controls on microbial activity and microbial communities are poorly understood, limiting our ability to predict greenhouse gas emissions. The objective of this thesis was to determine the microbial role in peat decomposition and greenhouse gas fluxes in northern peatlands. Nutrient, carbon (C) substrate, and microbial-ecological controls on microbial activity under natural climate variability, increased nutrient deposition, and commercial harvesting and restoration were explored in detail. Environmental change effects were evaluated in relation to processes and temporal variability in pristine sites. / The natural temporal variability of decomposition, microbial biomass, and nitrogen (N) was characterized in the Mer Bleue bog near Ottawa, ON over two years. In a warmer, drier year, lower water table position corresponded to increased N availability, which was in turn linked to enhanced microbial CO2 production, consistent with patterns in ecosystem respiration measured at the site level. It was shown that microbial activity can play an important role in inter-annual climate driven ecosystem respiration and net ecosystem CO2 exchange. / Through field and laboratory nutrient fertilization experiments, it was shown that increased nitrogen (N) deposition altered the heterotrophic microbial community at Met Bleue and led to decreased decomposition rates after one year, despite increased total microbial biomass. After the second year of fertilization, however, decomposition rates were elevated, presumably a result of a concomitant shift in moss species and supply of more bioavailable plant material. Comparison of fertilizations in the presence and absence of vegetation indicated that in oligotrophic sites, vegetation mediated elevated nutrient effects on decomposition and that N cycling occurred largely in the organic forms. / Aerobic and anaerobic microbial activity, peat organic and nutrient chemistry, microbial biomass, and methanogen, CH4-oxidizing bacteria, bacteria, and archaea were characterized in two sets of pristine, actively harvested, harvested and abandoned, and harvested and restored peatlands in Quebec and New Brunswick.

Two ombrotrophic peat bogs (NC2 and BL2) from North Stradbroke Island, Australia, were precisely dated using 210Pb and analyzed by scanning electron microscopy. Sub-samples were total digested and sequentially leached for trace and major elements concentrations using ICP-MS and ICP-OES. Total Pb concentrations in both profiles increased with the time. PAAS normalized REE patterns were characterized by relatively flat patterns, with slight enrichment in LREE, and a significant negative Eu anomaly. The temporal changes in metal concentrations, 206Pb/207Pb ratios, REEs, and ash content observed in the two profiles suggest three different periods with distinct conditions in terms of dust provenance and atmospheric pollution: (1) Pre-anthropogenic (pre-1842); (2) Early industrial (from 1840s to 1920s); (3) Industrial (post-1930s). Ombrotrophic peat bogs may be reliable archives of environmental pollution, but also shows that adjacent sites may provide contrasting evidence. Despite their close proximity, the two sites show different trends in metal deposition. Metals in NC appear to be largely bound to minerals and inorganic materials, while in BL they are mainly organic-related. Indeed the peculiar behaviour of Pb in the BL profile suggests that biological process may cause Pb isotopic fractionation. Ash contents, texture, Pb isotopic compositions, Sb/Pb values, patterns of selected trace elements (Pb, Cu, Zn, Cd, Cr, Co, Sb, Ni, Se, As, Be and Mo), and their leaching behaviours suggests that NC and BL are chemically different types of peat bogs. NC peat bog is an open sink for elements, and can be used to define regional anthropogenic impacts. In contrast, the BL site appears to be influenced by local natural and anthropogenic processes and activities, such as changes in land use. Furthermore, it demonstrated that only some of the environmental-related trace elements preserve their original depositional record. Arsenic, Be, Co, and Zn are highly mobile under weak acid conditions, and are therefore not suitable for assessing temporal trends of pollution. Cadmium, Ni, and V may also be highly mobile under certain conditions. In contrast, Pb, Cu, Cr, Mo, and Sb are not subject to vertical migration, and are useful for establishing the pollution record of ombrotrophic peat bogs.