In order to pursue continuous profit and long term management, the human resources is can be consider as an important assets of enterprises.The goal of human resource development is set up for organization future development, and staff capability can also been improve from the effective execution of education and training. Moreover, human resource development is a tool of promoting manpower into organizational ability via education and training. Thus, enterprises in various countries have invested in human resource management for the improvement in the level of its development.This research has covered many areas, including, motivations of education and training , personal knowledge transfer, positive effort of personal knowledge transfer in relate to work performance and learning effectiveness, and evaluation of the result after educational training . This research is based on 281 effectively survey from staff who has been through business educational training among manufacturing, service and financial sectors in Taiwan.By applying SEM, ANOVA system on real event analysis, the result of study is shown as below. Firstly, motivations of education and training and personal knowledge transfer have generated positive effort in relating to work performance and learning effectiveness. Secondly, according to survey, motivations of education and training has positive impact on personal knowledge transfer, and at the same time, personal knowledge transfer also brings positive influence to work performance. Therefore, it also indicates that motivations of education and training has positive impact to work performance as well. Third, as known motivations of education and training have positive impact on personal knowledge transfer. On the other hand, personal knowledge transfer has brought positive influence to learning effectiveness. Therefore, it also indicates that motivations of education and training has positive impact to learning effectiveness as well.Eventually, various personal characteristics may cause different impact on motivations of education and training , personal knowledge transfer, work performance and learning effectiveness.